1,568 research outputs found
Long-range Ni/Mn structural order in epitaxial double perovskite La2NiMnO6 thin films
We report and compare the structural, magnetic, and optical properties of
ordered La2NiMnO6 thin films and its disordered LaNi0.5Mn0.5O3 counterpart. An
x-ray diffraction study reveals that the B-site Ni/Mn ordering induces
additional XRD reflections as the crystal symmetry is transformed from a
pseudocubic perovskite unit cell in the disordered phase to a monoclinic form
with larger lattice parameters for the ordered phase. Polarized Raman
spectroscopy studies reveal that the ordered samples are characterized by
additional phonon excitations that are absent in the disordered phase. The
appearance of these additional phonon excitations is interpreted as the
clearest signature of Brillouin zone folding as a result of the long-range
Ni/Mn ordering in La2NiMnO6. Both ordered and disordered materials display a
single ferromagnetic-to-paramagnetic transition. The ordered films display also
a saturation magnetization close to 4.8 mB/f.u. and a transition temperature
(FM-TC) around 270 K, while the disordered ones have only a 3.7 mB/f.u.
saturation magnetization and a FM-TC around 138 K. The differences in their
magnetic behaviours are understood based on the distinct local electronic
configurations of their Ni/Mn cations.Comment: 15 pages, 5 fig
A radical approach to promote multiferroic coupling in double perovskites
Double perovskites provide a unique opportunity to induce and control
multiferroic behaviors in oxide systems. The appealing possibility to design
materials with a strong coupling between the magnetization and the polarization
fields may be achieved in this family since these magnetic insulators can
present structural self-ordering in the appropriate growth conditions. We have
studied the functional properties of La2CoMnO6 and Bi2CoMnO6 epitaxial thin
films grown by pulsed laser deposition. Cation-ordered La2CoMnO6 films display
a magnetic Curie temperature of 250 K while cation-disordered Bi2CoMnO6 films
present ferromagnetism up to ~ 800 K. Such high transition temperature for
magnetic ordering can be further tuned by varying the strain in the films
indicating an important contribution from the structural characteristics of the
materials. Our approach might be generalized for other oxide systems. At this
end, our results are compared with other multiferroic systems. The roles of
various cations, their arrangements and structural effects are further
discussed.Comment: 12 pages, 5 fig
Phase formation, phonon behavior, and magnetic properties of novel ferromagnetic La3BAlMnO9 (B = Co or Ni) triple perovskites
In the quest for novel magnetoelectric materials, we have grown, stabilized
and explored the properties of La3BAlMnO9 (B = Co or Mn) thin films. In this
paper, we report the influence of the growth parameters that promote B/Al/Mn
ordering in the pseudo-cubic unit cell and their likely influence on the
magnetic and multiferroic properties. The temperature dependence of the
magnetization shows that La3CoAlMnO9 is ferromagnetic up to 190 K while
La3NiAlMnO9 shows a TC of 130 K. The behavior of these films are compared and
contrasted with related La2BMnO6 double perovskites. It is observed that the
insertion of AlO6 octahedra between CoO6 and MnO6 suppresses significantly the
strength of the superexchange interaction, spin-phonon and spin-polar coupling.Comment: 13 pages, 3 fig
Investigation of phonon behavior in Pr2NiMnO6 by micro-Raman spectroscopy
The temperature dependence of phonon excitations and the presence of spin
phonon coupling in polycrystalline Pr2NiMnO6 samples were studied using
micro-Raman spectroscopy and magnetometry. Magnetic properties show a single
ferromagnetic-to-paramagnetic transition at 228 K and a saturation
magnetization close to 4.95 \muB/f.u.. Three distinct Raman modes at 657, 642,
and 511 cm-1 are observed. The phonon excitations show a clear hardening due to
anharmonicity from 300 K down to 10 K. Further, temperature dependence of the
657 cm-1 mode shows only a small softening. This reflects the presence of a
relatively weak spin-phonon coupling in Pr2NiMnO6 contrary to other double
perovskites previously studied.Comment: 10 pages, 4 fig
Orbital fluctuations in the VO perovskites
The properties of Mott insulators with orbital degrees of freedom are
described by spin-orbital superexchange models, which provide a theoretical
framework for understanding their magnetic and optical properties. We introduce
such a model derived for configuration of V ions in
the VO perovskites, =Lu,Yb,,La, and demonstrate that
orbital fluctuations along the axis are responsible for the
huge magnetic and optical anisotropies observed in the almost perfectly cubic
compound LaVO. We argue that the GdFeO distortion and the large
difference in entropy of -AF and -AF phases is responsible for the second
magnetic transition observed at in YVO. Next we address the
variation of orbital and magnetic transition temperature, and
, in the VO perovskites, after extending the spin-orbital model
by the crystal-field and the orbital interactions which arise from the
GdFeO and Jahn-Teller distortions of the VO octahedra. We further find
that the orthorhombic distortion which increases from LaVO to LuVO
plays a crucial role by controlling the orbital fluctuations, and via the
modified orbital correlations influences the onset of both magnetic and orbital
order.Comment: 25 pages, 10 figure
Electronic structure of Fe and magnetism in the double perovskites CaFeReO and BaFeReO
The Fe electronic structure and magnetism in (i) monoclinic CaFeReO
with a metal-insulator transition at K and (ii) quasi-cubic
half-metallic BaFeReO ceramic double perovskites are probed by soft
x-ray absorption spectroscopy (XAS) and magnetic circular dichroism (XMCD).
These materials show distinct Fe XAS and XMCD spectra, which are
primarily associated with their different average Fe oxidation states (close to
Fe for CaFeReO and intermediate between Fe and Fe
for BaFeReO) despite being related by an isoelectronic
(Ca/Ba) substitution. For CaFeReO, the powder-averaged Fe
spin moment along the field direction ( T), as probed by the XMCD
experiment, is strongly reduced in comparison with the spontaneous Fe moment
previously obtained by neutron diffraction, consistent with a scenario where
the magnetic moments are constrained to remain within an easy plane. For
T, the unsaturated XMCD signal is reduced below consistent with a
magnetic transition to an easy-axis state that further reduces the
powder-averaged magnetization in the field direction. For BaFeReO, the
field-aligned Fe spins are larger than for CaFeReO ( T) and the
temperature dependence of the Fe magnetic moment is consistent with the
magnetic ordering transition at K. Our results illustrate the
dramatic influence of the specific spin-orbital configuration of Re
electrons on the Fe local magnetism of these Fe/Re double perovskites.Comment: 7 pages, 3 figure
Charge and orbital order in transition metal oxides
A short introduction to the complex phenomena encountered in transition metal
oxides with either charge or orbital or joint charge-and-orbital order, usually
accompanied by magnetic order, is presented. It is argued that all the types of
above ordered phases in these systems follow from strong Coulomb interactions
as a result of certain compromise between competing instabilities towards
various types of magnetic order and optimize the gain of kinetic energy in
doped systems. This competition provides a natural explanation of the stripe
order observed in doped cuprates, nickelates and manganites. In the undoped
correlated insulators with orbital degrees of freedom the orbital order
stabilizes particular types of anisotropic magnetic phases, and we contrast the
case of decoupled spin and orbital degrees of freedom in the manganites with
entangled spin-orbital states which decide about certain rather exotic
phenomena observed in the perovskite vanadates at finite temperature. Examples
of successful concepts in the theoretical approaches to these complex systems
are given and some open problems of current interest are indicated.Comment: 20 pages, no figure
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