9,600 research outputs found
Fracton pairing mechanism for "strange" superconductors: Self-assembling organic polymers and copper-oxide compounds
Self-assembling organic polymers and copper-oxide compounds are two classes
of "strange" superconductors, whose challenging behavior does not comply with
the traditional picture of Bardeen, Cooper, and Schrieffer (BCS)
superconductivity in regular crystals. In this paper, we propose a theoretical
model that accounts for the strange superconducting properties of either class
of the materials. These properties are considered as interconnected
manifestations of the same phenomenon: We argue that superconductivity occurs
in the both cases because the charge carriers (i.e., electrons or holes)
exchange {\it fracton excitations}, quantum oscillations of fractal lattices
that mimic the complex microscopic organization of the strange superconductors.
For the copper oxides, the superconducting transition temperature as
predicted by the fracton mechanism is of the order of K. We suggest
that the marginal ingredient of the high-temperature superconducting phase is
provided by fracton coupled holes that condensate in the conducting
copper-oxygen planes owing to the intrinsic field-effect-transistor
configuration of the cuprate compounds. For the gate-induced superconducting
phase in the electron-doped polymers, we simultaneously find a rather modest
transition temperature of K owing to the limitations imposed by
the electron tunneling processes on a fractal geometry. We speculate that
hole-type superconductivity observes larger onset temperatures when compared to
its electron-type counterpart. This promises an intriguing possibility of the
high-temperature superconducting states in hole-doped complex materials. A
specific prediction of the present study is universality of ac conduction for
.Comment: 12 pages (including separate abstract page), no figure
On the Nature and Shape of Tubulin Trails: Implications on Microtubule Self-Organization
Microtubules, major elements of the cell skeleton are, most of the time, well
organized in vivo, but they can also show self-organizing behaviors in time
and/or space in purified solutions in vitro. Theoretical studies and models
based on the concepts of collective dynamics in complex systems,
reaction-diffusion processes and emergent phenomena were proposed to explain
some of these behaviors. In the particular case of microtubule spatial
self-organization, it has been advanced that microtubules could behave like
ants, self-organizing by 'talking to each other' by way of hypothetic (because
never observed) concentrated chemical trails of tubulin that are expected to be
released by their disassembling ends. Deterministic models based on this idea
yielded indeed like-looking spatio-temporal self-organizing behaviors.
Nevertheless the question remains of whether microscopic tubulin trails
produced by individual or bundles of several microtubules are intense enough to
allow microtubule self-organization at a macroscopic level. In the present
work, by simulating the diffusion of tubulin in microtubule solutions at the
microscopic scale, we measure the shape and intensity of tubulin trails and
discuss about the assumption of microtubule self-organization due to the
production of chemical trails by disassembling microtubules. We show that the
tubulin trails produced by individual microtubules or small microtubule arrays
are very weak and not elongated even at very high reactive rates. Although the
variations of concentration due to such trails are not significant compared to
natural fluctuations of the concentration of tubuline in the chemical
environment, the study shows that heterogeneities of biochemical composition
can form due to microtubule disassembly. They could become significant when
produced by numerous microtubule ends located in the same place. Their possible
formation could play a role in certain conditions of reaction. In particular,
it gives a mesoscopic basis to explain the collective dynamics observed in
excitable microtubule solutions showing the propagation of concentration waves
of microtubules at the millimeter scale, although we doubt that individual
microtubules or bundles can behave like molecular ants
Atomic Force Microscopy and Optical Studies of Organic Thin Films with Hydrogen-Bonded Networks
Brewster angle microscopy and atomic force microscopy were used to characterize the surface morphology of thin films in situ or after transfer onto solid supports. Two acids were studied, differing in carboxylic acid head groups, resulting in significantly different morphological features for thin films formed from these two amphiphiles on a Langmuir trough. Differences in self-assembly and domain sizes were correlated with the formation of hydrogen-bonded networks. The influence of surface hydrophobicity or hydrophilicity during deposition on morphology was also characterized, with spherulitic features appearing in some samples
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