Optical fibre sensors with applications in gas and biological sensing

This thesis describes the study of various grating based optical fibre sensors for applications in refractive index sensing. The sensitivity of these sensors has been studied and in some cases enhanced using novel techniques. The major areas of development are as follows. The sensitivity of long period gratings (LPGs) to surrounding medium refractive index (SRI) for various periods was investigated. The most sensitive period of LPG was found to be around 160 µm and this was due to the core mode coupling to a single cladding mode but phase matching at two wavelength locations, creating two attenuation peaks, close to the waveguide dispersion turning point. Large angle tilted fibre gratings (TFGs) have similar behaviour to LPGs, in that they couple to the co-propagating cladding modes. The tilted structure of the index modulation within the core of the fibre gives rise to a polarisation dependency, differing the large angle TFG from a LPG. Since the large angle TFG couple to the cladding mode they are SRI sensitive, the sensitivity to SRI can be further increased through cladding etching using HF acid. The thinning of the cladding layer caused a reordering of the cladding modes and shifted to more SRI sensitive cladding modes as the investigation discovered. In a SRI range of 1.36 to 1.40 a sensitivity of 506.9 nm/URI was achieved for the etched large angle TFG, which is greater than the dual resonance LPG. UV inscribed LPGs were coated with sol-gel materials with high RIs. The high RI of the coating caused an increase in cladding mode effective index which in turn caused an increase in the LPG sensitivity to SRI. LPGs of various periods of LPG were coated with sol-gel TiO2 and the optimal thickness was found to vary for each period. By coating of the already highly SRI sensitive 160µm period LPG (which is a dual resonance) with a sol-gel TiO2, the SRI sensitivity was further increased with a peak value of 1458 nm/URI, which was an almost 3 fold increase compared to the uncoated LPG. LPGs were also inscribed using a femtosecond laser which produced a highly focused index change which was no uniform throughout the core of the optical fibre. The inscription technique gave rise to a large polarisation sensitivity and the ability to couple to multiple azimuthal cladding mode sets, not seen with uniform UV inscribed gratings. Through coupling of the core mode to multiple sets of cladding modes, attenuation peaks with opposite wavelength shifts for increasing SRI was observed. Through combining this opposite wavelength shifts, a SRI sensitivity was achieved greater than any single observed attenuations peak. The maximum SRI achieved was 1680 nm/URI for a femtosecond inscribed LPG of period 400 µm. Three different types of surface plasmon resonance (SPR) sensors with a multilayer metal top coating were investigated in D shape optical fibre. The sensors could be separated into two types, utilized a pre UV inscribed tilted Bragg grating and the other employed a post UV exposure to generate surface relief grating structure. This surface perturbation aided the out coupling of light from the core but also changed the sensing mechanism from SPR to localised surface plasmon resonance (LSPR). This greatly increased the SRI sensitivity, compared to the SPR sensors; with the gold coated top layer surface relief sensor producing the largest SRI sensitivity of 2111.5nm/URI was achieved. While, the platinum and silver coated top layer surface relief sensors also gave high SRI sensitivities but also the ability to produce resonances in air (not previously seen with the SPR sensors). These properties were employed in two applications. The silver and platinum surface relief devices were used as gas sensors and were shown to be capable of detecting the minute RI change of different gases. The calculated maximum sensitivities produced were 1882.1dB/URI and 1493.5nm/URI for silver and platinum, respectively. Using a DFB laser and power meter a cheap alternative approach was investigated which showed the ability of the sensors to distinguish between different gases and flow rates of those gases. The gold surface relief sensor was coated in a with a bio compound called an aptamer and it was able to detect various concentrations of a biological compound called Thrombin, ranging from 1mM to as low as 10fM. A solution of 2M NaCl was found to give the best stripping results for Thrombin from the aptamer and showed the reusability of the sensor. The association and disassociation constants were calculated to be 1.0638×106Ms-1 and 0.2482s-1, respectively, showing the high affinity of the Aptamer to thrombin. This supports existing working stating that aptamers could be alternative to enzymes for chemical detection and also helps to explain the low detection limit of the gold surface relief sensor

