Dielectric-based Components and Methods for Terahertz Sensing

[ES] En el presente trabajo, se investigan algunos aspectos de la interacción de los materiales dieléctricos con ondas de THz. La banda de THz, que incluye las frecuencias de 100 GHz a 30 THz, ha despertado un gran interés sobre todo por su baja energía y su buena capacidad de penetración en materiales de uso diario como tejidos y plásticos. Las características peculiares de estas ondas permiten su aplicación en diversos campos tecnológicos, especialmente como herramientas científicas y para la inspección de control de calidad. Para avanzar en la aplicación práctica de la radiación THz, la presente tesis doctoral investigó varios caminos. En primer lugar, se trataron métodos alternativos de bajo coste para la fabricación de componentes pasivos de THz, centrándose en los polarizadores. El interés en el control de la polarización nace de la demanda de un mayor control sobre las características físicas de los haces de THz. Asimismo, se han investigado los polarizadores wire grid flexible basados en el efecto de absorción dicroica. Se han fabricado polarizadores con grafito y GaIn24,5 depositados en materiales ordinarios utilizados como sustratos (papel y polímeros como PVA y PVC). Mediante la colaboración con el grupo de investigación chino dirigido por el profesor Liu de la Universidad de Tsinghua, se investigaron procesos de fabricación alternativos. Todos los componentes se simularon mediante un simulador comercial basado en la técnica de integrales finitas FIT (CST Microwave Studio). En segundo lugar, se investigó el potencial de la técnica de fixed delay para la detección rápida de elementos homogéneos y transparentes con posible aplicación en la inspección de calidad industrial. En este esquema, la variación de corriente del haz de THz en un punto específico está relacionada con la variación de sus parámetros ópticos, por lo que se demostró la capacidad de detectar defectos, así como de estimar sus volúmenes bajo ciertas condiciones. Por último, un enfoque diferente para el beam profile basado en un slit dieléctrico fue evaluada como alternativa a los métodos convencionales utilizados en la región de THz y la óptica. Todas las mediciones, tanto la espectroscopia como el control de la polarización, se hicieron por medio de un sistema basado en fibra TDS-THz, con antenas fotoconductoras (PCA), tanto para la generación como para la detección de THz.[EN] In the present work, some aspects of the role of dielectric materials when interacting with THz waves were investigated. The THz bandgap, which covers the frequencies from 100 GHz to 30 THz, has aroused great interest mainly due to its low energy and its good penetration capacity in some materials of daily use such as fabrics and plastics. The peculiar features of terahertz waves enable their application in various technological fields, especially as scientific tools and for quality control inspection. To advance in the practical application of THz radiation, the present doctoral thesis researched several paths. Firstly, alternative low-cost methods for manufacturing THz passive components, in particular, THz polarizers was treated. The interest in polarization control is derived from the demand for greater control over the physical characteristics of THz beams. Flexible wire grid polarizers based on the dichroic absorption effect have been investigated. The polarizers have been manufactured using graphite and GaIn24.5 deployed on ordinary materials used as substrates (paper and polymers such as PVA and PVC). Through a collaboration undertaken with the Chinese research group led by Professor Liu at Tsinghua University, alternative manufacturing processes were researched. All components were simulated through a commercial simulator based on the FIT finite integrals technique (CST Microwave Studio). Secondly, the potential of the fixed delay technique was investigated for rapid sensing of homogeneous and transparent items with possible application to industrial quality inspection. In this scheme, the current variation of the THz beam at a specific point is related to the variation of its optical parameters, thus it was demonstrated the ability of the method in detecting voids as well as in roughly estimating their volumes under certain conditions. Finally, a different approach for beam profiling based on a dielectric slit aperture was evaluated, as an alternative to the conventional methods used in the THz region and optics All measurements, both spectroscopy and polarization control, were made by means of a TDS-THz fibre-based system, with photoconductive antennas (PCA), both for the generation and detection of THz.[CA] En el present treball, s'investiguen alguns aspectes del paper dels materials dielèctrics quan interactuen amb ones de THz. El bandgap de THz, que cobreix les freqüències de 100 GHz a 30 THz, ha despertat un gran interés principalment a causa de la seua baixa energia i la seua bona capacitat de penetració en alguns materials d'ús diari com els teixits i els plàstics. Les característiques peculiars de les ones de terahertz permeten la seua aplicació en diversos camps tecnològics, especialment com a eines científiques i per a la inspecció de control de qualitat. Per a avançar en l'aplicació pràctica de la radiació THz, la present tesi doctoral investiga diversos camins. En primer lloc, es s'han tractat mètodes alternatius de baix cost per a la fabricació de components passius de THz, centrant-se principalment en polaritzadors de THz. L'interés en el control de la polarització es deriva de la demanda d'un major control sobre les característiques físiques dels feixos de THz. Així mateix, s'han investigat els polaritzadors amb reixes de filferro flexible basats en l'efecte d'absorció dicroica. Els polaritzadors s'han fabricat utilitzant grafit i GaIn24,5 desplegats en materials ordinaris utilitzats com a substrats (paper i polímers com el PVA i el PVC). Mitjançant una col·laboració empresa amb el grup d'investigació xinés dirigit pel professor Liu de la Universitat de Tsinghua, es van investigar processos de fabricació alternatius. Tots els components es van simular mitjançant un simulador comercial basat en la tècnica d'integrals finites FIT (CST Microwave Studio). En segon lloc, s'ha investigat el potencial de la tècnica de retard fix per a la detecció ràpida d'elements homogenis i transparents amb possible aplicació a la inspecció de qualitat industrial. En aquest esquema, la variació actual del feix de THz en un punt específic està relacionada amb la variació dels seus paràmetres òptics, per la qual cosa es va demostrar la capacitat del mètode per a detectar els buits així com en l'estimació aproximada dels seus volums sota certes condicions. Finalment, un enfocament diferent per al perfil de feix basat en una obertura d'escletxa dielèctrica ha sigut avaluada, com a alternativa als mètodes convencionals utilitzats a la regió de THz i l'òptica.Tots els mesuraments, tant l'espectroscòpia com el control de la polarització, es van fer per mitjà d'un sistema basat en fibra TDS-THz, amb antenes fotoconductores (PCA), tant per a la generació com per a la detecció de THz.Colleoni, MPM. (2020). Dielectric-based Components and Methods for Terahertz Sensing [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/149569TESI

