Behavior of Space Charge in Polyimide and the Influence on Power Semiconductor Device Reliability

Polyimide is widely used in film form as a passivation material for power semiconductor devices such as Si, SiC, and GaN. The magnitude of the electric field at the edge termination area of these semiconductor devices is becoming higher due to the increase of operational voltage and/or demand for shrinking the edge termination area to increase device active area. Hence, it is concerned that the accumulation of space charge in the encapsulation and passivation material may affect the insulation performance of these devices, for example, the degradation of withstand voltage due to distortion of the internal electric field caused by space charge accumulation. To design space charge resistance of semiconductor devices, it is important to understand the space charge behavior in polyimide films with a thickness of several to several tens of micrometers. This chapter addresses practical implementation, specifications, and issues on space charge in polyimide insulation on power semiconductor devices focusing on the space charge measurements in thin polyimide films using the latest developed LIMM method and DC conductivity measurements

Interpretation and Regulation of Electronic Defects in IGZO TFTs Through Materials & Processes

The recent rise in the market for consumer electronics has fueled extensive research in the field of display. Thin-Film Transistors (TFTs) are used as active matrix switching devices for flat panel displays such as LCD and OLED. The following investigation involves an amorphous metal-oxide semiconductor that has the potential for improved performance over current technology, while maintaining high manufacturability. Indium-Gallium-Zinc-Oxide (IGZO) is a semiconductor material which is at the onset of commercialization. The low-temperature large-area deposition compatibility of IGZO makes it an attractive technology from a manufacturing standpoint, with an electron mobility that is 10 times higher than current amorphous silicon technology. The stability of IGZO TFTs continues to be a challenge due to the presence of defect states and problems associated with interface passivation. The goal of this dissertation is to further the understanding of the role of defect states in IGZO, and investigate materials and processes needed to regulate defects to the level at which the associated influence on device operation is controlled. The relationships between processes associated with IGZO TFT operation including IGZO sputter deposition, annealing conditions and back-channel passivation are established through process experimentation, materials analysis, electrical characterization, and modeling of electronic properties and transistor behavior. Each of these components has been essential in formulating and testing several hypotheses on the mechanisms involved, and directing efforts towards achieving the goal. Key accomplishments and quantified results are summarized as follows: • XPS analysis identified differences in oxygen vacancies in samples before and after oxidizing ambient annealing at 400 °C, showing a drop in relative integrated area of the O 1s peak from 32% to 19%, which experimentally translates to over a thousand fold decrease in the channel free electron concentration. • Transport behavior at cryogenic temperatures identified variable range hopping as the electron transport mechanism at temperature below 130 K, whereas at temperature greater than 130 K, the current vs temperature response followed an Arrhenius relationship consistent with extended state transport. • Refinement of an IGZO material model for TCAD simulation, which consists of oxygen vacancy donors providing an integrated space charge concentration NVO = +5e15 cm-3, and acceptor-like band-tail states with a total integrated ionized concentration of NTA = -2e18 cm-3. An intrinsic electron mobility was established to be Un = 12.7 cm2/V∙s. • A SPICE-compatible 2D on-state operation model for IGZO TFTs has been developed which includes the integration of drain-impressed deionization of band-tail states and results in a 2D modification of free channel charge. The model provides an exceptional match to measured data and TCAD simulation, with model parameters for channel mobility (Uch = 12 cm2/V∙s) and threshold voltage (VT = 0.14 V) having a close match to TCAD analogs. • TCAD material and device models for bottom-gate and double-gate TFT configurations have been developed which depict the role of defect states on device operation, as well as provide insight and support of a presented hypothesis on DIBL like device behavior associated with back-channel interface trap inhomogeneity. This phenomenon has been named Trap Associated Barrier Lowering (TABL). • A process integration scheme has been developed that includes IGZO back-channel passivation with PECVD SiO2, furnace annealing in O2 at 400 °C, and a thin capping layer of alumina deposited via atomic layer deposition. This process supports device stability when subjected to negative and positive bias stress conditions, and thermal stability up to 140 °C. It also enables TFT operation at short channel lengths (Leff ~ 3 µm) with steep subthreshold characteristics (SS ~ 120 mV/dec). The details of these contributions in the interpretation and regulation of electronic defect states in IGZO TFTs is presented, along with the support of device characteristics that are among the best reported in the literature. Additional material on a complementary technology which utilizes flash-lamp annealing of amorphous silicon will also be described. Flash-Lamp Annealed Polycrystalline Silicon (FLAPS) has realized n-channel and p-channel TFTs with promising results, and may provide an option for future applications with the highest performance demands. IGZO is rapidly emerging as the candidate to replace a-Si:H and address the performance needs of display products produced by large panel manufacturing