Near- and mid-IR fibre grating devices and applications

This thesis presents a detailed research work on the fabrication, characterisation and applications of optical fibre grating devices with operation wavelengths cover from near- to mid- infrared (IR) range. One of the major contributions described in this thesis is the systematic investigation on the structures, fabrication methods and spectral, thermal, strain and surrounding refractive index (SRI) characteristics of near-IR fibre gratings including fibre Bragg gratings (FBGs), chirped fibre Bragg grating (CFBGs) and long period grating (LPGs). For some applications, such as special engineering sensors and high power fibre laser, the fibre gratings have been fabricated on different novel fibres (metal coated fibre and large mode field fibre), respectively. Another important contribution from the studies is experimental investigation on 45º tilted fibre gratings (45°-TFGs) and excessively tilted fibre gratings (ex-TFGs), and their applications. 45º-TFGs with high polarisation dependent loss (PDL) in single mode and polarisation maintaining (PM) fibres have been fabricated. The 45°-TFG has been employed as in fibre polariser to obtain the single polarised laser, which has been further developed as transverse loading sensor achieving high sensitivities. Furthermore, all fibre Lyot filter with narrow bandwidth (26 pm), constructed by two 45º-TFGs with 100m long cavity in PM fibre has been demonstrated. For ex-TFGs, SRI sensor based on a surface modified 81°-TFG, showing capability to detect glucose concentration with relatively high RI sensitivity (~168nm/RIU). Finally, an all-fibre loading sensor based on a hybrid 45° and 81° TFG structure has been demonstrated. Finally, I have fabricated fibre gratings into mid-IR 2μm range. The mid-IR FBGs have been evaluated for thermal and strain response, revealing higher temperature sensitivities than that in near-IR range. The mid-IR LPGs have been investigated for the thermal and refractive index sensitivities, also showing significant enhancement. The 45°-TFGs in mid-IR have been investigated for their PDL characteristics. The mid-IR FBGs and 45°-TFGs have been employed in Tm-doped fibre laser cavity to realize multi-wavelength continued wave (CW) and single polarisation operation

Cladding mode coupling in highly localized fiber Bragg gratings: modal properties and transmission spectra

The spectral characteristics of a fiber Bragg grating (FBG) with a transversely inhomogeneous refractive index profile, differs con- siderably from that of a transversely uniform one. Transmission spectra of inhomogeneous and asymmetric FBGs that have been inscribed with focused ultrashort pulses with the so-called point-by-point technique are investigated. The cladding mode resonances of such FBGs can span a full octave in the spectrum and are very pronounced (deeper than 20dB). Using a coupled-mode approach, we compute the strength of resonant coupling and find that coupling into cladding modes of higher azimuthal order is very sensitive to the position of the modification in the core. Exploiting these properties allows precise control of such reflections and may lead to many new sensing applications.Comment: Submission to OE, 16 pages, 6 figure

Optical Quality Resorbable Calcium-Phosphate Glasses for Biophotonic Applications

Recently developed calcium-phosphate glass formulations are proposed in this chapter as a new class of materials for biomedical optics and photonics. The glasses have been designed and carefully prepared in our laboratory to be dissolvable in biological fluids while being optically transparent, mechanically reliable both in dry and humid environments, and suitable for both preform extrusion and fiber drawing. Optical fibers have been drawn from these glasses using our custom-made induction heated drawing tower and showed attenuation loss values from one to two orders of magnitude lower than the counterpart polymeric-based bioresorbable devices reported in literature. In addition, the optical fibers have been implanted in living rats for several weeks and no clinical signs of any adverse effect have been found. Results on the inscription and characterization of different types of fiber Bragg grating-based optical filters will be also shown, together with the demonstration of the suitability of the above-mentioned bioresorbable optical fibers for time-domain diffuse optical spectroscopy

