Petrogenetic processes in the ultramafic, alkaline and carbonatitic magmatism in the Kola Alkaline Province: a review

Igneous rocks of the Devonian Kola Alkaline Carbonatite Province (KACP) in NW Russia and eastern Finland can be classified into four groups: (a) primitive mantle-derived silica-undersaturated silicate magmas; (b) evolved alkaline and nepheline syenites; (c) cumulate rocks; (d) carbonatites and phoscorites, some of which may also be cumulates. There is no obvious age difference between these various groups, so all of the magma-types were formed at the same time in a relatively restricted area and must therefore be petrogenetically related. Both sodic and potassic varieties of primitive silicate magmas are present. On major element variation diagrams, the cumulate rocks plot as simple mixtures of their constituent minerals (olivine, clinopyroxene, calcite etc). There are complete compositional trends between carbonatites, phoscorites and silicate cumulates, which suggests that many carbonatites and phoscorites are also cumulates. CaO/Al2O3 ratios for ultramafic and mafic silicate rocks in dykes and pipes range up to 5, indicating a very small degree of melting of a carbonated mantle at depth. Damkjernites appear to be transitional to carbonatites. Trace element modelling indicates that all the mafic silicate magmas are related to small degrees of melting of a metasomatised garnet peridotite source. Similarities of the REE patterns and initial Sr and Nd isotope compositions for ultramafic alkaline silicate rocks and carbonatites indicate that there is a strong relationship between the two magma-types. There is also a strong petrogenetic link between carbonatites, kimberlites and alkaline ultramafic lamprophyres. Fractional crystallisation of olivine, diopside, melilite and nepheline gave rise to the evolved nepheline syenites, and formed the ultramafic cumulates. All magmas in the KACP appear to have originated in a single event, possibly triggered by the arrival of hot material (mantle plume?) beneath the Archaean/Proterozoic lithosphere of the northern Baltic Shield that had been recently metasomatised. Melting of the carbonated garnet peridotite mantle formed a spectrum of magmas including carbonatite, damkjernite, melilitite, melanephelinite and ultramafic lamprophyre. Pockets of phlogopite metasomatised lithospheric mantle also melted to form potassic magmas including kimberlite. Depth of melting, degree of melting and presence of metasomatic phases are probably the major factors controlling the precise composition of the primary melts formed

Dismantling the deep earth : geochemical constraints from hotspot lavas for the origin and lengthscales of mantle heterogeneity

Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2008Chapter 1 presents the first published measurements of Sr-isotope variability in olivine-hosted melt inclusions. Melt inclusions in just two Samoan basalt hand samples exhibit most of the total Sr-isotope variability observed in Samoan lavas. Chapter 3 deals with the largest possible scales of mantle heterogeneity, and presents the highest magmatic 3He/4He (33.8 times atmospheric) discovered in Samoa and the southern hemisphere. Along with Samoa, the highest 3He/4He sample from each southern hemisphere high 3He/4He hotspot exhibits lower 143Nd/144Nd ratios than their counterparts in the northern hemisphere. Chapter 2 presents geochemical data for a suite of unusually enriched Samoan lavas. These highly enriched Samoan lavas have the highest 87Sr/86Sr values (0.72163) measured in oceanic hotspot lavas to date, and along with trace element ratios (low Ce/Pb and Nb/U ratios), provide a strong case for ancient recycled sediment in the Samoan mantle. Chapter 4 explores whether the eclogitic and peridotitic portions of ancient subducted oceanic plates can explain the anomalous titanium, tantalum and niobium (TITAN) enrichment in high 3He/4He ocean island basalts (OIBs). The peridotitic portion of ancient subducted plates can contribute high 3He/4He and, after processing in subduction zones, a refractory, rutile-bearing eclogite may contribute the positive TITAN anomalies.Funding was provided by a National Science Foundation Graduate Research Fellowship, the National Science Foundation grants EAR- 0509891 and EAR-0652707 to Stanley R. Hart, the Woods Hole Oceanographic Institution Academic Programs Office, the Woods Hole Oceanographic Institution Deep Ocean Exploration Institute, the Woods Hole Oceanographic Institution Coastal Ocean Institute, and the Ocean Ventures Fund

Triassic alkaline magmatism of the Hawasina Nappes: Post-breakup melting of the Oman lithospheric mantle modified by the Permian Neotethyan Plume

