Integrated Micro Fuel Processor And Flow Delivery Infrastructure

Apparatus for transporting a fluid, atomizers, reactors, integrated fuel processing apparatus, combinations thereof, methods of atomizing reactants, methods of moving fluids, methods of reverse-flow in a reactor, and combinations thereof, are provided. One exemplary apparatus for transporting a fluid, among others, includes: a channel for receiving a fluid; a sensor for determining an internal condition of the fluid in the channel; and a channel actuator in communication with the sensor for changing a cross-sectional area of the channel based on the internal condition, wherein the change in cross-sectional area controls a parameter selected from a pressure and a fluid flow.Georgia Tech Research Corporatio

Applications of hydrogenation and dehydrogenation on noble metal catalysts

Hydrogenation and dehydrogenation on Pd- and Pt- catalysts are encountered in many industrial hydrocarbon processes. The present work considers the development of catalysts and their kinetic modeling along a general and rigorous approach. The first part deals with the kinetics of selective hydrogenation, more particularly of the C3 cut of a thermal cracking unit for olefins production. The kinetics of the gas phase selective hydrogenation of methyl-acetylene (MA) and propadiene (PD) over a Pd/γ-alumina catalyst were investigated in a fixed bed tubular reactor at temperatures 60 - 80 oC and a pressure of 20 bara. Hougen-Watson type kinetic equations were derived. The formation of higher oligomers slowly deactivated the catalyst. The effect of the deactivating agent on the rates of the main reactions as well as on the deactivating agent formation itself was expressed in terms of a deactivation function multiplying the corresponding rates at zero deactivation. Then, the kinetic model was plugged into the reactor model to simulate an industrial adiabatic reactor. In the second part the production of hydrogen from hydrocarbons was investigated. In both cyclohexane and decalin dehydrogenations, conversions higher than 98% could be obtained over Pt/γ-alumina catalyst at temperature of 320 and 340 oC, respectively, with no apparent deactivation for 30 h and with co-feed of H2 in the feed. Except for H2 and trace amounts of side cracking products, less than 0.01%, benzene was the only dehydrogenated product in cyclohexane dehydrogenation. In the case of decalin dehydrogenation, partially dehydrogenated product, tetralin, was also formed with selectivity lower than 5%, depending on operating conditions. A rigorous Hougen-Watson type kinetic model was derived, which accounted for both the dehydrogenation of cis- and trans- decalin in the feed and also the isomerization of the two isomers. Jet A is the logic fuel in the battlefields. The dehydrogenation of Jet A can produce H2 for military fuel cell application. Although the H2 production is lower than that of steam/autothermal reforming, it eliminates the needs of high temperature and product separation operation

