6,898 research outputs found

    Pathways for the Valorization of Animal and Human Waste to Biofuels, Sustainable Materials, and Value-Added Chemicals

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    Human and animal waste, including waste products originating from human or animal digestive systems, such as urine, feces, and animal manure, have constituted a nuisance to the environment. Inappropriate disposal and poor sanitation of human and animal waste often cause negative impacts on human health through contamination of the terrestrial environment, soil, and water bodies. Therefore, it is necessary to convert these wastes into useful resources to mitigate their adverse environmental effect. The present study provides an overview and research progress of different thermochemical and biological conversion pathways for the transformation of human- and animal-derived waste into valuable resources. The physicochemical properties of human and animal waste are meticulously discussed, as well as nutrient recovery strategies. In addition, a bibliometric analysis is provided to identify the trends in research and knowledge gaps. The results reveal that the USA, China, and England are the dominant countries in the research areas related to resource recovery from human or animal waste. In addition, researchers from the University of Illinois, the University of California Davis, the Chinese Academy of Sciences, and Zhejiang University are front runners in research related to these areas. Future research could be extended to the development of technologies for on-site recovery of resources, exploring integrated resource recovery pathways, and exploring different safe waste processing methods

    Assessing Atmospheric Pollution and Its Impacts on the Human Health

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    This reprint contains articles published in the Special Issue entitled "Assessing Atmospheric Pollution and Its Impacts on the Human Health" in the journal Atmosphere. The research focuses on the evaluation of atmospheric pollution by statistical methods on the one hand, and on the other hand, on the evaluation of the relationship between the level of pollution and the extent of its effect on the population's health, especially on pulmonary diseases

    KYT2022 Finnish Research Programme on Nuclear Waste Management 2019–2022 : Final Report

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    KYT2022 (Finnish Research Programme on Nuclear Waste Management 2019–2022), organised by the Ministry of Economic Affairs and Employment, was a national research programme with the objective to ensure that the authorities have sufficient levels of nuclear expertise and preparedness that are needed for safety of nuclear waste management. The starting point for public research programs on nuclear safety is that they create the conditions for maintaining the knowledge required for the continued safe and economic use of nuclear energy, developing new know-how and participating in international collaboration. The content of the KYT2022 research programme was composed of nationally important research topics, which are the safety, feasibility and acceptability of nuclear waste management. KYT2022 research programme also functioned as a discussion and information-sharing forum for the authorities, those responsible for nuclear waste management and the research organizations, which helped to make use of the limited research resources. The programme aimed to develop national research infrastructure, ensure the continuing availability of expertise, produce high-level scientific research and increase general knowledge of nuclear waste management

    PARAMETRIC APPROACHES TO BALANCE STORMWATER MANAGEMENT AND HUMAN WELLBEING WITHIN URBAN GREEN SPACE

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    Through rapid urbanisation, urban green spaces (UGS) have become increasingly limited and valuable in high-density urban environments. However, meeting the diverse requirements of sustainable urban development often leads to conflicts in UGS usage. For example, the presence of stormwater treatment facilities may hinder residents' access to adjacent UGS. Traditional approaches to UGS design typically focus on separate evaluations of human wellbeing and stormwater management. However, using questionnaires, interviews, and surveys for human wellbeing evaluation can be challenging to generalise across different projects and cities. Additionally, professional hydrological models used for stormwater management require extensive knowledge of hydrology and struggle to integrate their 2D evaluation methods with 3D models. To address these challenges, this thesis proposes a novel framework to integrate the two types of analysis within a system for balancing the needs of human wellbeing and stormwater management in UGS design. The framework incorporates criteria and parameters for evaluating human wellbeing and stormwater management in a 3D model and introduces an approach to compare these two needs in terms of UGS area and suitable location. The contributions of this thesis to multi-objective UGS design are as follows: (1) defining human wellbeing evaluation through Accessibility and Usability assessment, which considers factors such as connectivity, walking distance, space enclosure, and space availability; (2) simplifying stormwater evaluation using particle systems and design curves to streamline complex hydrological models; (3) integrating the two evaluations by comparing their quantified requirements for UGS area and location; and (4) incorporating parameters to provide flexibility and accommodate various design scenarios and objectives. The advantages of this evaluation framework are demonstrated through two case studies: (1) the human wellbeing analysis based on spatial parameters in the framework shows sensitivity to site variations, including UGS quantity and distribution, population density, terrain, road context, height of void space, and more; (2) the simplified stormwater analysis effectively captures site variations represented by UGS quantity and distribution, building distribution, as well as terrain, providing recommendations for each UGS with different types and sizes of stormwater facilities. (3) With the features of spatial parameter evaluation, the framework is feasible to adjust relevant thresholds and include more parameters to respond to specific project needs. (4) By quantifying the two different requirements for UGS and comparing them, any UGS with high usage conflicts can be easily identified. By evaluating all proposed criteria for UGSs in the 3D model, designers can conveniently observe simulation and adjust design scenarios to address identified usage conflicts. Thus, the proposed evaluation framework in this thesis would be valuable in effectively supporting further multi-objective UGS design

