Interseismic quiescence and triggered slip of active normal faults of Kīlauea Volcano's south flank during 2001-2018

The mobile south flank of Kīlauea Volcano hosts two normal fault systems, the Koa'e fault system (KFS) and the Hilina fault system (HFS). In historical time, at least three M>6.5 earthquakes have occurred on the basal detachment of the Kīlauea Volcano's south flank, with the most recent being the 4 May 2018 M6.9 earthquake. Here we analyze kinematic Global Positioning System data collected from 2001 to 2017 and interferometric synthetic aperture radar data before, during, and after the 2018 M6.9 earthquake to determine the crustal motion across the HFS and KFS faults. Our results indicate that the HFS faults did not significantly slip during the interseismic period from 2007 to 2011. Despite its substantial magnitude, interferometric synthetic aperture radar (InSAR) data show that the 2018 M6.9 earthquake triggered subcentimeter level slip along sections of the previously mapped HFS branches. Up to 20 cm of offset occurred on what appears to be a newly formed (or previously unknown) fault near the eastern end of the HFS. During the 3 months following the M6.9 earthquake, up to ~30 cm of slip occurred along the KFS, which helps accommodate rapid large‐scale subsidence of Kīlauea's summit region as large volumes of summit reservoir magma fed the lower East Rift Zone eruption. The HFS appears to activate only in concert with large earthquakes on the basal detachment. The KFS, on the other hand, moves both seismically during small local earthquakes and aseismically in response to nearby earthquakes and caldera subsidence

Study of groundwater properties and behaviour using geospatial techniques

Groundwater contributes a significant proportion of the earth’s freshwater and is essential to sustain life on earth, but its availability in spatial and temporal dimensions is not uniform. With the advent of efficient pumps and rural electrification, global groundwater extraction increased from 312 km3/year in the 1960s to 800 km3/year in 2000s; approximately 70% of this extraction is used for agriculture. About half of domestic human water consumption in urban areas is from groundwater. The ever-increasing dependence on groundwater has led to its depletion across various parts of the world. This trend must be reversed to sustain the critical role of groundwater. Groundwater monitoring based on validated data can provide information that can guide decision making to decrease groundwater stress on local and global scales. This thesis aims to monitor spatio-temporal changes in groundwater and related phenomena (like land subsidence) using geospatial techniques like InSAR, GRACE, GIS, data analysis and data visualisation. The over-extraction or rebound of groundwater can lead to land deformation because of the change in effective stress of underground sediments. Groundwater-induced land movement can cause damage to property and resources, and hence it must be monitored for the safety and economics of a city. This thesis explores the suitability of Persistent Scatterer Interferometric Synthetic Aperture Radar (PSInSAR) to measure land deformation and different senor-software for InSAR processing. The groundwater quantity variation and resulting land deformation for London using InSAR and Gravity Recovery and Climate Experiment (GRACE) between 2002-2010 were analysed. Long-term, decreasing, complex, non-linear patterns in the spatial and temporal domains from both InSAR and GRACE datasets were observed. The land movement velocities varied from -6 to +6 mm/year, and their reliability was validated with observed GNSS data by conducting a two-sample t-test. The average groundwater loss estimated from GRACE was found to be 9.003 MCM/year. The results demonstrate that InSAR and GRACE complement each other and can be an excellent source of monitoring groundwater for hydrologists. Then groundwater induced subsidence for London and the National Capital Territory of Delhi (NCT-Delhi) between 2016 and 2020 were studied. The land movement velocities were found to vary between -24 mm/year to +24 mm/year for London and between -18 mm/year to +30 mm/year for NCT-Delhi. This land movement was compared with observed groundwater levels and spatio-temporal variation of groundwater. A 1-D mathematical model was used to quantify land deformation for a given change in groundwater level. It was broadly observed that when large volumes of groundwater are extracted, it leads to land subsidence, and when groundwater is recharged, surface uplift is witnessed. However the local geology, did play an important role in the extent of subsidence, which was considered in the mathematical model. The increased pressure on groundwater can cause spatio-temporal changes in its quality because of various atmospheric stimulations, varied geology, variation in subsurface mineralogy and factors controlling residence times. Moreover, the variation of groundwater quality is vital for the sustainable management and safety of groundwater. Thus, the variation in groundwater quality is analysed from observed data for London between 2000 and 2020. The data samples were used from 500 wells in the London basin, and the data is provided in the free open access domain by Environment Agency. The overall groundwater in London was found to be dominant magnesium bicarbonate type which typically represents shallow fresh groundwater, and spatio-temporal variations of hardness, sodium, and dissolved oxygen (DO) were also studied. Significant variations in the range of each constituent were found, which was attributed to variation in the geology of the London Palaeogene aquifers and anthropogenic activities. All the case studies help better understand the phenomenon of spatio-temporal variation in groundwater behaviour and associated land deformation for urban cities. The research presented in this thesis can be used to determine whether groundwater is available and suitable for its intended purpose, discover pollutants, examine any spatio-temporal variations, and monitor land subsidence

