Dynamic Monte Carlo Simulations of Anisotropic Colloids

We put forward a simple procedure for extracting dynamical information from Monte Carlo simulations, by appropriate matching of the short-time diffusion tensor with its infinite-dilution limit counterpart, which is supposed to be known. This approach --discarding hydrodynamics interactions-- first allows us to improve the efficiency of previous Dynamic Monte Carlo algorithms for spherical Brownian particles. In a second step, we address the case of anisotropic colloids with orientational degrees of freedom. As an illustration, we present a detailed study of the dynamics of thin platelets, with emphasis on long-time diffusion and orientational correlations.Comment: 12 pages, 9 figure

Multiparticle Reactions with Spatial Anisotropy

We study the effect of anisotropic diffusion on the one-dimensional annihilation reaction kA->inert with partial reaction probabilities when hard-core particles meet in groups of k nearest neighbors. Based on scaling arguments, mean field approaches and random walk considerations we argue that the spatial anisotropy introduces no appreciable changes as compared to the isotropic case. Our conjectures are supported by numerical simulations for slow reaction rates, for k=2 and 4.Comment: nine pages, plain Te

Dynamics of elastically strained islands in presence of an anisotropic surface energy

The equilibrium solutions and coarsening dynamics of strained semi-conductor islands are investigated analytically and numerically. We develop an analytical model to study the effect of surface energy anisotropy on the dynamics coarsening of islands. We propose a simple model to explain the effect of this anisotropy on the coarsening time. We find that the anisotropy slows down the coarsening. This effect is rationalised using a quasi-analytical description of the island profile

Anisotropic 2D diffusive expansion of ultra-cold atoms in a disordered potential

We study the horizontal expansion of vertically confined ultra-cold atoms in the presence of disorder. Vertical confinement allows us to realize a situation with a few coupled harmonic oscillator quantum states. The disordered potential is created by an optical speckle at an angle of 30{\deg} with respect to the horizontal plane, resulting in an effective anisotropy of the correlation lengths of a factor of 2 in that plane. We observe diffusion leading to non-Gaussian density profiles. Diffusion coefficients, extracted from the experimental results, show anisotropy and strong energy dependence, in agreement with numerical calculations

Spectrum of slow and super-slow (picosecond to nanosecond) water dynamics around organic and biological solutes

Water dynamics in the solvation shell of solutes plays a very important role in the interaction of biomolecules and in chemical reaction dynamics. However, a selective spectroscopic study of the solvation shell is difficult because of the interference of the solute dynamics. Here we report on the observation of heavily slowed down water dynamics in the solvation shell of different solutes by measuring the low-frequency spectrum of solvation water, free from the contribution of the solute. A slowdown factor of ~50 is observed even for relatively low concentrations of the solute. We go on to show that the effect can be generalized to different solutes including proteins