Development of sensors and non-destructive techniques to determine the performance of coatings in construction

The primary objective of this work was to examine and develop techniques for monitoring the degradation of Organically Coated Steel (OCS) in-situ. This included the detection of changes associated with the weathering to both the organic coating and metallic substrate. Initially, a review of current promising techniques was carried out however many were found to be unsuitable for this application and the adaptation of current techniques and the development of new techniques was considered. A brief concept investigation, based on initial testing and considerations, was used to determine a number of sensing techniques to examine. These included embedded, Resonant Frequency Identification (RFID), Magnetic Flux Leakage (MFL) and dielectric sensing. Each of these techniques were assessed for the application, prototyped, and tested against a range of samples to determine the accuracy and sensitivity of degradation detection provided. A range of poorly and highly durable coated samples were used in conjunction with accelerated weathering testing for this aim. Track based electronic printed sensors were presented as both a cut edge corrosion tracking and coating capacitance measurement method. While suffering somewhat from electrical paint compatibility issues both concepts showed merit in initial trials however the capacitive sensor ultimately proved insufficiently responsive to coating changes. The embedded, progressive failure-based, cut edge corrosion sensor was produced and tested in modern coating systems with moderate success. Novel applications of RFID and MLF techniques were considered and proved capable of detecting large changes in substrate condition due to significant corrosion. However, there was a lack of sufficient sensitivity when considering early-stage corrosion of durable modern OCS products. Finally, it was shown that a chipless antenna could be designed and optimised for novelly monitoring the changes to the dielectric properties of a paint layer due to degradation. However, ultimately this test, due to equipment requirements, lent itself more to lab testing than in-situ. Due to some of these limitations a different approach was considered in which the environmental factors influencing degradation were examined with the aim of relating these to performance across a building. It was observed that a combination of high humidity and the build-up of aggressive natural deposits contributed to high degradation rates in sheltered regions, such as building eaves, where microclimates were created. The build-up of deposits and their effect was presented as a key degradation accelerant during in-use service. A unique numerical simulation approach was developed to predict the natural washing, via rain impact and characteristics of the building analysed. This approach showed promise for determining areas unlikely to be naturally washed, and therefore subjected to a degradation accelerating, build-up of deposits. Given these understandings coated wetness sensors were considered as a realistic live-monitoring device capable of determining deposit build up and ultimately OCS lifetime

Techniques for In Situ Monitoring the Performance of Organic Coatings and Their Applicability to the Pre-Finished Steel Industry: A Review

A review is carried out in this paper into techniques that currently exist for, of have the potential to be used for, monitoring the performance of organic coating. Specific attention is paid to the applicability of each method to pre-finished steel used in the construction industry as these are rarely monitored in situ and their expected performance is often only estimated from lab-based accelerated corrosion testing. Monitoring could allow more accurate estimates of building cladding lifespan and required maintenance schedules; provide customers with active performance data; additionally, with a better understanding of performance, more appropriate coatings or coating weights could be selected for a construction project, offering economic benefits as part of smart building developments. An introduction to coatings, their use for corrosion protection, failure mechanisms, and relevant monitoring techniques is given before current assessment techniques are described in terms of their working principles. Examples of recent work are presented for the techniques that have been investigated for monitoring or directly relatable purposes. The review concludes that there are several good reasons why an optimum corrosion monitoring technology does not currently exist, however, promising research is emerging in the field of wireless and embedded sensor design which is providing optimistic results

