Accident Scenarios Caused by Lightning Impact on Atmospheric Storage Tanks

In recent years, severe natural events raised the concern for the so-called NaTech (natural-technological) accident scenarios: technological accidents caused by the impact of a natural event on an industrial facility or infrastructure. Severe scenarios typical of the process industry, as fires, explosions, toxic releases, and water pollution were reported as the consequence of natural events in industrial areas. The historical analysis of accidental scenarios triggered by lightning shows that the impact of a lightning on an atmospheric storage tank might be the initiating event of a severe accident. The analysis of past accident evidences that several alternative damage mechanisms and accident scenarios may follow lightning impact. Although lightning hazard is well known and is usually considered in the risk analysis of chemical and process plants, well accepted quantitative procedures to assess the contribution of accidents triggered by lightning to industrial risk are still lacking. In particular, the approaches to the assessment of accident scenarios following lightning strike are mostly based on expert judgment. In the present study, a detailed methodology is presented for the assessment of quantified event trees following lightning impact on an atmospheric tank. Different damage mechanisms have been considered in order to assess the frequencies of loss of containment due to lightning strikes. The results were used in a case study to assess the overall risk due to lightning impact scenarios in typical lay-outs of tank farms of oil refineries.JRC.G.6-Security technology assessmen

Accident scenarios caused by lightning impact on atmospheric storage tanks

In recent years, severe natural events raised the concern for the so-called NaTech (natural-technological) accident scenarios: Technological accidents caused by the impact of a natural event on an industrial facility or infrastructure. Severe scenarios typical of the process industry, as fires, explosions, toxic releases, and water pollution were reported as the consequence of natural events in industrial areas. The historical analysis of accidental scenarios triggered by lightning shows that the impact of a lightning on an atmospheric storage tank might be the initiating event of a severe accident. The analysis of past accident evidences that several alternative damage mechanisms and accident scenarios may follow lightning impact. Although lightning hazard is well known and is usually considered in the risk analysis of chemical and process plants, well accepted quantitative procedures to assess the contribution of accidents triggered by lightning to industrial risk are still lacking. In particular, the approaches to the assessment of accident scenarios following lightning strike are mostly based on expert judgment. In the present study, a detailed methodology is presented for the assessment of quantified event trees following lightning impact on an atmospheric tank. Different damage mechanisms have been considered in order to assess the frequencies of loss of containment due to lightning strikes. The results were used in a case study to assess the overall risk due to lightning impact scenarios in typical lay-outs of tank farms of oil refineries. Copyright © 2013, AIDIC Servizi S.r.l

Preparation of Wax from Waste Plastic

The aim of the present work address the issue of recycling of plastic by thermal pyrolysis. In this study PP waste has been converted to PP wax. The process was carried out in a semi-batch reactor with various temperature range of 350-450 °C and the different time range of 50-120 min. The waxes from pyrolysis of PP was obtained and the effect of temperature and time on product yield has been studied. The maximum yield of 59% was obtained at optimum conditions of 450 °C and 75 min. Further, the obtained product at optimum conditions has been carried out for its physical and chemical analysis. From the physical analysis studies it observed that the penetration degree of wax ranging from 0.0 – 13.3 mm, and the melting point of PP wax is observed at an optimum condition is 122 °C. As a consequence of the chemical analysis like FTIR of PP wax shows that most of the functional group are aliphatic in nature. Which was also confirmed through GCMS analysis, especially the highest of compounds are aliphatic hydrocarbons and very few of them are carbonyl and aromatics in nature. The utmost 74% of Cyclopentane, 2-propenyl is observed in PP wax. However, from 1HNMR studies it was proved that the obtained compounds were highly branched hydrocarbons. From the above result it can be proved that the wax obtained from PP pyrolysis can be used for industry and domestic purpose

Alternative sweetener from curculigo fruits

This study gives an overview on the advantages of Curculigo Latifolia as an alternative sweetener and a health product. The purpose of this research is to provide another option to the people who suffer from diabetes. In this research, Curculigo Latifolia was chosen, due to its unique properties and widely known species in Malaysia. In order to obtain the sweet protein from the fruit, it must go through a couple of procedures. First we harvested the fruits from the Curculigo trees that grow wildly in the garden. Next, the Curculigo fruits were dried in the oven at 50 0C for 3 days. Finally, the dried fruits were blended in order to get a fine powder. Curculin is a sweet protein with a taste-modifying activity of converting sourness to sweetness. The curculin content from the sample shown are directly proportional to the mass of the Curculigo fine powder. While the FTIR result shows that the sample spectrum at peak 1634 cm–1 contains secondary amines. At peak 3307 cm–1 contains alkynes