Developing ultrasensitive and CMOS compatible ISFETs in the BEOL of industrial UTBB FDSOI transistors

Le marché des capteurs a récemment connu une croissance spectaculaire alimentée par l'application remarquable de capteurs dans l'électronique de consommation, l'industrie de l'automatisation, les appareils portables, le secteur automobile et l'internet des objets de plus en plus adopté. La technologie avancée des complementary metal oxide semiconductor (CMOS), les technologies de nano et de micro-fabrication et les plateformes de synthèse de matériaux innovantes sont également des moteurs du développement incroyable de l'industrie des capteurs. Ces progrès ont permis la réalisation de capteurs dotés de nombreuses caractéristiques telles que la précision accrue, les dimensions miniaturisées, l’intégrabilité, la production de masse, le coût très réduit et le temps de réponse rapide. Les ion-sensitive field-effect transistors (ISFETs) sont des capteurs à l'état solide (bio) chimiques, destinés à la détection des ions H+ (pH), Na+ et K+. Malgré cela, la commercialisation des ISFETs est encore à ses balbutiements, après près de cinq décennies de recherche et développement. Cela est dû principalement à la sensibilité limitée, à la controverse sur l'utilisation de l'électrode de référence pour le fonctionnement des ISFETs et à des problèmes de stabilité. Dans cette thèse, les ISFETs ultrasensibles et compatibles CMOS sont intégrés dans le BEOL des transistors UTBB FDSOI standard. Un circuit diviseur capacitif est utilisé pour polariser la grille d’avant afin d'assurer des performances stables du capteur. En exploitant la fonction d’amplification intrinsèque fournie par les transistors UTBB FDSOI, nous avons présenté des ISFET ultra sensibles. L'amplification découle du fort couplage électrostatique entre la grille avant et la grille arrière du FDSOI et des capacités asymétriques des deux grilles. Un changement de tension au niveau de la grille avant apparaît sur la grille arrière sous la forme d'un décalage amplifié de la tension. L'amplification, représentée par le facteur de couplage (γ), est égale au rapport de la capacité de l'oxyde de grille et de la capacité de le buried oxide (BOX). Par conséquent, en fonctionnalisant la détection du pH sur la grille avant pour les dispositifs FDSOI, la modification du potentiel de surface sur la grille avant est détectée par la grille arrière et amplifiée du facteur de couplage (γ), donnant lieu à un capteur chimique à l'état solide à sensibilité ultra-élevée. L'intégration de la fonctionnalité de détection a été réalisée en back end of line (BEOL), ce qui offre les avantages d'une fiabilité et d'une durée de vie accrues du capteur, d'une compatibilité avec le processus CMOS standard et d'une possibilité d'intégration d'un circuit diviseur capacitif. Le fonctionnement des MOSFETs, sans une polarisation appropriée de la grille avant, les rend vulnérables aux effets de grilles flottantes indésirables. Le circuit diviseur capacitif résout ce problème en polarisant la grille avant tout enmaintenant la fonctionnalité de détection sur la même grille par un couplage capacitif au métal commun du BEOL. Par conséquent, le potentiel au niveau du métal BEOL est une somme pondérée du potentiel de surface au niveau de la grille de détection et de la polarisation appliquée au niveau de la grille de contrôle. Le capteur proposé est modélisé et simulé à l'aide de TCAD-Sentaurus. Un modèle mathématique complet a été développé. Il fournit la réponse du capteur en fonction du pH de la solution (entrée du capteur) et des paramètres de conception du circuit diviseur capacitif et du transistor UTBB FDSOI. Dans ce cas, des résultats cohérents ont été obtenus des travaux de modélisation et de simulation, avec une sensibilité attendue de 780 mV / pH correspondant à un film de détection ayant une réponse de Nernst. La modélisation et la simulation du capteur proposé ont également été validées par une fabrication et une caractérisation du capteur de pH à grille étendue avec validation de son concept. Ces capteurs ont été développés par un traitement séparé du composant de détection de pH, qui est connecté électriquement au transistor uniquement lors de la caractérisation du capteur. Ceci permet une réalisation plus rapide et plus simple du capteur sans avoir besoin de masques et de motifs par lithographie. Les capteurs à grille étendue ont présenté une sensibilité de 475 mV/pH, ce qui est supérieur aux ISFET de faible puissance de l'état de l’art. Enfin, l’intégration de la fonctionnalité de détection directement dans le BEOL des dispositifs FDSOI UTBB a été poursuivie. Une sensibilité expérimentale de 730 mV/pH a été obtenue, ce qui confirme le modèle mathématique et la réponse simulée. Cette valeur est 12 fois supérieure à la limite de Nernst et supérieure aux capteurs de l'état de l’art. Les capteurs sont également évalués pour la stabilité, la résolution, l'hystérésis et la dérive dans lesquels d'excellentes performances sont démontrées. Une nouvelle architecture de détection du pH est également démontrée avec succès, dans laquelle la détection est fonctionnalisée au niveau de la diode de protection de la grille plutôt que de la grille