Methodologies and Applications Review

Funding Information: The Authors acknowledge Fundação para a Ciência e a Tecnologia (FCT-MCTES) for its financial support via the project UIDB/00667/2020 (UNIDEMI). Pedro M. Ferreira also acknowledges FCT-MCTES for funding the PhD grant UI/BD/151055/2021. Publisher Copyright: © 2022 by the authors.Sensing Technology (ST) plays a key role in Structural Health-Monitoring (SHM) systems. ST focuses on developing sensors, sensory systems, or smart materials that monitor a wide variety of materials’ properties aiming to create smart structures and smart materials, using Embedded Sensors (ESs), and enabling continuous and permanent measurements of their structural integrity. The integration of ESs is limited to the processing technology used to embed the sensor due to its high-temperature sensitivity and the possibility of damage during its insertion into the structure. In addition, the technological process selection is dependent on the base material’s composition, which comprises either metallic or composite parts. The selection of smart sensors or the technology underlying them is fundamental to the monitoring mode. This paper presents a critical review of the fundaments and applications of sensing technologies for SHM systems employing ESs, focusing on their actual developments and innovation, as well as analysing the challenges that these technologies present, in order to build a path that allows for a connected world through distributed measurement systems.publishersversionpublishe

Terahertz response of microfluidic-jetted fabricated 3D flexible metamaterials

Conventional materials exhibit some restrictions on their electromagnetic properties. Especially in terahertz region, for example, materials that exhibit magnetic response are far less common in nature than materials that exhibit electric response. However, materials can be designed, namely artificial man-made metamaterials that exhibit electromagnetic properties that are not found in natural materials by adjusting, for example, the dielectric, magnetic or structural parameters of the constituent elements. This dissertation demonstrates the use of new fabrication techniques to construct metamaterials in THz range via a material deposition system. The metamaterials are fabricated by stacking alternative layers with conventional designs such as single ring- split ring resonators (SRR) and microstrips to form a 3D metamaterial structure. Conductive nano-particle Ag, Cu and semiconductor polymer fluids are used as structural mediums. The metamaterials are fabricated on polyimide substrate. Their flexible nature will be advantageous in future device innovations. In order to obtain electromagnetic resonance in the terahertz range, the dimensions of the single ring-SRR and microstrips are first approximated by analytical methods and then confirmed by numerical simulation. The fabricated metamaterials are then characterized in transmission mode using Time-domain THz Spectroscopy (THz-TDS) in the 0.1 to 2 THz range

Condition Monitoring Technologies for Synthetic Fiber Ropes - a Review

This paper presents a review of different condition monitoring technologies for fiber ropes. Specifically, it presents an overview of the articles and patents on the subject, ranging from the early 70’s up until today with the state of the art. Experimental results are also included and discussed in a conditionmonitoring context,where failuremechanisms and changes in physical parameters give improved insight into the degradation process of fiber ropes. From this review, it is found that automatic width measurement has received surprisingly little attention, and might be a future direction for the development of a continuous condition monitoring system for synthetic fiber ropes

Radio frequency non-destructive testing and evaluation of defects under insulation

PhD ThesisThe use of insulation such as paint coatings has grown rapidly over the past decades. However, defects and corrosion under insulation (CUI) still present challenges for current non-destructive testing and evaluation (NDT&E) techniques. One of such challenges is the large lift-off introduced by thick insulation layer. Inaccessibility due to insulation leads corrosion and defects to be undetected, which can lead to catastrophic failure. Furthermore, lift-off effects due to the insulation layers reduce the sensitivities. The limitations of existing NDT&E techniques heighten the need for novel approaches to the characterisation of corrosion and defects under insulation. This research project is conducted in collaboration with International Paint®, and a radio frequency non-destructive evaluation for monitoring structural condition is proposed. High frequency (HF) passive RFID in conjunction with microwave NDT is proposed for monitoring and imaging under insulation. The small-size, battery-free and cost-efficient nature of RFID makes it attractive for long-term condition monitoring. To overcome the limitations of RFID-based sensing system such as effective monitoring area and lift-off tolerance, microwave NDT is proposed for the imaging of larger areas under thick insulation layers. Experimental studies are carried out in conjunction with specially designed mild steel sample sets to demonstrate the detection capabilities of the proposed systems. The contributions of this research can be summarised as follows. Corrosion detection using HF passive RFID-based sensing and microwave NDT is demonstrated in experimental feasibility studies considering variance in surface roughness, conductivity and permeability. The lift-off effects introduced by insulation layers are reduced by applying feature extraction with principal component analysis and non-negative matrix factorisation. The problem of thick insulation layers is overcome by employing a linear sweep frequency with PCA to improve the sensitivity and resolution of microwave NDT-based imaging. Finally, the merits of microwave NDT are identified for imaging defects under thick insulation in a realistic test scenario. In conclusion, HF passive RFID can be adapted for long term corrosion monitoring of steel under insulation, but sensing area and lift-off tolerance are limited. In contrast, the microwave NDT&E has shown greater potential and capability for monitoring corrosion and defects under insulation