    Quantifying non-exhaust emissions and the impact of hybrid and electric vehicles using combined measurement and modelling approaches

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    Road traffic is a significant emission source of urban particulate matter (PM). Due to the implementation of exhaust regulatory standards in the UK, PM emissions which arise from the wear of brakes, tyres and the road surface, together with the resuspension of road dust are now predicted to exceed tailpipe emissions. While a growing body of academic literature has developed in recent years, non-exhaust emissions (NEE) remain unregulated and largely understudied, and the impact of powertrain electrification on the vehicle fleet has not been quantified. Thus, the aim of this thesis is to improve our understanding of these important emission sources and to determine the impact of NEE on urban air pollution - both now, and in the future. A series of highly time-resolved atmospheric measurement campaigns has been undertaken at roadside and background locations to determine roadside traffic increments. These measurements provide a comprehensive dataset of traffic emissions in London, Birmingham and Manchester, incorporating locations with different vehicle mix and speed, during summer and winter periods. PM mass and elemental tracers have been used to estimate the contribution of NEE concentrations using a scaling factor approach. A novel CO2 dilution approach has been undertaken to determine average fleet emission factors (EFs), whilst the impact of electric vehicle regenerative braking has also been simulated. The results indicate that NEE concentrations and EFs are highly dependent upon meteorological conditions, traffic speed, traffic volume and vehicle class. Brake wear is the dominant source of road traffic PM emissions in congested environments, whilst for each emission source, heavy duty vehicles (HDVs) contribute an order of magnitude greater than light duty vehicles (LDVs). On the other hand, despite the predicted increase in mass, the regenerative braking simulations suggest that passenger vehicles under electric powertrains will reduce brake wear emissions by 65 – 95%. This reduction depends on the assessed drive cycle and vehicle class, highlighting the importance of driving style on future brake wear emissions. The EFs developed in this thesis have been combined with traffic forecasts to project total national emissions in the UK up to 2035 – and can be used to validate the national atmospheric emission inventory. To conclude, a number of recommendations have been made with respect to air quality measurement strategies and emission policies which are needed to further our understanding of NEE, and to reduce these traffic-related emissions. It is proposed that a multi-disciplinary study should be undertaken encompassing laboratory dynamometer testing, on-vehicle measurements and environmental atmospheric measurements.Open Acces

    Feature Papers in Compounds

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    This book represents a collection of contributions in the field of the synthesis and characterization of chemical compounds, natural products, chemical reactivity, and computational chemistry. Among its contents, the reader will find high-quality, peer-reviewed research and review articles that were published in the open access journal Compounds by members of the Editorial Board and the authors invited by the Editorial Office and Editor-in-Chief

    Measurement of the Environmental Impact of Materials

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    Throughout their life cycles—from production, usage, through to disposal—materials and products interact with the environment (water, soil, and air). At the same time, they are exposed to environmental influences and, through their emissions, have an impact on the environment, people, and health. Accelerated experimental testing processes can be used to predict the long-term environmental consequences of innovative products before these actually enter the environment. We are living in a material world. Building materials, geosynthetics, wooden toys, soil, nanomaterials, composites, wastes and more are research subjects examined by the authors of this book. The interactions of materials with the environment are manifold. Therefore, it is important to assess the environmental impact of these interactions. Some answers to how this task can be achieved are given in this Special Issue

    Extractable organics and colour in a bleached kraft mill effluent land application system and recipient ground waters