avant des dispositifs UTBB FDSOI. La commutation de courant abrupte, aussi basse que 9 mV/decade, pourrait potentiellement augmenter la sensibilité de polarisation fixée à 6,6 decade/pH. Nous avons démontré expérimentalement une sensibilité de 1,25 decade/pH supérieure à la sensibilité reportée à l’état de l’art.Abstract: The sensor market has recently seen a dramatic growth fueled by the remarkable application of sensors in the consumer electronics, automation industry, wearable devices, the automotive sector, and in the increasingly adopted internet of things (IoT). The advanced complementary metal oxide semiconductor (CMOS) technology, the nano and micro fabrication technologies, and the innovative material synthesis platforms are also driving forces for the incredible development of the sensor industry. These technological advancements have enabled realization of sensors with characteristic features of increased accuracy, miniaturized dimension, integrability, volume production, highly reduced cost, and fast response time. Ion-sensitive field-effect transistors (ISFETs) are solid state (bio)chemical sensors, for pH (H+), Na+, K+ ion detection, that are equipped with the promise of the highly aspired features of CMOS devices. Despite this, the commercialization of ISFETs is still at the stage of infancy after nearly five decades of research and development. This is due mainly to the limited sensitivity, the controversy over the use of the reference electrode for ISFET operation, and because of stability issues. In this thesis, ultrasensitive and CMOS compatible ISFETs are integrated in the back end of line (BEOL) of standard UTBB FDSOI transistors. A capacitive divider circuit is employed for biasing the front gate for stable performance of the sensor. Exploiting the intrinsic amplification feature provided by UTBB FDSOI transistors, we demonstrated ultrahigh sensitive ISFETs. The amplification arises from the strong electrostatic coupling between the front gate and the back gate of the FDSOI, and the asymmetric capacitances of the two gates. A change in voltage at the front gate appears at the back gate as an amplified shift in voltage. The amplification, referred to as the coupling factor (γ), is equal to the ratio of the gate oxide capacitance and the buried oxide (BOX) capacitance. Therefore, functionalizing the pH sensing at the front gate of FDSOI devices, the change in surface potential at the front gate is detected at the back gate amplified by the coupling factor (γ), giving rise to an ultrahigh-sensitive solid state chemical sensor. Integration of the sensing functionality was made in the BEOL which gives the benefits of increased reliability and life time of the sensor, compatibility with the standard CMOS process, and possibility for embedding a capacitive divider circuit. Operation of the MOSFETs without a proper front gate bias makes them vulnerable for undesired floating body effects. The capacitive divider circuit addresses these issues by biasing the front gate simultaneously with the sensing functionality at the same gate through capacitive coupling to a common BEOL metal. Therefore, the potential at the BEOL metal would be a weighted sum of the surface potential at the sensing gate and the applied bias at the control gate. The proposed sensor is modeled and simulated using TCAD-Sentaurus. A complete mathematical model is developed which provides the output of the sensor as a function of the solution pH (input to the sensor), and the design parameters of the capacitive divider circuit and the UTBB FDSOI transistor. In that case, consistent results have been obtained from the modeling and simulation works, with an expected sensitivity of 780 mV/pH corresponding to a sensing film having Nernst response. The modeling and simulation of the proposed sensor was further validated by a proof of concept extended gate pH sensor fabrication and characterization. These sensors were developed by a separated processing of just the pH sensing component, which is electrically connected to the transistor only during characterization of the sensor. This provides faster and simpler realization of the sensor without the need for masks and patterning by lithography. The extended gate sensors showed 475 mV/pH sensitivity which is superior to state of the art low power ISFETs. Finally, integration of the sensing functionality directly in the BEOL of the UTBB FDSOI devices was pursued. An experimental sensitivity of 730 mV/pH is obtained which is consistent with the mathematical model and the simulated response. This is more than 12-times higher than the Nernst limit, and superior to state of the art sensors. Sensors are also evaluated for stability, resolution, hysteresis, and drift in which excellent performances are demonstrated. A novel pH sensing architecture is also successfully demonstrated in which the detection is functionalized at the gate protection diode rather than the front gate of UTBB FDSOI devices. The abrupt current switching, as low as 9 mV/decade, has the potential to increase the fixed bias sensitivity to 6.6 decade/pH. We experimentally demonstrated a sensitivity of 1.25 decade/pH which is superior to the state of the art sensitivity