Optical fibre sensors with applications in gas and biological sensing

This thesis describes the study of various grating based optical fibre sensors for applications in refractive index sensing. The sensitivity of these sensors has been studied and in some cases enhanced using novel techniques. The major areas of development are as follows. The sensitivity of long period gratings (LPGs) to surrounding medium refractive index (SRI) for various periods was investigated. The most sensitive period of LPG was found to be around 160 µm and this was due to the core mode coupling to a single cladding mode but phase matching at two wavelength locations, creating two attenuation peaks, close to the waveguide dispersion turning point. Large angle tilted fibre gratings (TFGs) have similar behaviour to LPGs, in that they couple to the co-propagating cladding modes. The tilted structure of the index modulation within the core of the fibre gives rise to a polarisation dependency, differing the large angle TFG from a LPG. Since the large angle TFG couple to the cladding mode they are SRI sensitive, the sensitivity to SRI can be further increased through cladding etching using HF acid. The thinning of the cladding layer caused a reordering of the cladding modes and shifted to more SRI sensitive cladding modes as the investigation discovered. In a SRI range of 1.36 to 1.40 a sensitivity of 506.9 nm/URI was achieved for the etched large angle TFG, which is greater than the dual resonance LPG. UV inscribed LPGs were coated with sol-gel materials with high RIs. The high RI of the coating caused an increase in cladding mode effective index which in turn caused an increase in the LPG sensitivity to SRI. LPGs of various periods of LPG were coated with sol-gel TiO2 and the optimal thickness was found to vary for each period. By coating of the already highly SRI sensitive 160µm period LPG (which is a dual resonance) with a sol-gel TiO2, the SRI sensitivity was further increased with a peak value of 1458 nm/URI, which was an almost 3 fold increase compared to the uncoated LPG. LPGs were also inscribed using a femtosecond laser which produced a highly focused index change which was no uniform throughout the core of the optical fibre. The inscription technique gave rise to a large polarisation sensitivity and the ability to couple to multiple azimuthal cladding mode sets, not seen with uniform UV inscribed gratings. Through coupling of the core mode to multiple sets of cladding modes, attenuation peaks with opposite wavelength shifts for increasing SRI was observed. Through combining this opposite wavelength shifts, a SRI sensitivity was achieved greater than any single observed attenuations peak. The maximum SRI achieved was 1680 nm/URI for a femtosecond inscribed LPG of period 400 µm. Three different types of surface plasmon resonance (SPR) sensors with a multilayer metal top coating were investigated in D shape optical fibre. The sensors could be separated into two types, utilized a pre UV inscribed tilted Bragg grating and the other employed a post UV exposure to generate surface relief grating structure. This surface perturbation aided the out coupling of light from the core but also changed the sensing mechanism from SPR to localised surface plasmon resonance (LSPR). This greatly increased the SRI sensitivity, compared to the SPR sensors; with the gold coated top layer surface relief sensor producing the largest SRI sensitivity of 2111.5nm/URI was achieved. While, the platinum and silver coated top layer surface relief sensors also gave high SRI sensitivities but also the ability to produce resonances in air (not previously seen with the SPR sensors). These properties were employed in two applications. The silver and platinum surface relief devices were used as gas sensors and were shown to be capable of detecting the minute RI change of different gases. The calculated maximum sensitivities produced were 1882.1dB/URI and 1493.5nm/URI for silver and platinum, respectively. Using a DFB laser and power meter a cheap alternative approach was investigated which showed the ability of the sensors to distinguish between different gases and flow rates of those gases. The gold surface relief sensor was coated in a with a bio compound called an aptamer and it was able to detect various concentrations of a biological compound called Thrombin, ranging from 1mM to as low as 10fM. A solution of 2M NaCl was found to give the best stripping results for Thrombin from the aptamer and showed the reusability of the sensor. The association and disassociation constants were calculated to be 1.0638×106Ms-1 and 0.2482s-1, respectively, showing the high affinity of the Aptamer to thrombin. This supports existing working stating that aptamers could be alternative to enzymes for chemical detection and also helps to explain the low detection limit of the gold surface relief sensor.EThOS - Electronic Theses Online ServiceGBUnited Kingdo