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    This thesis describes a study of the behaviour of extractable organics and colour in a land application system used to treat highly coloured, organic-rich, alkali extraction stage and foul condensate effluents from a traditional bleached kraft mill. The land application system comprised 44 unlined seepage basins, totalling 86 ha in area, into which approximately 10,000 m³ d⁻¹ effluent was loaded for approximately eight months of each year. The study aimed to determine (1) the effectiveness of the system for treating major effluent organics, including monoterpenes, fatty acids, resin acids, chlorophenolics, and colour, and (2) the effects of the system on organic contamination of sediments, aquifer materials, and ground waters. The study was carried out in four parts, investigating: (i) the behaviour of extractable organics and colour in the effluent drains and seepage basins; (ii) the penetration of extractable organics into the sediments beneath the seepage basins; (iii) the organic chemistry of shallow ground waters beneath the seepage system, and of deeper off-site ground waters; and (iv) behaviour of extractable organics and colour in laboratory soil-column simulating the land application process. In addition, a review of land application of pulp mill effluents was carried out, and analytical methods for determining extractable organics in effluents, sediments, and ground waters were developed. Concentrations of extractable organics and chlorophenolics were reduced by >95% over a 40 day period in the seepage basins. Removal rates decreased in the order fatty acids > chlorophenolics ≈ monoterpenes > resin acids. Resin acids underwent reductive and oxidative transformations, producing transient intermediates including 13-abietenoic acid and 13β-hydroxyabietanoic acid. A suite of relatively stable transformed species, dominated by the saturated compound abietanoic acid, remained in the seepage pond after 40 days. Colour removal over the same period was approximately 25%. High concentrations of effluent-derived extractable organics were found in surficial sediments beneath the seepage basins. Major compounds were resin acids, largely saturated species, and diterpene hydrocarbon transformation products. Diterpene hydrocarbons were dominated by retene, fichtelite, and dehydroabietin. Surficial sediments contained concentrations of total resin acids and diterpene hydrocarbons of up to 10,000 mg kg⁻¹. Concentrations dropped with depth, but high levels were found in discrete zones at depths of up to 5 m beneath the surface. This indicated that effluent movement was occurring through permeable conduits rather than via uniform infiltration through the soil, and was consistent with the fractured geology of the site. Ground waters taken from seven well clusters, sampling depths between 2 and 15 m beneath the seepage basins, contained elevated sodium and chloride concentrations (200-400 mg L⁻¹) and spatially variable colour levels (100-2000 CPU). Effluent-derived extractable organics were also found in variable concentrations. Major compounds were methyl-substituted 2-cyclopentenones, resin acids, and diterpene hydrocarbons. Resin acids and diterpene hydrocarbons were the generally dominant compound classes, concentrations totalling 20-2600 μg L⁻¹. Preliminary assessment of chlorophenolics found low levels, totalling 2-4 μg L⁻¹ in the most contaminated ground waters. The results indicated that contamination of shallow ground water was occurring, but the nature and level of this contamination was highly spatially variable. As found for the sediment studies, these findings were consistent with effluent infiltration through heterogeneous, fractured, sub-surface geology. The hydrogeology of the area was determined to be dominated by ground water movement through fractured zones in four major ignimbrite aquifers. Wells were placed at depths between 9 and 110 m, and at distances from immediately adjacent to 2.7 km from the seepage area to sample ground water from these zones. Contamination was found largely within the highly fractured, high flow zones of two of these units, the Marshall A and, to a lesser extent, the Marshall B ignimbrite aquifers. Concentrations of effluent-sourced extractable organics (largely resin acids and diterpene hydrocarbons) and colour were highest immediately beneath the seepage area, maximum concentrations of 110 μg L⁻¹ total resin acids and diterpene hydrocarbons, and 900 CPU colour being found. Concentrations dropped rapidly with distance from the ponds, decreasing by approximately 90% within about 100 m from the seepage area. There was evidence for retardation of organics relative to sodium and chloride in the off-site aquifers. Laboratory simulations of effluent infiltration through seepage site soils were carried out under two application regimes (permanently flooded, and flood-dry cycle) to determine the range of treatment possibilities occurring in the seepage system. Leachate chemistry was monitored over an approximately two year period, and soil extractives measured at the end of the study. Mass balance was used to estimate effluent treatment efficiency. The flood-dry (aerobic) application regime resulted in essentially compete degradative removal of extractable organics. Under the flooded (anaerobic) regime, extractable organic removal was limited for all constituents other than fatty acids, which were >90% removed. Resin acids were strongly retained by the soil, approximately 72% remaining in the soil at the end of the study. Approximately 25% was recovered in the leachate. Monoterpenes were highly mobile, moving rapidly through the soil. A relatively stable suite of transformed compounds was found in the leachates. Monoterpene removal was estimated to be approximately 55%. Under flooded conditions, transformation rather than degradative removal of extractable organics occurred. Colour intensification, rather than reduction, occurred at times in both application regimes. At the end of the study, colour removal in the flood-dry cycle regime was 2%, and in the flooded regime an increase of 51% was measured. In summary, the study found that the land application system resulted in large decreases (>95%) in the concentrations of extractable organics, but little overall treatment of effluent colour. Ground waters affected by effluent infiltration were highly variable in composition, but in general contained elevated colour levels, and moderate-to-low concentrations of extractable organics. Resin acids and diterpene hydrocarbons were the dominant class of extractable organics found in sediments and ground waters beneath the seepage system