Low-temperature amorphous oxide semiconductors for thin-film transistors and memristors: physical insights and applications

While amorphous oxides semiconductors (AOS), namely InGaZnO (IGZO), have found market application in the display industry, their disruptive properties permit to envisage for more advanced concepts such as System-on-Panel (SoP) in which AOS devices could be used for addressing (and readout) of sensors and displays, for communication, and even for memory as oxide memristors are candidates for the next-generation memories. This work concerns the application of AOS for these applications considering the low thermal budgets (< 180 °C) required for flexible, low cost and alternative substrates. For maintaining low driving voltages, a sputtered multicomponent/multi-layered high-κ dielectric (Ta2O5+SiO2) was developed for low temperature IGZO TFTs which permitted high performance without sacrificing reliability and stability. Devices’ performance under temperature was investigated and the bias and temperature dependent mobility was modelled and included in TCAD simulation. Even for IGZO compositions yielding very high thermal activation, circuit topologies for counteracting both this and the bias stress effect were suggested. Channel length scaling of the devices was investigated, showing that operation for radio frequency identification (RFID) can be achieved without significant performance deterioration from short channel effects, which are attenuated by the high-κ dielectric, as is shown in TCAD simulation. The applicability of these devices in SoP is then exemplified by suggesting a large area flexible radiation sensing system with on-chip clock-generation, sensor matrix addressing and signal read-out, performed by the IGZO TFTs. Application for paper electronics was also shown, in which TCAD simulation was used to investigate on the unconventional floating gate structure. AOS memristors are also presented, with two distinct operation modes that could be envisaged for data storage or for synaptic applications. Employing typical TFT methodologies and materials, these are ease to integrate in oxide SoP architectures

Interpretation and Physical Modeling of Electronic Transport and Defect States in IGZO Thin-Film Transistors

