The Operator form of 3H (3He) and its Spin Structure

An operator form of the 3N bound state is proposed. It consists of eight operators formed out of scalar products in relative momentum and spin vectors, which are applied on a pure 3N spin 1/2 state. Each of the operators is associated with a scalar function depending only on the magnitudes of the two relative momenta and the angle between them. The connection between the standard partial wave decomposition of the 3N bound state and the operator form is established, and the decomposition of these scalar function in terms of partial wave components and analytically known auxiliary functions is given. That newly established operator form of the 3N bound state exhibits the dominant angular and spin dependence analytically. The scalar functions are tabulated and can be downloaded. As an application the spin dependent nucleon momentum distribution in a polarized 3N bound state is calculated to illustrate the use of the new form of the 3N bound state.Comment: 21 pages, 1 table, 8 figures, revtex

A New Perspective on Path Integral Quantum Mechanics in Curved Space-Time

A fundamentally different approach to path integral quantum mechanics in curved space-time is presented, as compared to the standard approaches currently available in the literature. Within the context of scalar particle propagation in a locally curved background, such as described by Fermi or Riemann normal co-ordinates, this approach requires use of a constructed operator to rotate the initial, intermediate, and final position ket vectors onto their respective local tangent spaces, defined at each local time step along some arbitrary classical reference worldline. Local time translation is described using a quantum mechanical representation of Lie transport, that while strictly non-unitary in operator form, nevertheless correctly recovers the free-particle Lagrangian in curved space-time, along with new contributions. This propagator yields the prediction that all probability violating terms due to curvature contribute to a quantum violation of the weak equivalence principle, while the remaining terms that conserve probability also correspondingly satisfy the weak equivalence principle, at least to leading-order in the particle's Compton wavelength. Furthermore, this propagator possesses an overall curvature-dependent and gauge-invariant phase factor that can be interpreted as the gravitational Aharonov-Bohm effect and Berry's phase.Comment: 14 pages, 1 figure; major additions and revisions introduced; main conclusions are unchanged; new affiliation adde

Asymmetric recombination and electron spin relaxation in the semiclassical theory of radical pair reactions

We describe how the semiclassical theory of radical pair recombination reactions recently introduced by two of us [D. E. Manolopoulos and P. J. Hore, J. Chem. Phys. 139, 124106 (2013)] can be generalised to allow for different singlet and triplet recombination rates. This is a non-trivial generalisation because when the recombination rates are different the recombination process is dynamically coupled to the coherent electron spin dynamics of the radical pair. Furthermore, because the recombination operator is a two-electron operator, it is no longer sufficient simply to consider the two electrons as classical vectors: one has to consider the complete set of 16 two-electron spin operators as independent classical variables. The resulting semiclassical theory is first validated by comparison with exact quantum mechanical results for a model radical pair containing 12 nuclear spins. It is then used to shed light on the spin dynamics of a carotenoid-porphyrin-fullerene (CPF) triad containing considerably more nuclear spins which has recently been used to establish a 'proof of principle' for the operation of a chemical compass [K. Maeda et al., Nature 453, 387 (2008)]. We find in particular that the intriguing biphasic behaviour that has been observed in the effect of an Earth-strength magnetic field on the time-dependent survival probability of the photo-excited C+PF- radical pair arises from a delicate balance between its asymmetric recombination and the relaxation of the electron spin in the carotenoid radical