27,875 research outputs found

    Approximation of System Components for Pump Scheduling Optimisation

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    © 2015 The Authors. Published by Elsevier Ltd.The operation of pump systems in water distribution systems (WDS) is commonly the most expensive task for utilities with up to 70% of the operating cost of a pump system attributed to electricity consumption. Optimisation of pump scheduling could save 10-20% by improving efficiency or shifting consumption to periods with low tariffs. Due to the complexity of the optimal control problem, heuristic methods which cannot guarantee optimality are often applied. To facilitate the use of mathematical optimisation this paper investigates formulations of WDS components. We show that linear approximations outperform non-linear approximations, while maintaining comparable levels of accuracy

    Single molecule photon counting statistics for quantum mechanical chromophore dynamics

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    We extend the generating function technique for calculation of single molecule photon emission statistics [Y. Zheng and F. L. H. Brown, Phys. Rev. Lett., 90,238305 (2003)] to systems governed by multi-level quantum dynamics. This opens up the possibility to study phenomena that are outside the realm of purely stochastic and mixed quantum-stochastic models. In particular, the present methodology allows for calculation of photon statistics that are spectrally resolved and subject to quantum coherence. Several model calculations illustrate the generality of the technique and highlight quantitative and qualitative differences between quantum mechanical models and related stochastic approximations. Calculations suggest that studying photon statistics as a function of photon frequency has the potential to reveal more about system dynamics than the usual broadband detection schemes.Comment: Submitted to the Journal of Physical Chemistr
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