This work is a comprehensive study on the interpretation and modeling of electronic transport behavior and defect states in indium-gallium-zinc-oxide (IGZO) TFTs. Key studies have focused on advancing the state of IGZO TFTs by addressing several challenges in device stability, scaling, and device modeling. These studies have provided new insight on the associated mechanisms and have resulted in the realization of scaled thin-film transistors that exhibit excellent electrical performance and stability. This work has demonstrated the ability to scale the conventional inverted staggered IGZO TFT down to one micron channel length, with excellent on-state and off-state performance where the VT ≈1 V, µeff =12 cm2/Vs, Ileak ≤ 10-12 A/µm and SS ≈ 160 mV/dec. The working source/drain electrodes are direct metal contact regions to the IGZO, which requires several microns of gate overlap to provide ohmic behavior with minimal series resistance and ensure tolerance to overlay error. New results utilizing ion implantation for self-aligned source/drain regions present a path towards submicron channel length. This strategy offers a reduction in channel length as well as parasitic capacitance, which translates to improvement in RC delay and associated voltage losses due to charge-sharing. The realization of self-aligned TFTs using boron ion implantation for selective activation was introduced in a first-time report of boron-doped IGZO. Cryogenic measurements made on long-channel devices has revealed temperature-dependent behavior that is not explained by existing TCAD models employed for defect states and carrier mobility. A completely new device model using Silvaco Atlas has been established which properly accounts for the role of donor-like oxygen vacancy defects, acceptor-like band-tail states, acceptor-like interface traps, and a temperature-dependent intrinsic channel mobility. The developed model demonstrates a remarkable match to transfer characteristics measured at T = 150 K to room temperature. A power-law fit for the µch = f(T) relationship, which resembles 〖μ ~ T〗^((+3)⁄2) behavior consistent with ionized defect scattering. The mobility model is expressly independent of carrier concentration, without dependence on the applied gate bias. The device model is consistent with a compact model developed for circuit simulation (SPICE) that has been recently refined to include on-state and off-state operation. While IGZO is the only AOS technology mature enough for commercialization, the effective electron channel mobility µeff ~ 10 cm2/Vs presents a performance limitation. Other candidate AOS materials which have higher reported channel mobility values have also been investigated; specifically, indium-tungsten-oxide (IWO) and indium-gallium-tin-oxide (ITGO). These investigations serve as preliminary studies; device characteristics support the claims of high channel mobility; however the influence of defect states clearly indicates the need for further process development. The advancements realized in IGZO TFTs in this work will serve as a foundation for these alternative AOS materials

Silicon- and Graphene-based FETs for THz technology

[EN] This Thesis focuses on the study of the response to Terahertz (THz) electromagnetic radiation of different silicon substrate-compatible FETs. Strained-Si MODFETs, state-of- the-art FinFETs and graphene-FETs were studied. The first part of this thesis is devoted to present the results of an experimental and theoretical study of strained-Si MODFETs. These transistors are built by epitaxy of relaxed-SiGe on a conventional Si wafer to permit the fabrication of a strained-Si electron channel to obtain a high-mobility electron gas. Room temperature detection under excitation of 0.15 and 0.3 THz as well as sensitivity to the polarization of incoming radiations were demonstrated. A two-dimensional hydrodynamic-model was developed to conduct TCAD simulations to understand and predict the response of the transistors. Both experimental data and TCAD results were in good agreement demonstrating both the potential of TCAD as a tool for the design of future new THz devices and the excellent performance of strained-Si MODFETs as THz detectors (75 V/W and 0.06 nW/Hz0.5). The second part of the Thesis reports on an experimental study on the THz behavior of modern silicon FinFETs at room temperature. Silicon FinFETs were characterized in the frequency range 0.14-0.44 THz. The results obtained in this study show the potential of these devices as THz detectors in terms of their excellent Responsivity and NEP figures (0.66 kV/W and 0.05 nW/Hz0.5). Finally, a large part of the Thesis is devoted to the fabrication and characterization of Graphene-based FETs. A novel transfer technique and an in-house-developed setup were implemented in the Nanotechnology Clean Room of the USAL and described in detail in this Thesis. The newly developed transfer technique enables to encapsulate a graphene layer between two flakes of h-BN. Raman measurements confirmed the quality of the fabricated graphene heterostructures and, thus, the excellent properties of encapsulated graphene. The asymmetric dual grating gate graphene FET (ADGG-GFET) concept was introduced as an efficient way to improve the graphene response to THz radiation. High quality ADGG-GFETs were fabricated and characterized under THz radiation. DC measurements confirmed the high quality of graphene heterostructures as it was shown on Raman measurements. A clear THz detection was found for both 0.15 THz and 0.3 THz at 4K when the device was voltage biased either using the back or the top gate of the G-FET. Room temperature THz detection was demonstrated at 0.3 THz using the ADGG-GFET. The device shows a Responsivity and NEP around 2.2 mA/W and 0.04 nW/Hz0.5 respectively at respectively at 4K. It was demonstrated the practical use of the studied devices for inspection of hidden objects by using the in-house developed THz imaging system

Approche industrielle aux boîtes quantiques dans des dispositifs de silicium sur isolant complètement déplété pour applications en information quantique