Impact of Etna’s volcanic emission on major ions and trace elements composition of the atmospheric deposition

Mt. Etna, on the eastern coast of Sicily (Italy), is one of the most active volcanoes on the planet and it is widely recognized as a big source of volcanic gases (e.g., CO2 and SO2), halogens, and a lot of trace elements, to the atmosphere in the Mediterranean region. Especially during eruptive periods, Etna’s emissions can be dispersed over long distances and cover wide areas. A group of trace elements has been recently brought to attention for their possible environmental and human health impacts, the Technology-critical elements. The current knowledge about their geochemical cycles is still scarce, nevertheless, recent studies (Brugnone et al., 2020) evidenced a contribution from the volcanic activity for some of them (Te, Tl, and REE). In 2021, in the framework of the research project “Pianeta Dinamico”, by INGV, a network of 10 bulk collectors was implemented to collect, monthly, atmospheric deposition samples. Four of these collectors are located on the flanks of Mt. Etna, other two are in the urban area of Catania and three are in the industrial area of Priolo, all most of the time downwind of the main craters. The last one, close to Cesarò (Nebrodi Regional Park), represents the regional background. The research aims to produce a database on major ions and trace element compositions of the bulk deposition and here we report the values of the main physical-chemical parameters and the deposition fluxes of major ions and trace elements from the first year of research. The pH ranged from 3.1 to 7.7, with a mean value of 5.6, in samples from the Etna area, while it ranged between 5.2 and 7.6, with a mean value of 6.4, in samples from the other study areas. The EC showed values ranging from 5 to 1032 μS cm-1, with a mean value of 65 μS cm-1. The most abundant ions were Cl- and SO42- for anions, Na+ and Ca+ for cations, whose mean deposition fluxes, considering all sampling sites, were 16.6, 6.8, 8.4, and 6.0 mg m-2 d, respectively. The highest deposition fluxes of volcanic refractory elements, such as Al, Fe, and Ti, were measured in the Etna’s sites, with mean values of 948, 464, and 34.3 μg m-2 d-1, respectively, higher than those detected in the other sampling sites, further away from the volcanic source (26.2, 12.4, 0.5 μg m-2 d-1, respectively). The same trend was also observed for volatile elements of prevailing volcanic origin, such as Tl (0.49 μg m-2 d-1), Te (0.07 μg m-2 d-1), As (0.95 μg m-2 d-1), Se (1.92 μg m-2 d-1), and Cd (0.39 μg m-2 d-1). Our preliminary results show that, close to a volcanic area, volcanic emissions must be considered among the major contributors of ions and trace elements to the atmosphere. Their deposition may significantly impact the pedosphere, hydrosphere, and biosphere and directly or indirectly human health

EVOLUTION OF THE SUBCONTINENTAL LITHOSPHERE DURING MESOZOIC TETHYAN RIFTING: CONSTRAINTS FROM THE EXTERNAL LIGURIAN MANTLE SECTION (NORTHERN APENNINE, ITALY)