Advanced UV inscribed fibre grating structures and applications in optical sensing and laser systems

This thesis presents detailed investigation of UV inscribed fibre grating based devices and novel developments in the applications of such devices in optical sensing and fibre laser systems. The major contribution of this PhD programme includes the systematic study on fabrication, spectral characteristics and applications of different types of UV written in-fibre gratings such as Type I and IA Fibre Bragg Gratings (FBGs), Chirped Fibre Bragg Gratings (CFBGs) and Tilted Fibre Gratings (TFGs) with small, large and 45º tilted structures inscribed in normal silica fibre. Three fabrication techniques including holographic, phase-mask and blank beam exposure scanning, which were employed to fabricate a range of gratings in standard single mode fibre, are fully discussed. The thesis reports the creation of smart structures with self-sensing capability by embedding FBG-array sensors in Al matrix composite. In another part of this study, we have demonstrated the particular significant improvements made in sensitising standard FBGs to the chemical surrounding medium by inducing microstructure to the grating by femtosecond (fs) patterning assisted chemical etching technique. Also, a major work is presented for the investigation on the structures, inscription methods and spectral Polarisation Dependent Loss (PDL) and thermal characteristics of different angle TFGs. Finally, a very novel application in realising stable single polarisation and multiwavelength switchable Erbium Doped Fibre Lasers (EDFLs) using intracavity polarisation selective filters based on TFG devices with tilted structures at small, large and exact 45° angles forms another important contribution of this thesis

Polymer optical fiber gratings for microwave photonics and communications application