La mise en oeuvre des qubits de spin électronique à base de boîtes quantiques réalisés en utilisant une technologie avancée de métal-oxyde-semiconducteur complémentaire (en anglais: CMOS ou Complementary Metal-Oxide-Semiconductor) fonctionnant à des températures cryogéniques permet d’envisager la fabrication industrielle reproductible et à haut rendement de systèmes de qubits de spin à grande échelle. Le développement d’une architecture de boîtes quantiques à base de silicium fabriquées en utilisant exclusivement des techniques de fabrication industrielle CMOS constitue une étape majeure dans cette direction. Dans cette thèse, le potentiel de la technologie UTBB (en anglais: Ultra-Thin Body and Buried oxide) silicium sur isolant complétement déplété (en anglais: FD-SOI ou Fully Depleted Silicon-On-Insulator) 28 nm de STMicroelectronics (Crolles, France) a été étudié pour la mise en oeuvre de boîtes quantiques bien définies, capables de réaliser des systèmes de qubit de spin. Dans ce contexte, des mesures d’effet Hall ont été réalisées sur des microstructures FD-SOI à 4.2 K afin de déterminer la qualité du noeud technologique pour les applications de boîtes quantiques. De plus, un flot du processus d’intégration, optimisé pour la mise en oeuvre de dispositifs quantiques utilisant exclusivement des méthodes de fonderie de silicium pour la production de masse est présenté, en se concentrant sur la réduction des risques de fabrication et des délais d’exécution globaux. Enfin, deux géométries différentes de dispositifs à boîtes quantiques FD-SOI de 28nm ont été conçues et leurs performances ont été étudiées à 1.4 K. Dans le cadre d’une collaboration entre Nanoacademic Technologies, Institut quantique et STMicroelectronics, un modèle QTCAD (en anglais: Quantum Technology Computer-Aided Design) en 3D a été développé pour la modélisation de dispositifs à boîtes quantiques FD-SOI. Ainsi, en complément de la caractérisation expérimentale des structures de test via des mesures de transport et de spectroscopie de blocage de Coulomb, leur performance est modélisée et analysée à l’aide du logiciel QTCAD. Les résultats présentés ici démontrent les avantages de la technologie FD-SOI par rapport à d’autres approches pour les applications de calcul quantique, ainsi que les limites identifiées du noeud 28 nm dans ce contexte. Ce travail ouvre la voie à la mise en oeuvre des nouvelles générations de dispositifs à boîtes quantiques FD-SOI basées sur des noeuds technologiques inférieurs.Abstract: Electron spin qubits based on quantum dots implemented using advanced Complementary Metal-Oxide-Semiconductor (CMOS) technology functional at cryogenic temperatures promise to enable reproducible high-yield industrial manufacturing of large-scale spin qubit systems. A milestone in this direction is to develop a silicon-based quantum dot structure fabricated using exclusively CMOS industrial manufacturing techniques. In this thesis, the potential of the industry-standard process 28 nm Ultra-Thin Body and Buried oxide (UTBB) Fully Depleted Silicon-On-Insulator (FD-SOI) technology of STMicroelectronics (Crolles, France) was investigated for the implementation of well-defined quantum dots capable to realize spin qubit systems. In this context, Hall effect measurements were performed on FD-SOI microstructures at 4.2 K to determine the quality of the technology node for quantum dot applications. Moreover, an optimized integration process flow for the implementation of quantum devices, using exclusively mass-production silicon-foundry methods is presented, focusing on reducing manufacturing risks and overall turnaround times. Finally, two different geometries of 28 nm FD-SOI quantum dot devices were conceived, and their performance was studied at 1.4 K. In the framework of a collaboration between Nanoacademic Technologies, Institut quantique, and STMicroelectronics, a 3D Quantum Technology Computer-Aided Design (QTCAD) model was developed for FD-SOI quantum dot device modeling. Therefore, along with the experimental characterization of the test structures via transport and Coulomb blockade spectroscopy measurements, their performance is modeled and analyzed using the QTCAD software. The results reported here demonstrate the advantages of the FD-SOI technology over other approaches for quantum computing applications, as well as the identified limitations of the 28 nm node in this context. This work paves the way for the implementation of the next generations of FD-SOI quantum dot devices based on lower technology nodes