Our study is focussed on mantle bodies from the External Ligurian ophiolites, within the Monte Gavi and Monte Sant'Agostino areas. Here, two distinct pyroxenite-bearing mantle sections were recognized, mainly based on their plagioclase-facies evolution. The Monte Gavi mantle section is nearly undeformed and records reactive melt infiltration under plagioclase-facies conditions. This process involved both peridotites (clinopyroxene-poor lherzolites) and enclosed spinel pyroxenite layers, and occurred at 0.7–0.8 GPa. In the Monte Gavi peridotites and pyroxenites, the spinel-facies clinopyroxene was replaced by Ca-rich plagioclase and new orthopyroxene, typically associated with secondary clinopyroxene. The reactive melt migration caused increase of TiO2 contents in relict clinopyroxene and spinel, with the latter also recording a Cr2O3 increase. In the Monte Gavi peridotites and pyroxenites, geothermometers based on slowly diffusing elements (REE and Y) record high temperature conditions (1200-1250 °C) related to the melt infiltration event, followed by subsolidus cooling until ca. 900°C. The Monte Sant'Agostino mantle section is characterized by widespread ductile shearing with no evidence of melt infiltration. The deformation recorded by the Monte Sant'Agostino peridotites (clinopyroxene-rich lherzolites) occurred at 750–800 °C and 0.3–0.6 GPa, leading to protomylonitic to ultramylonitic textures with extreme grain size reduction (10–50 μm). Compared to the peridotites, the enclosed pyroxenite layers gave higher temperature-pressure estimates for the plagioclase-facies re-equilibration (870–930 °C and 0.8–0.9 GPa). We propose that the earlier plagioclase crystallization in the pyroxenites enhanced strain localization and formation of mylonite shear zones in the entire mantle section. We subdivide the subcontinental mantle section from the External Ligurian ophiolites into three distinct domains, developed in response to the rifting evolution that ultimately formed a Middle Jurassic ocean-continent transition: (1) a spinel tectonite domain, characterized by subsolidus static formation of plagioclase, i.e. the Suvero mantle section (Hidas et al., 2020), (2) a plagioclase mylonite domain experiencing melt-absent deformation and (3) a nearly undeformed domain that underwent reactive melt infiltration under plagioclase-facies conditions, exemplified by the the Monte Sant'Agostino and the Monte Gavi mantle sections, respectively. We relate mantle domains (1) and (2) to a rifting-driven uplift in the late Triassic accommodated by large-scale shear zones consisting of anhydrous plagioclase mylonites. Hidas K., Borghini G., Tommasi A., Zanetti A. & Rampone E. 2021. Interplay between melt infiltration and deformation in the deep lithospheric mantle (External Liguride ophiolite, North Italy). Lithos 380-381, 105855

Impact of geogenic degassing on C-isotopic composition of dissolved carbon in karst systems of Greece

The Earth C-cycle is complex, where endogenic and exogenic sources are interconnected, operating in a multiple spatial and temporal scale (Lee et al., 2019). Non-volcanic CO2 degassing from active tectonic structures is one of the less defined components of this cycle (Frondini et al., 2019). Carbon mass-balance (Chiodini et al., 2000) is a useful tool to quantify the geogenic carbon output from regional karst hydrosystems. This approach has been demonstrated for central Italy and may be valid also for Greece, due to the similar geodynamic settings. Deep degassing in Greece has been ascertained mainly at hydrothermal and volcanic areas, but the impact of geogenic CO2 released by active tectonic areas has not yet been quantified. The main aim of this research is to investigate the possible deep degassing through the big karst aquifers of Greece. Since 2016, 156 karst springs were sampled along most of the Greek territory. To discriminate the sources of carbon, the analysis of the isotopic composition of carbon was carried out. δ13CTDIC values vary from -16.61 to -0.91‰ and can be subdivided into two groups characterized by (a) low δ13CTDIC, and (b) intermediate to high δ13CTDIC with a threshold value of -6.55‰. The composition of the first group can be related to the mixing of organic-derived CO2 and the dissolution of marine carbonates. Springs of the second group, mostly located close to Quaternary volcanic areas, are linked to possible carbon input from deep sources

Land Surface Monitoring Based on Satellite Imagery

This book focuses attention on significant novel approaches developed to monitor land surface by exploiting satellite data in the infrared and visible ranges. Unlike in situ measurements, satellite data provide global coverage and higher temporal resolution, with very accurate retrievals of land parameters. This is fundamental in the study of climate change and global warming. The authors offer an overview of different methodologies to retrieve land surface parameters— evapotranspiration, emissivity contrast and water deficit indices, land subsidence, leaf area index, vegetation height, and crop coefficient—all of which play a significant role in the study of land cover, land use, monitoring of vegetation and soil water stress, as well as early warning and detection of forest fires and drought