Tesis por compendio[ES] Con el continuo desarrollo de materiales y tecnologías de fabricación durante las últimas tres décadas, la atenuación de la transmisión de las fibras ópticas de polímero (POF) se ha reducido considerablemente. Las POF son ventajosas para las redes domésticas, así como para las interconexiones de almacenamiento, y tienen ventajas significativas para muchas aplicaciones de detección, que incluye el límite alto de tensión elástica, alta resistencia a la fractura, alta flexibilidad en la flexión, alta sensibilidad a la tensión y coeficientes termoópticos negativos. Esta tesis consigue mejorar la tecnología de irradiación con láser para POF e investiga dispositivos especiales basados en redes de difracción en POF para comunicaciones ópticas, microondas, fotónica y detección. En particular, desarrollamos la tecnología de fabricación rápida de FBGs en POF con un estudio detallado y la optimización de los parámetros de fabricación de redes de difracción de Bragg en fibra (FBG). Los resultados más destacados incluyen un FBG uniforme de 8 dB con un solo pulso láser Nd: YAG (26 nsm) (8 ns) basado en fibra dopada con BDK, que es el tiempo más corto presentado hasta ahora para la fabricación de FBGs en POF. La irradiación de fibras ópticas de polímero utilizando diferentes materiales basado en el láser KrF a 248 nm permitió demostrar un mejor rendimiento en comparación con el sistema que emplea el láser He-Cd a 325 nm. Además, se fabricaron FBGs uniformes en POFs de índice escalón dopadas con TS en menos de 1 segundo mediante la repetición de pulsos con baja energía. Finalmente, el estudio de la irradiación UV con pulsos de baja energía para la fabricación de redes de difracción estables permitió ahorrar energía en el proceso de fabricación de FBGs en POF, como uno de los principales requisitos para la producción en masa. Basándonos en la tecnología de fabricación mejorada, nos centramos en la fabricación de redes de difracción con diferentes estructuras: se fabricó un FBG con desplazamiento de fase utilizando dos pulsos de 15 ns a 248 nm KrF superpuestos por el método de Moiré; el primer FBG con chirp sintonizable se logró utilizando un solo pulso corto del láser, que abrió nuevas perspectivas a las aplicaciones basadas en redes de difracción con chirp en POF; también se propuso un nuevo método basado en gradientes térmicos para obtener FBG con chirp en POF basadas en FBG uniformes, y se demostró como la forma más conveniente publicada hasta la fecha para lograr este tipo de FBGs no uniformes en POF; y, finalmente, también se han fabricado redes de difracción de largo período utilizando un proceso de fabricación de corto tiempo, especialmente en comparación con investigaciones anteriores. En la última parte de la tesis, y en base a los dispositivos basados en redes de difracción obtenidos a lo largo de este trabajo, se han propuesto varias aplicaciones . De manera similar a los FBG en fibra de sílice, los FBGs con chirp en POF tienen muchas aplicaciones futuras en las áreas de comunicaciones ópticas y de los sensores. Este documento describe la aplicación de detección de tensión basada en una FBG con chirp sintonizable en POF, su aplicación para detección térmica en sistemas biomédicos; e ilustra el potencial de los dispositivos de dispersión sintonizables en el campo de las comunicaciones ópticas, bien como compensación de dispersión o en fotónica de microondas.[CA] Amb el continu desenvolupament de materials i tecnologies de fabricació durant les últimes tres dècades, l'atenuació de la transmissió de les fibres òptiques de polímer (POF) s'ha reduït considerablement. Els POF són avantatjosos per a les xarxes domèstiques, així com per a les interconnexions d'emmagatzematge, i tenen avantatges significatius per a moltes aplicacions de detecció, inclosos els límits de tensió elàstica alta, alta resistència a la fractura, alta flexibilitat en la flexió, alta sensibilitat a la tensió i potencials coeficients termoópticos negatius. Aquesta tesi va millorar la tecnologia d'irradiació amb làser per a POF i va investigar dispositius basats en xarxes difracció de Bragg (FBG) especials en POF per a comunicació òptica, microones, fotònica i detecció. En particular, desenvolupem la tecnologia de fabricació ràpida de FBG en POF amb un estudi detallat i l'optimització dels paràmetres per a la seua fabricació. Els punts destacats dels resultats inclouen un FBG uniforme de 8 dB amb un sol pols del làser Nd: YAG (266 nm) (8 ns) basat en fibra dopada amb BDK, que és el temps més curt reportat per a la fabricació de POF FBG. La irradiació de fibres òptiques de polímer utilitzant diferents materials sota el sistema de làser KrF a 248 nm va permetre demostrar un millor rendiment en comparació amb el sistema de làser Kimmon de 325 nm. A més, els FBG uniformes en el POF dopat amb TS d'índex escalonat es van aconseguir amb menys d'1 segon mitjançant la repetició de polsos de control i l'energia baixa de pols. Finalment, l'estudi de la irradiació d'energia de pols per a la fabricació de FBGs estables va permetre estalviar energia en el procés de fabricació de FBGs en POF, com un dels principals objectius de la producció en massa. Basant-nos en la tecnologia de fabricació millorada, ens centrem en la fabricació de diferents estructures de xarxes de difracció: es va fabricar un FBG amb desplaçament de fase utilitzant dos polsos de 15 ns a 248 nm KrF superposats pel mètode de Moiré; el primer FBG amb chirp sintonitzable es va aconseguir utilitzant un sol pols curt de làser, que va obrir les aplicacions basades en FBG amb chirp en POF; també es va proposar un nou mètode amb gradients tèrmics per a obtindre FBG en POF basat en FBG uniformes, i es va demostrar com la forma més convenient publicada fins hui per a aconseguir FBG POF estimulada; i, finalment, també s'han aconseguit xarxes de llarg període utilitzant un procés de fabricació de curt temps, especialment en comparació amb investigacions anteriors. Finalment, sobre la base dels dispositius de xarxes de difracció obtinguts al llarg d'aquest treball, s'han proposat diverses aplicacions potencials en aquesta tesi. De manera similar que per als FBG amb silici, el FBG amb chirp en POF té moltes aplicacions potencials en comunicacions òptiques i a l¿àrea de sensors. Aquest document descriu l'aplicació de detecció de tensió basada en FBG amb chirp sintonitzable en POF; a més, l'aplicació de detecció tèrmica en sistemes biomèdics; i el potencial dels dispositius de dispersió sintonitzables en les comunicacions òptiques, com per eixample a la compensació de dispersió o a la fotònica de microones.[EN] With the continuing development of material and fabrication technologies over the last three decades, the transmission attenuation of polymer optical fibers (POF) has been greatly decreased. POFs are advantageous for home networks as well as storage interconnections and have significant advantages for many sensing applications, including high elastic strain limits, high fracture toughness, high flexibility in bending, high sensitivity to strain and potential negative thermo-optic coefficients. This thesis improved the laser irradiation technology for POF and investigated special grating devices in POF for optical communication, microware photonics and sensing. In particular, we developed fast POF grating fabrication technology with a detailed study and optimization of the polymer optical fiber Bragg grating (POFBG) fabrication parameters. Highlights of the results include an 8 dB uniform POFBG with one single Nd:YAG (266nm) laser pulse (8 ns) based on BDK doped fiber, which is the shortest time ever reported for POFBG fabrication. The irradiation of polymer optical fibers using different materials under 248 nm KrF laser system allowed to demonstrate a better performance compared with 325 nm Kimmon laser system. Furthermore, uniform FBGs in step-index TS doped POF were achieved with less than 1 second by means of controlling pulse repetition and low pulse energy. Finally, the study of low UV pulse power irradiation for fabricating stable gratings allowed to save energy in the POF grating fabrication process, as one of the main goals for mass production. Based on the improved fabrication technology, we focused on the fabrication of different grating structures: a phase-shifted FBG was fabricated by using two 15 ns 248 nm KrF pulses overlapped by Moiré method; the first tunable chirped FBG was achieved by using a single laser short pulse, which opened the applications based on chirped POF BGs; also a novel thermal annealing method was proposed to obtain chirped POFBGs based on uniform FBGs, and proved as the ever published most convenient way to achieve chirped POFBG; and finally, long period gratings have been also achieved by using a short time fabrication process, specially when compared with previous research. Finally, based on the grating devices obtained throughout this work, several potential applications have been proposed in this thesis. Similarly, to silica chirped FBG, chirped FBG in POF have many potential applications in optical communications and sensing area. This document described the potential strain sensing application based on tunable chirped POFBG; also, the thermal detection application in bio-medical systems; and the potential of tunable dispersion devices in optical communications, i.e., dispersion compensation or microwave photonics.Min, R. (2019). Polymer optical fiber gratings for microwave photonics and communications application [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/125473TESISCompendi