Poly(ethylenedioxythiophene) based electronic devices for sensor applications

Organic electronic devices, based on Poly (3,4-ethylenedioxythiophene)-Poly (styrene sulfonic acid) (PEDOT-PSS) as the active layer for sensor applications, have been studied. Two sets of sensors have been developed. In one case, sensors consisting of PEDOT-PSS resistors have been realized and demonstrated for soil moisture monitoring. The resistor model for the soil moisture sensor enables the sensor device to be fabricated at low cost and easily tested with a simple structure. Unlike the large dimension device used in Time Domain Reflectometry (TDR), the sensors are small and are capable of capturing microscale behavior of moisture in soil which is useful for geological and geotechnical engineering applications. The Field Effect Transistors (FETs) based on PEDOT-PSS and GOx have been developed for a glucose sensing application. The sensitivity of the developed FET-based sensors is enhanced by selecting the channel as the active sensing region as compared with the previously reported devices which use the gate as the active sensing region. This also allows the devices to be designed by a simple and cost-effective means, unlike other complex platform designs for polymer-based sensor devices. PEDOT-PSS based sensors showed higher sensitivity and reversible electrical properties when compared to early versions of sensors fabricated using polymer electrolytes which showed irreversible change in the electrical properties when exposed to high moisture content. The output characteristics, which is the change in electrical sheet resistance of the PEDOT-PSS film versus the percentage change in relative humidity (%RH), show that the conductivity of the film decreases when it is exposed to increasing levels of moisture content. The change in the output resistance of the developed PEDOT-PSS based sensor device was observed to be from 2.5 MΩ to 4.0 MΩ when exposed to soil samples (e.g. Buckshot Clay, CH) with 15–35 % change in gravimetric water content. The FET-based glucose sensor using PEDOT-PSS and GOx as the channel materials, is designed and developed with the capability of precise, fast, and wide sensing range of measurement compared to that of traditional glucose sensors, which are costly and operate on a complex electrochemical based principle. The fabrication and characteristics testing steps of the present glucose sensor are also simpler in comparison to other glucose sensors, which use electrochemical cells for measurements. In the present device, GOx was immobilized on PEDOT-PSS conducting polymer film using a simple cost effective spin-coating technique. A linear increase in the FET drain current was observed, which was resulted from the increase in glucose concentration. The sensitivity of the glucose sensor was determined to be 0.3 Ampere per 1 mg/ml of glucose concentration. A linear range of response was found from 0.2 to 3 mg/ml of glucose, with a response time of 10–20 s. The results indicated that the reported FET-based glucose sensor retains the enzyme bioactivity and can be applied as a glucose biosensor. Moreover, the glucose sensor presented in this dissertation has displayed a reasonable level of sensitivity, repeatability, and stability. The evaluated range of glucose detection shows that the developed biosensor can be used to detect glucose concentration for normal and diabetic patients. This finding also opens a potential pathway for further development of novel biosensor devices

Advanced Photovoltaic Devices Enabled by Lattice-Mismatched Epitaxy

Thin-film III-V semiconductor-based photovoltaic (PV) devices, whose light conversion efficiency is primarily limited by the minority carrier lifetimes, are commonly designed to minimize the formation of crystalline defects (threading dislocations or, in extreme cases, fractures) that can occur, in particular, due to a mismatch in lattice constants of the epitaxial substrate and of the active film. At the same time, heteroepitaxy using Si or metal foils instead of costly III-V substrates is a pathway to enabling low-cost thin-film III-V-based PV and associated devices, yet it requires to either use metamorphic buffers or lateral confinement either by substrate patterning or by growing high aspect ratio structures. Mismatched epitaxy can be used for high-efficiency durable III-V space PV systems by incorporation of properly engineered strained quantum confined structures into the solar cells that can enable bandgap engineering and enhanced radiation tolerance. One of the major topics covered in this work is optical and optoelectronic modeling and physics of the triple-junction solar cell featuring planar Si middle sub-cell and GaAs0.73P0.27 and InAs0.85P0.15 periodic nanowire (NW) top and bottom sub-cells, respectively. In particular, the dimensions of the NW arrays that would enable near-unity broad-band absorption for maximum generated current were identified. For the top cell, the planarized array dimensions corresponding to maximum generated current and current matching with the underlying Si sub-cell were found to be 350 nm for NW diameter and 450 – 500 nm for NW spacing. For the GaAs0.73P0.27, resonant coupling was the main factor driving the absorption, yet addressing the coupling of IR light in the transmission mode in the InAs0.85P0.15 nanoscale arrays was challenging and unique. Given the nature of the Si and bottom NW interface, the designs of high refractive index encapsulation materials and conformal reflectors were proposed to enable the use of thin NWs (300 – 400 nm) for sufficient IR absorption. A novel co-simulation tool combining RSoft DiffractMOD® and Sentaurus Device® was established and utilized to design the p-i-n 3D junction and thin conformal GaP passivation coating for maximum GaAs0.73P0.27 NW sub-cell efficiency (16.5%) mainly impacted by the carrier surface annihilation. Development of a highly efficient GaAs solar cell enhanced with InxGa1-xAs/GaAsyP1-y quantum wells (QWs) is also demonstrated as one of the key parts of the dissertation. The optimizations including design of GaAsP strain balancing that would support efficient thermal (here, 17 nm-thick GaAs0.90P0.10 for 9.2 nm-thick In0.10Ga0.90As QWs) and/or tunneling (4.9 nm-thick GaAs0.68P0.32) carrier escape out of the QW while maintaining a consistent morphology of the QW layers in extended QW superlattices were performed using the principles of strain energy minimization and by tuning the growth parameters. The fundamental open-circuit voltage (V¬oc) restraints in radiative and non-radiative recombination-limited regimes in the QW solar cells were studied for a variety of InxGa1-xAs compositions (x=6%, 8%, 10%, and 14%) and number of QWs using spectroscopic and dark current analysis and modeling. Additionally, the design and use of distributed Bragg reflectors for targeted up to 90% QW absorption enhancement is demonstrated resulting in an absolute QW solar cell efficiency increase by 0.4% due to nearly doubled current from the QWs and 0.1% enhancement relatively to the optically-thick baseline device with no QWs