    Investigating drivers of cyanobacterial blooms in Aotearoa – New Zealand lakes using sedimentary ancient DNA

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    Healthy lake ecosystems support biodiversity and human populations. They provide many ecosystem services such as water, food and energy. Lakes can be impacted by natural disturbances, but they are increasingly threatened by human-induced disturbances. Studies have shown that eutrophication and climate change often enhance cyanobacteria over other photosynthetic taxa. As cyanobacterial blooms are becoming more frequent and intense throughout the world, more lake systems are being investigated. In some cases there is not a clear link between eutrophication and cyanobacterial blooms. One such example is Lake Pounui (Wairarapa, New Zealand), which has little intensive agriculture in its catchment but water quality has degraded markedly in the last decade. The lake now experiences heavy cyanobacterial blooms every summer. This could be due to the presence of a non-native fish population, the European perch (Perca fluviatilis). This thesis examined the relationship between cyanobacterial blooms and perch introduction in New Zealand lakes, including a multi-trophic study in Lake Pounui. Perch were introduced c. 1870 in New Zealand but introduction records are patchy and sometimes non-existent. Moreover, most lake systems are not studied until they are already degraded. This thesis used a combination of traditional proxies (pollen, charcoal, pigments) and modern proxies (sedimentary ancient DNA, XRF scanning) from lake sediment cores to reconstruct lake ecology in pre-human times, after M¯aori settlement between the 13th to 15th century, and after European settlement from 1840 AD. Timelines and intensity of human impact were reconstructed with pollen, charcoal analysis, and sediment dating when possible. Cyanobacterial communities in six lakes were reconstructed through their sedimentary ancient DNA (sedaDNA) using metabarcoding and droplet digital PCR (ddPCR) in Chapter 2. Bloom-forming species were present in all lakes prior to human arrival; however their overall abundance was low. Total cyanobacteria abundance and richness increased in all lakes after European settlement but was very pronounced in four lakes, where bloom-forming taxa became dominant. The trends in cyanobacterial abundance from ddPCR were then compared to cyanobacterial pigments (canthaxanthin, echinenone, myxoxanthophyll and zeaxanthin) using highperformance liquid chromatography in Chapter 3, to assess the likelihood of the historical increase observed. Pigments / sedaDNA relationships were more consistent when all pigments were summed, which is likely due to differences in species composition across lakes. The positive correlations confirmed an increase in cyanobacterial biomass since European arrival. Due to patchy records for fish introduction, fish sedimentary DNA was compared to environmental DNA (eDNA) from water samples as a methodological check (Chapter 4) before applying this method to the sediment cores. This study was undertaken in three small and shallow lowland lakes by targeting perch and rudd (Scardinius erythrophthalmus). Fish DNA was evenly distributed across the whole lake except when the fish population was low. Samples collected from the sediment contained fish DNA more often than water samples in two out of the three small shallow lakes (including Lake Pounui). Sediment geochemistry probably impeded detection in the third lake. Perch sedaDNA was therefore used as an indication of fish presence in Lake Pounui for Chapter 5, which explored multitrophic changes in Lake Pounui over the last c. 1,000 years. In addition to pollen, charcoal, and 14C dating, XRF scanning was used to reconstruct mineralogic shifts from the catchment (Ti/inc, K/inc) and within the lake (inc/coh). Biological trends were reconstructed by targeting the sedaDNA of bacteria (16S rRNA), microeukaryotes (18S rRNA), metazoans (CO1), and macrophytes (rbcL, trnL). Complemented by historical records and studies, the data produced in this thesis indicated that the biggest changes in Lake Pounui happened after European settlement (c. 1845), with land clearance, perch introduction, climate change, and probable fertiliser application driving the degradation of the water quality in c. 180 years. This study revealed shifts in native communities (macrophytes, bacteria, oligochaete worms) and the appearance of new species (perch, macrophytes, freshwater nematodes) previously undocumented using sedaDNA. The results highlight just how complex yet fragile lake ecosystems can be and how little we still know about them. Sedimentary ancient DNA is a useful tool to study the insidious and long-lasting impact of nonnative species on freshwater ecosystems because it widens the range of species that can be studied. However, it needs to be complemented with other proxies. This thesis provides a framework to study fish DNA in small shallow lakes (Chapter 4). It can also inform future management and restoration strategies in lakes, especially in Lake Pounui, by retracing historical water quality (Chapter 2) and identifying taxa present prior to, during, and after lake degradation (Chapter 5)
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