DYNAMICS AND CONTROL OF FORCED UNSTEADY-STATE CATALYTIC REACTORS

This research deals with the dynamics and control of forced unsteady-state catalytic reactors and it is focused on two topics: 1. auto-thermal after-treatment of lean VOC mixtures. Two reactor configurations have been taken into consideration: the reverse-flow reactor (RFR), where the flow direction is periodically changed, and the network of two or three reactors (RN), where the flow direction remains the same, but the feeding position is periodically changed, thus simulating a moving bed. This study (§3) has been organised as follows: - modelling of the two reactor configurations and study of the influence of the main operating parameters (§3.1 and §3.2). As the RFR shows higher stability with respect to disturbances in the feed a deeper investigation has been carried out on this device; - optimisation of the RFR. A simplified model has been used for this analysis in order to strongly reduce the computational effort which is required by detailed models. It has been pointed out that both heat capacity and thermal conductivity of the catalyst play a role, not less important than kinetic activity, strongly influencing the minimum inlet VOC concentration required for autothermal operation (§3.3); - experimental validation of the modelling results in a bench-scale RFR with reduced influence of the wall effects. This activity has been carried at the Departamento de Ingeniería Química y Tecnología del Medio Ambiente-Universidad de Oviedo (Spain) in the framework of the Research Project "Azioni Integrate Italia-Spagna", granted by the Italian Ministry of Research (MIUR). In addition to the intrinsecally dynamic behaviour of the RFR, one must deal with unexpected external perturbations (feed concentration, composition and temperature) which may lead to reactor extinction or catalyst overheating. In order to avoid these problems it is necessary to implement some closed-loop control strategy based on the measurement of the inlet concentration (and composition) and the outlet conversion. This study has been organised as follows: - a model-based soft-sensor (observer) has been developed, in order to quickly and reliably estimate the feed composition from some temperature measurements in the reactor, thus avoiding expensive hardware sensors and time consuming on-line measurements. As deriving an observer from a detailed model is an overwhelming task, a simplified model has been developed and validated in a medium size RFR. This research has been carried out in cooperation with prof. H. Hammoury and D. Schweich of the CPE-Lyon, France (§4.1); - a Model Based control strategy has been proposed and tested to prevent reaction extinction and catalyst overheating (§4.2); 2. enhancement of conversion and selectivity in exothermic, equilibriumlimited reactions. Methanol synthesis and syngas prouction by partial oxidation of methane have been considered as test reactions. This section has been organised as follows: - modelling of the two processes in the two reactor configurations previously described. The influence of the main operating conditions has been addressed with the aim to optimise the two processes. As the RN has shown higher conversion and selectivity with respect to the RFR, in the following the research will be focused on this device (§5); - a simple open loop control policy, which can be useful for a safe startup, has been also tested to study the response of the RN to disturbances on the input parameters, showing that a more robust control strategy is needed for this application; - if a tight control on the outlet product conversion is needed, a Model Predictive Control scheme (MPC) should be used, varying the switching time to maximise the conversion and the selectivity of the reactor. The on-line optimisation requires a simplified model and a Neural Network based model has been developed (§6

Conversion of Greenhouse Gases to Value Added Products Assisted By Catalytic Nonthermal Plasma

The negative impact the greenhouse gases, especially carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) on the environment is well established and development of suitable technologies is warranted in order to regulate their increasing concentrations in the atmosphere. Co-processing of these gases has the advantage of waste minimization, energy production, resource utilization and pollution control. However, as the activation of these gases is highly endothermic, conventional thermocatalytic techniques may not be effective. In this context, nonthermal plasma (NTP) generated by electrical discharges was proposed as an alternative to the conventional methods. NTP created by electrical discharges generate the energetic electrons that colloid with the target gas molecules to decompose them without increasing the temperature of the back ground gas. However, as NTP is non–selective, catalytic NTP was proposed, in order to improve the selectivity to the desired product. The objectives of this research work were to explore NTP for the conversion of the selected greenhouse gases to value added products and to arrive at the suitable catalyst combination to obtain the best selectivity to the desired products like syngas and methanol. This presentation will focus o

Alternative Fuels for Transportation

With existing petroleum oil and natural gas reserves enough for only several more decades, there is an imminent need for alternative energy sources. This critical situation has incited greater improvements in automotive technology and the increased use of nonconventional fuels. Alternative Fuels for Transportation covers the potential, production methods, properties, vehicle tests, merits, and drawbacks of alternative fuels. The esteemed editor highlights the importance of moving toward alternative fuels and the problems and environmental impact of depending on petroleum products. Each self-contained chapter focuses on a particular fuel source, including vegetable oils, biodiesel, methanol, ethanol, dimethyl ether, liquefied petroleum gas, natural gas, hydrogen, electric, fuel cells, and fuel from nonfood crops. For most of these fuels, production methods, storage, transportation and distribution, physiochemical properties, system modification, engine tests, economics, applications, safety aspects, material compatibility, and future scope are discussed. Although we now know that increases in greenhouse gases will contribute to global climate change, the transportation sector and decentralized power generation continue to heavily rely on petroleum products, particularly gasoline and diesel. Exploring how to counteract the world’s energy insecurity and environmental pollution, this book provides a comprehensive understanding of nonconventional fuel sources and technology