Nanodot-based organic memory devices

In this study, resistor-type, diode-type, and transistor-type organic memory devices were investigated, aiming at the low-cost plastic integrated circuit applications. A series of solution-processing techniques including spin-coating, inkjet printing, and self-assembly were employed to fabricate these devices. The organic resistive memory device is based on a novel molecular complex film composed of tetracyanoquinodimethane (TCNQ) and a soluble methanofullerene derivative [6,6]-phenyl C61-butyric acid methyl ester (PCBM). It has an Al/molecules/Al sandwich structure. The molecular layer was formed by spin-coating technique instead of expensive vacuum deposition method. The current-voltage characteristics show that the device switches from the initial \u27low\u27 conduction state to \u27high\u27 conduction state upon application of external electric field at room temperature and return to \u27low\u27 conduction state when a high current pulse is applied. The on/off ratio is over 106. Each state has been found to remain stable for more than five months, even after the external electric field is removed. The PCBM nanodots wrapped by TCNQ molecules can form potential wells for charge trapping, and are believed to be responsible for the memory effects. A rewritable diode memory device was achieved in an improved configuration, i.e., ITO-PEDOT:PSS-PCBM/TCNQ-Al, where a semiconductor polymer PEDOT:PSS is used to form p+-N heterojunction with PCBM/TCNQ. It exhibits a diode characteristic (low conductive) before switching to a high-conductive Poole-Frenkel regime upon applying a positive external bias to ITO. The on/off ratio at +1.0 V is up to 105. Simulation results from Taurus-Medici are in qualitative agreement with the experimental results and the proposed charge storage model. The transistor-type memory device is fabricated on a heavily doped n-type silicon (n+-Si) substrate with a 100 nm thick thermally-grown oxide layer. The n+-Si serves as the gate electrode, while the oxide layer functions as the control gate dielectric. Gold nanoparticles as the charge storage units are deposited on the substrate by electrostatic self-assembly method. A self-assembled multilayer of polyelectrolytes, together with a thin spin-coated poly(4-vinyl phenol) layer, covers the gold nanoparticles and separates them from the poly(3-hexyl thiophene) channel. Conducting polymer PEDOT:PSS is inkjet printed to form the source/drain electrodes. The device exhibits significant hysteresis behavior in its Ids-Vgs characteristics. The charge storage in gold nanodots (diameter = 16 nm) was confirmed by comparing with devices having no gold nanoparticles, although the effects of interfacial traps may be also significant. The data retention time of the transistor memory is about 60 seconds, which needs to be further improved. It appears that this is the first demonstration of memory effects in an organic transistor caused by charge storage in metal nanodots in the gate dielectric. Therefore, the approach reported in this work offers a new direction to make low-cost organic transistor memories