Advanced tilted fiber gratings and their applications

This thesis presents a detailed numerical analysis, fabrication method and experimental investigation on 45º tilted fiber gratings (45º-TFGs) and excessively tilted fiber gratings (Ex-TFGs), and their applications in fiber laser and sensing systems. The one of the most significant contributions of the work reported in this thesis is that the 45º-TFGs with high polarization extinction ratio (PER) have been fabricated in single mode telecom and polarization maintaining (PM) fibers with spectral response covering three prominent optic communication and central wavelength ranges at 1060nm, 1310nm and 1550nm. The most achieved PERs for the 45º-TFGs are up to and greater than 35-50dB, which have reached and even exceeded many commercial in-fiber polarizers. It has been proposed that the 45º-TFGs of high PER can be used as ideal in-fiber polarizers for a wide range of fiber systems and applications. In addition, in-depth detailed theoretical models and analysis have been developed and systematic experimental evaluation has been conducted producing results in excellent agreement with theoretical modeling. Another important outcome of the research work is the proposal and demonstration of all fiber Lyot filters (AFLFs) implemented by utilizing two (for a single stage type) and more (for multi-stage) 45º-TFGs in PM fiber cavity structure. The detailed theoretical analysis and modelling of such AFLFs have also been carried out giving design guidance for the practical implementation. The unique function advantages of 45º-TFG based AFLFs have been revealed, showing high finesse multi-wavelength transmission of single polarization and wide range of tuneability. The temperature tuning results of AFLFs have shown that the AFLFs have 60 times higher thermal sensitivity than the normal FBGs, thus permitting thermal tuning rate of ~8nm/10ºC. By using an intra-cavity AFLF, an all fiber soliton mode locking laser with almost total suppression of siliton sidebands, single polarization output and single/multi-wavelength switchable operation has been demonstrated. The final significant contribution is the theoretical analysis and experimental verification on the design, fabrication and sensing application of Ex-TFGs. The Ex-TFG sensitivity model to the surrounding medium refractive index (SRI) has been developed for the first time, and the factors that affect the thermal and SRI sensitivity in relation to the wavelength range, tilt angle, and the size of cladding have been investigated. As a practical SRI sensor, an 81º-TFG UV-inscribed in the fiber with small (40μm) cladding radius has shown an SRI sensitivity up to 1180nm/RIU in the index of 1.345 range. Finally, to ensure single polarization detection in such an SRI sensor, a hybrid configuration by UV-inscribing a 45º-TFG and an 81º-TFG closely on the same piece of fiber has been demonstrated as a more advanced SRI sensing system

