417,037 research outputs found
Benchmarking the SPARC software program for estimating solubilities of naphthalene and anthracene in organic solvents
The SPARC software program was benchmarked for calculating the solubilities of two representative polyaromatic hydrocarbons (PAHs), naphthalene and anthracene, in a range of organic solvents at various temperatures. Although SPARC was able to reasonably approximate the solubilities of naphthalene in some organic solvents, gross errors were obtained for other solvents. For anthracene, poor prediction performance was observed in all solvents considered. Overall, the results suggest that SPARC is currently not suitable for accurately predicting the solubilities of representative PAHs relevant for the petroleum sector in various organic solvents
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Correlating Interlayer Spacing and Separation Capability of Graphene Oxide Membranes in Organic Solvents.
Membranes synthesized by stacking two-dimensional graphene oxide (GO) hold great promise for applications in organic solvent nanofiltration. However, the performance of a layer-stacked GO membrane in organic solvent nanofiltration can be significantly affected by its swelling and interlayer spacing, which have not been systematically characterized. In this study, the interlayer spacing of the layer-stacked GO membrane in different organic solvents was experimentally characterized by liquid-phase ellipsometry. To understand the swelling mechanism, the solubility parameters of GO were experimentally determined and used to mathematically predict the Hansen solubility distance between GO and solvents, which is found to be a good predictor for GO swelling and interlayer spacing. Solvents with a small solubility distance (e.g., dimethylformamide, N-methyl-2-pyrrolidone) tend to cause significant GO swelling, resulting in an interlayer spacing of up to 2.7 nm. Solvents with a solubility distance larger than 9.5 (e.g., ethanol, acetone, hexane, and toluene) only cause minor swelling and are thus able to maintain an interlayer spacing of around 1 nm. Correspondingly, GO membranes in solvents with a large solubility distance exhibit good separation performance, for example, rejection of more than 90% of the small organic dye molecules (e.g., rhodamine B and methylene blue) in ethanol and acetone. Additionally, solvents with a large solubility distance result in a high slip velocity in GO channels and thus high solvent flux through the GO membrane. In summary, the GO membrane performs better in solvents that are unlike GO, i.e., solvents with large solubility distance
On the mechanism of the reaction of enamines and dimethyl acetylenedicarboxylate (DMAD) in polar and apolar solvents
[2+2]-Cycloadducts of enamines and DMAD, formed in apolar solvents, isomerize to pyrrolizine derivatives under mild conditions in protic polar solvents like methanol and 1-butanol
A Smooth Interface Method for Simulating Liquid Crystal Colloid Dispersions
A new method is presented for mesoscopic simulations of particle dispersions
in liquid crystal solvents. It allows efficient first-principle simulations of
the dispersions involving many particles with many-body interactions mediated
by the solvents. Demonstrations have been performed for the aggregation of
colloid dispersions in two-dimensional nematic and smectic-C* solvents
neglecting hydrodynamic effects, which will be taken into account in the near
future.Comment: 13 pages, 4 figure
Solvent Deactivation of Mimosa Webworm Larval Webbing (Lepidoptera: Plutellidae)
Untreated larval webbing of the mimosa webworm, Homadaula anisocentra stimulated oviposition. Six-week-old webbing was as active as two-day-old webbing. Stimulatory activity of webbing was lost after rinsing with highly polar solvents, but not after rinsing with nonpolar solvents. Addition of the polar solvent rinses did not induce activity in other substrates nor restore activity to rinsed webbing. No differences in structure were found in a scanning electron microscope examination of unrinsed webbing and webbing rinsed with solvents of varying polarity
Two-Dimensional Electronic Spectroscopy of Chlorophyll a: Solvent Dependent Spectral Evolution
The interaction of the monomeric chlorophyll Q-band electronic transition with solvents of differing physical-chemical properties is investigated through two-dimensional electronic spectroscopy (2DES). Chlorophyll constitutes the key chromophore molecule in light harvesting complexes. It is well-known that the surrounding protein in the light harvesting complex fine-tunes chlorophyll electronic transitions to optimize energy transfer. Therefore, an understanding of the influence of the environment on the monomeric chlorophyll electronic transitions is important. The Q-band 2DES is inhomogeneous at early times, particularly in hydrogen bonding polar solvents, but also in nonpolar solvents like cyclohexane. Interestingly this inhomogeneity persists for long times, even up to the nanosecond time scale in some solvents. The reshaping of the 2DES occurs over multiple time scales and was assigned mainly to spectral diffusion. At early times the reshaping is Gaussian-like, hinting at a strong solvent reorganization effect. The temporal evolution of the 2DES response was analyzed in terms of a Brownian oscillator model. The spectral densities underpinning the Brownian oscillator fitting were recovered for the different solvents. The absorption spectra and Stokes shift were also properly described by this model. The extent and nature of inhomogeneous broadening was a strong function of solvent, being larger in H-bonding and viscous media and smaller in nonpolar solvents. The fastest spectral reshaping components were assigned to solvent dynamics, modified by interactions with the solute
Ultrafast Intramolecular Charge Transfer of Formyl Perylene Observed Using Femtosecond Transient Absorption Spectroscopy
The excited-state photophysics of formylperylene (FPe) have been investigated in a series of nonpolar, polar
aprotic, and polar protic solvents. A variety of experimental and theoretical methods were employed including
femtosecond transient absorption (fs-TA) spectroscopy with 130 fs temporal resolution. We report that the
ultrafast intramolecular charge transfer from the perylene unit to the formyl (CHO) group can be facilitated
drastically by hydrogen-bonding interactions between the carbonyl group oxygen of FPe and hydrogen-donating
solvents in the electronically excited state. The excited-state absorption of FPe in methanol (MeOH) is close
to the reported perylene radical cation produced by bimolecular quenching by an electron acceptor. This is
a strong indication for a substantial charge transfer in the S1 state in protic solvents. The larger increase of
the dipole moment change in the protic solvents than that in aprotic ones strongly supports this observation.
Relaxation mechanisms including vibrational cooling and solvation coupled to the charge-transfer state are
also discussed
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist
Tables of ^1H and ^(13)C NMR chemical shifts have been compiled for common organic compounds often used as reagents or found as products or contaminants in deuterated organic solvents. Building upon the work of Gottlieb, Kotlyar, and Nudelman in the Journal of Organic Chemistry, signals for common impurities are now reported in additional NMR solvents (tetrahydrofuran-d_8, toluene-d_8, dichloromethane-d_2, chlorobenzene-d_5, and 2,2,2-trifluoroethanol-d_3) which are frequently used in organometallic laboratories. Chemical shifts for other organics which are often used as reagents or internal standards or are found as products in organometallic chemistry are also reported for all the listed solvents
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