Environmental Risk Analysis: Problems and Perspectives in Different Countries

The authors discuss various industrial accidents, which have led to growing concerns about the potential hazards and risks involved in chemical process industries

Environmental, human health and socio-economic effects of cement powders: The multicriteria analysis as decisional methodology

The attention to sustainability-related issues has grown fast in recent decades. The experience gained with these themes reveals the importance of considering this topic in the construction industry, which represents an important sector throughout the world. This work consists on conducting a multicriteria analysis of four cement powders, with the objective of calculating and analysing the environmental, human health and socio-economic effects of their production processes. The economic, technical, environmental and safety performances of the examined powders result from official, both internal and public, documents prepared by the producers. The Analytic Hierarchy Process permitted to consider several indicators (i.e., environmental, human health related and socio-economic parameters) and to conduct comprehensive and unbiased analyses which gave the best, most sustainable cement powder. As assumed in this study, the contribution of each considered parameter to the overall sustainability has a different incidence, therefore the procedure could be used to support on-going sustainability efforts under different conditions. The results also prove that it is not appropriate to regard only one parameter to identify the ‘best’ cement powder, but several impact categories should be considered and analysed if there is an interest for pursuing different, often conflicting interests

Working in it, through it, and among it all day. Chrome Dust at J & J White of Rutherglen, 1893-1967

Article examining working conditions at J & J White of Rutherglen from 1893-1967

Study on fouling behaviour of ultrafiltration and nanofiltration during purification of different organic matter polluted wastewaters

The boundary flux concept is a profitable tool to analyse fouling issues in membrane processes. The boundary flux value separates an operating region characterized by reversible fouling formation from irreversible one. Boundary flux values are not constant, but function of time, as calculated by the sub-boundary fouling rate value. The knowledge of both parameters may fully describe the membrane performances in sub-boundary operating regimes. Many times, for wastewater purification purposes, ultrafiltration and nanofiltration membranes are employed to treat different wastewater streams. This appears to be feasible from both technical and economical point of view many times. Whereas initial productivity and selectivity to reach the desired purification targets are generally guaranteed, key to reach process feasibility is that the membrane must resist to fouling issues, with a limited reduction of the performances as a function of time. In other words, longevity of the membranes must be that high to minimise their substitution and, consequently, operating (consumable) costs for the replacement. In this work, after a brief introduction to the boundary flux concept, for many different wastewater, the boundary flux and sub-boundary fouling rate values of different microfiltration and ultrafiltration membranes will be discussed and compared. By this approach, it will be possible to separate those systems where the use membranes for their treatment results successfully from those that represent a challenge (from a technical and/or economic point of view). This will depend sensibly of the feedstock characteristics and, in detail, on the particle size of the suspended matter and guidelines for process designers will be discussed. In most cases, it will be shown that membranes appear to perform very well, making this technology very interesting for many case studies

Developments in the Safety Science Domain and in Safety Management From the 1970s Till the 1979 Near Disaster at Three Mile Island

Objective: What has been the influence of general management schools and safety research into causes of accidents and disasters on managing safety from 1970 till 1979? Method: The study was limited to original articles and documents, written in English or Dutch from the period under concern. For the Netherlands, the professional journal De Veiligheid (Safety) has been consulted. Results and conclusions: Dominant management approaches started with 1) the classical management starting from the 19th century, with scientific management from the start of the 20st century as a main component. During the interwar period 2) behavioural management started, based on behaviourism, followed by 3) quantitative management from the Second World War onwards. After the war 4) modern management became important. A company was seen as an open system, interacting with an external environment with external stakeholders. These schools management were not exclusive, but have existed in the period together. Early 20th century, the U.S. 'Safety First' movement was the starting point of this knowledge development on managing safety, with cost reduction and production efficiency as key drivers. Psychological models and metaphors explained accidents from ‘unsafe acts’. And safety was managed with training and selection of reckless workers, all in line with scientific management. Supported by behavioural management, this approach remained dominant for many years, even long after World War II. Influenced by quantitative management, potential and actual disasters after the war led to two approaches; loss prevention (up-scaling process industry) and reliability engineering (inherently dangerous processes in the aerospace and nuclear industries). The distinction between process safety and occupational safety became clear after the war, and the two developed into relatively independent domains. In occupational safety in the 1970s human errors thought to be symptoms of mismanagement. The term ‘safety management’ was introduced in scientific safety literature as well as concepts as loose, and tightly coupled processes, organizational culture, incubation of a disaster and mechanisms blinding organizations for portents of disaster scenarios. Loss prevention remained technically oriented. Till 1979 there was no clear relation with safety management. Reliability engineering, based on systems theory did have that relation with the MORT technique as a management audit. The Netherlands mainly followed Anglo-Saxon developments. Late 1970s, following international safety symposia in The Hague and Delft, independent research started in The Netherland