Fabrication and characterisation of 45º and Ex 45º:tilted fibre gratings and their applications in fibre lasers and sensors

In this thesis, I present the studies on fabrication, spectral and polarisation characterisation of fibre gratings with tilted structures at 45º and > 45º (namely 45º- TFGs and ex 45º-TFGs throughout this thesis) and a range of novel applications with these two types of grating. One of the major contributions made in this thesis is the systematic investigation of the grating structures, inscription analysis and spectral and polarisation properties of both types of TFGs. I have inscribed 45º-TFGs in standard telecom and polarisation maintaining (PM) fibres. Two wavelength regions of interest have been explored including 1.55 µm and 1.06 µm. Detailed analysis on fabrication and characterisation of 45º-TFGs on PM fibres have also been carried out for the first time. For ex 45º- TFGs, fabrication has been investigated only on low-cost standard telecom fibre. Furthermore, thermal responses have been measured and analysed showing that both types of TFG have low responsivity to temperature change. More importantly, their refractive index (RI) responses have been characterised to verify the high responsivity to surrounding medium. Based on the unique polarisation properties, both types of TFG have been applied in fibre laser systems to improve the laser performance, which forms another major contribution of the research presented in this thesis. The integration of a 45º-TFG to the Erbium doped fibre laser (EDFL) enables single polarisation laser output at a single wavelength. When combing with ex 45º-TFGs, the EDFL can be transformed to a multi-wavelength switchable laser with single polarisation output. Furthermore, by utilising the polarisation property of the TFGs, a 45º-TFG based mode locked fibre laser is implemented. This laser can produce laser pulses at femtosecond scale and is the first application of TFG in the field of nonlinear optics. Another important contribution from the studies is the development of TFG based passive and active optical sensor systems. An ex 45º-TFG has been successfully developed into a liquid level sensor showing high sensitivity to water based solvents. Strain and twist sensors have been demonstrated via a fibre laser system using both 45°- and ex 45º-TFG with capability identifying not just the twist rate but also the direction. The sensor systems have shown the added advantage of low cost signal demodulation. In addition, load sensor applications have been demonstrated using the 45º-TFG based single polarisation EDFL and the experimental results show good agreement with the theoretical simulation

Desenvolvimento e otimização de sensores em fibra ótica produzidos por laser de femtosegundo

