9,838 research outputs found
Arrested state of clay-water suspensions: gel or glass?
The aging of a charged colloidal system has been studied by Small Angle
X-rays Scattering, in the exchanged momentum range Q=0.03 - 5 nm-1, and by
Dynamic Light Scattering, at different clay concentrations (Cw =0.6 % - 2.8 %).
The static structure factor, S(Q), has been determined as a function of both
aging time and concentration. This is the first direct experimental evidence of
the existence and evolution with aging time of two different arrested states in
a single system simply obtained only by changing its volume fraction: an
inhomogeneous state is reached at low concentrations, while a homogenous one is
found at high concentrations.Comment: 5 pages, 2 figure
Routes to gelation in a clay suspension
The gelation of water suspension of a synthetic clay (Laponite) has been
studied by dynamic light scattering in a wide range of clay weight
concentration (Cw = 0.003-0.031). At variance with previous determination,
indicating a stable liquid phase for Cw < Cw*=0.015-0.018, we find that the
gelation takes actually place in the whole examined Cw range. More importantly,
we find that Cw* marks the transition between two different routes to gelation.
We hypothesize that at low concentration Laponite suspension behaves as an
attractive colloid and that the slowing down of the dynamics is attained by the
formation of larger and larger clusters while at high concentration the basic
units of the gel could be the Debye Huckel spheres associated to single
Laponite plates.Comment: 5 pages, 4 figure
Ceramic nanostructure materials, membranes and composite layers
Synthesis methods to obtain nanoscale materials will be briefly discussed with a focus on sol-gel methods. Three types of nanoscale composites (powders, membranes and ion implanted layers) will be discussed and exemplified with recent original research results. Ceramic membranes with a thickness of 1–10 μm consist of a packing of elementary particles with a size of 3–7 nm. The mean pore size is about 2.5–3 nm. The preparation routes are based on sol and sol-gel technologies. The pores can be modified by liquid as well as by gas deposition techniques. This leads to modification of the chemical character and the effective pore size and gives rise to microstructure elements well below the size of the pores (3 nm). The modification of ceramic surface layers with a thickness of 0.05–0.5 μm by ion implantation and annealing procedures yields amorphous or strongly supersatured metastable solid solutions of e.g. Fe2O3 (or TiO2) in zirconia-yttria solid solutions or of very finely dispersed metal particles in the ceramic surface layers. Particle sizes are of the order of 2–4 nm. Both types of structures have interesting transport, catalytic and mechanical properties
Theory and simulation of gelation, arrest and yielding in attracting colloids
We present some recent theory and simulation results addressing the phenomena
of colloidal gelation at both high and low volume fractions, in the presence of
short-range attractive interactions. We discuss the ability of mode-coupling
theory and its adaptations to address situations with strong heterogeneity in
density and/or dynamics. We include a discussion of the effect of attractions
on the shear-thinning and yield behaviour under flow.Comment: 17 pages, 6 figure
Thick films of YSZ electrolytes by dip-coating process
Yttria stabilized zirconia (YSZ, 8% Y2O3) thick films were coated on porous Ni-YSZ substrates using the dip-coating process and a suspension with a new formulation. The
suspension was obtained by addition of a polymeric matrix in a stable suspension of a commercial YSZ (Tosoh) powders dispersed in an azeotropic MEK-EtOH mixture. The green layers were densified after an optimization of the suspension composition. YSZ Tosoh particles encapsulated by a zirconium alkoxide sol and added with colloidal alkoxide
precursor are used to load the suspension. The in situ growth of these colloids increases significantly the layers density after an appropriated heat treatment. The obtained films are continuous, homogeneous and 20 μm thick. Different microstructures are obtained depending on the synthesis parameters of the suspension
Local structure of percolating gels at very low volume fractions
The formation of colloidal gels is strongly dependent on the volume fraction
of the system and the strength of the interactions between the colloids. Here
we explore very dilute solutions by the means of numerical simulations, and
show that, in the absence of hydrodynamic interactions and for sufficiently
strong interactions, percolating colloidal gels can be realised at very low
values of the volume fraction. Characterising the structure of the network of
the arrested material we find that, when reducing the volume fraction, the gels
are dominated by low-energy local structures, analogous to the isolated
clusters of the interaction potential. Changing the strength of the interaction
allows us to tune the compactness of the gel as characterised by the fractal
dimension, with low interaction strength favouring more chain-like structures
Aging of rotational diffusion in colloidal gels and glasses
We study the rotational diffusion of aging Laponite suspensions for a wide
range of concentrations using depolarized dynamic light scattering. The
measured orientational correlation functions undergo an ergodic to non-ergodic
transition that is characterized by a concentration-dependent
ergodicity-breaking time. We find that the relaxation times associated with
rotational degree of freedom as a function of waiting time, when scaled with
their ergodicity-breaking time, collapse on two distinct master curves. These
master curves are similar to those previously found for the translational
dynamics; The two different classes of behavior were attributed to colloidal
gels and glasses. Therefore, the aging dynamics of rotational degree of freedom
provides another signature of the distinct dynamical behavior of colloidal gels
and glasses.Comment: 12 pages, 7 figure
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