In this work, optical fibre sensors were developed and optimized using a pulsed femtosecond laser. In addition to the inherent advantages of using femtosecond pulses, by emitting radiation in the NIR band, it was possible to modify the refractive index inside dielectric materials, namely silica and polymer optical fibres. Prior to the manufacturing of optical structures, a theoretical study was carried out on the peculiarities of writing-systems based on femtosecond lasers, as well as on the most common devices inscribed in optical fibres, namely Bragg gratings, long period gratings, and Fabry-Pérot interferometers. After assembling femtosecond NIR laser system, Bragg gratings, long period gratings, Fabry-Pérot interferometers, and interferometers based on the optical Vernier effect were manufactured using the direct-writing and phase mask methods. Using the micromachining setup, different structures were created in already existing optical fibre sensors, namely channels in hollow Fabry-Pérot cavities and laser etching around Bragg gratings inscribed in polymers optical fibres. The spectral responses of all devices were extensively characterized to, mainly, variations of temperature and strain, revealing unique sensitivity values, especially for the interferometers based on the optical Vernier effect (> 1 nm/°C and 0.1 nm/µε for temperature and strain, respectively). To demystify the thermal stability of fibre Bragg gratings, a theoretical and experimental study was carried out where several Bragg gratings were inscribed by different techniques, involving different lasers as well as silica and polymer optical fibres. The experimental results corroborated the theoretical predictions, where it was concluded that the gratings inscribed by the point-to-point method using a femtosecond laser have a greater thermal stability and lifetime, even when subjected to longer and higher temperature regimes. Finally, a bridge was stablished between the fundamental research developed during the manufacture of the elementary optical fibre sensors, and possible applications. Five different sensor concepts were demonstrated and tested, capable of detecting variations in magnetic fields, fluids refractive index, temperature, strain and humidity. As results, astonishing sensitivity values were attained, and several cross-sensitivity problems were mitigated, thus establishing the foundations for the development of new prototypes for the future.Neste trabalho foram desenvolvidos e otimizados sensores em fibra ótica através de um laser pulsado de femtosegundo. Para além das vantagens inerentes de usar pulsos da ordem do femtosegundo, ao emitir radiação na banda do infravermelho foi possível modificar o índice de refração no interior de materiais dielétricos, nomeadamente fibras óticas de sílica e polímero. Antes de proceder ao fabrico das estruturas óticas, foi realizado um estudo teórico sobre as peculiaridades dos sistemas de escrita baseados em lasers de femtosegundo, bem como sobre os principais dispositivos inscritos em fibra ótica, nomeadamente redes de Bragg, redes de período longo, e interferómetros de Fabry-Pérot. Após montado o sistema laser NIR de femtosegundo, através de inscrição direta e por máscara de fase foram fabricadas redes de Bragg, redes de período longo, interferómetros de Fabry-Pérot, e interferómetros baseados no efeito ótico de Vernier. Com a montagem de micromaquinação, diferentes estruturas foram criadas em sensores já existentes, nomeadamente buracos em cavidades Fabry-Pérot e remoção de material ao redor de redes de Bragg. As respostas espetrais de todos os dispositivos foram extensivamente caracterizadas, nomeadamente a variações de temperatura e tensão, revelando elevados valores de sensibilidades, especialmente para os interferómetros baseados no efeito ótico de Vernier (> 1 nm/°C e 0.1 nm/µε para temeprature e tensão, respetivamente). Para desmistificar a estabilidade térmica de redes de Bragg em fibra ótica, foi feito um estudo teórico e experimental onde várias redes de Bragg foram gravadas por diferentes técnicas, envolvendo diferentes lasers e fibras óticas de sílica e polímero. Os resultados experimentais corroboraram as previsões teóricas, onde se concluiu que as redes gravadas pelo método de ponto-a-ponto usando um laser de femtosegundo detêm uma maior estabilidade térmica e tempo de vida, mesmo quando submetidas a regimes longos de altas temperaturas. Por fim, foi feita a ponte entre a investigação fundamental desenvolvida durante o fabrico de dispositivos elementares em fibras óticas e possíveis aplicações. Foram demonstrados e testados cinco conceitos diferentes de sensores, capazes de detetar variações de campos magnéticos, índice de refração de fluídos, temperatura, tensão e humidade. Foram atingidos valores de sensibilidade surpreendentes, bem como mitigados problemas de sensibilidade cruzada, tendo sido assim estabelecidas as fundações para o desenvolvimento de novos protótipos para o futuro.Programa Doutoral em Engenharia Físic