International audienceMiddle to Late Triassic lavas were sampled within three tectonostratigraphic groups of the Hawasina Nappes in the Oman Mountains. They are predominantly alkali basalts and trachybasalts, associated with minor sub-alkaline basalts, trachyandesites, trachytes and rhyolites. Their major, trace elements and Nd-Pb isotopic compositions are very similar to those of the Permian plume-related high-Ti basalts which also occur in the Hawasina Nappes. The Triassic lavas derive from low-degree melting of an enriched OIB-type mantle source, characterized by εNdi = 0.3-5.3 and (206Pb/204Pb)i = 16.96-19.31 (for t = 230 My). With time, melting depths decreased from the garnet + spinel to the spinel lherzolite facies and the degree of melting increased. The oldest are distinguished from the others by unradiogenic Nd and Pb signatures, with εNdi = − 4.5 to − 1.2 and (206Pb/204Pb)i = 16.35-17.08, which we attribute to their contamination by Arabo-Nubian lower crust. The lavas likely derived from the Oman lithospheric mantle, the original DMM-HIMU signature of which was overprinted during its pervasive metasomatism by the Permian plume-related melts. We suggest that these lavas were emplaced during post-breakup decompression-triggered melting in the Middle Triassic during global kinematic reorganization of the Tethyan realm

Naturaliste plateau: constraints on the timing and evolution of the Kerguelen Large Igneous Province and its role in Gondwana breakup

Volcanism associated with the Kerguelen Large Igneous Province is found scattered in southwestern Australia (the ca 136 to ca 130 Ma Bunbury Basalts, and ca 124 Ma Wallaby Plateau), India (ca 118 Ma Rajmahal Traps and Cona Basalts), and Tibet (the ca 132 Ma Comei Basalts), but apart from the ∼70 000 km2 Wallaby Plateau, these examples are spatially and volumetrically minor. Here, we report dredge, geochronological and geochemical results from the ∼90 000 km2 Naturaliste Plateau, located ∼170 to ∼500 km southwest of Australia. Dredged lavas and intrusive rocks range from mafic to felsic compositions, and prior geophysical analyses indicate these units comprise much of the plateau substrate. 40Ar/39Ar plagioclase ages from mafic units and U–Pb zircon ages from silicic rocks indicate magmatic emplacement from 130.6 ± 1.2 to 129.4 ± 1.3 Ma for mafic rocks and 131.8 ± 3.9 to 128.2 ± 2.3 Ma for silicic rocks (2σ). These Cretaceous Naturaliste magmas incorporated a significant component of continental crust, with relatively high 87Sr/86Sr (up to 0.78), high 207Pb/204 Pb ratios (15.5–15.6), low 143Nd/144Nd (0.511–0.512) and primitive-mantle normalised Th/Nb of 11.3 and La/Nb of 3.97. These geochemical results are consistent with the plateau being underlain by continental basement, as indicated by prior interpretations of seismic and gravity data, corroborated by dredging of Mesoproterozoic granites and gneisses on the southern plateau flank. The Cretaceous Naturaliste Plateau igneous rocks have signatures indicative of extraction from a depleted mantle, with trace-element and isotopic values that overlap with Kerguelen Plateau lavas reflect crustal contamination. Our chemical and geochronological results therefore show the Naturaliste Plateau contains evidence of an extensive igneous event representing some of the earliest voluminous Kerguelen hotspot magmas. Prior work reports that contemporaneous correlative volcanic sequences underlie the nearby Mentelle Basin, and the Enderby Basin and Princess Elizabeth Trough in the Antarctic. When combined, the igneous rocks in the Naturaliste, Mentelle, Wallaby, Enderby, Princess Elizabeth, Bunbury and Comei-Cona areas form a 136–124 Ma Large Igneous Province covering >244 000 km2

From subduction to extension: The tectonomagmatic evolution of the Bulgarian Rhodopes

The Bulgarian Rhodopes provide an unique opportunity to study processes that take place at convergent continental margins. Ophiolite complexes incorporated in the Rhodopean nappe stack as well as the directly overlying post-collisional volcanism allow the investigation of processes from subduction, collision, and subsequent lithospheric extension triggering lithospheric mantle melting that leads to volcanism in collisional orogens. The first part of this dissertation investigates the high-pressure (HP) metamorphic history of ophiolite complexes incorporated in different levels of the Rhodopean nappe stack. The determination of the exact timing of these HP events as well as the characterization of the metamorphic protoliths is crucial for reconstructing the geodynamic evolution of the Rhodopes. In this context, the Lu-Hf isotope system has already been proven useful to date HP mineral assemblages in other Alpine units and was therefore applied to four eclogite samples from different units of the nappe stack of the Bulgarian Rhodopes. The Lu-Hf garnet dating revealed a metamorphic event during the Cretaceous (~ 126 Ma) affecting the highest nappe unit investigated (Upper Allochthon) and an Eocene event (~ 43 Ma) for the Middle Allochthon. These results provide evidence for two separate subduction events in the Rhodopes, in support of previous findings. Moreover, thrusting of the Middle over the Lower Allochthon can be narrowed down to the time span 42 - 34 Ma. The second and third part of this dissertation provides an extensive dataset on the post-collisional volcanism in the Bulgarian Rhodopes as well as for arc lavas from Santorini, which are used as a comparative suite throughout the text. The Bulgarian post-collisional volcanism is characterized by a high magnitude of incompatible trace element enrichment, which is particularly shown by its affiliation to the high-K and shoshonite series. Two petrogenetic models that were previously proposed for the generation of high-K magmas involve the melting of ancient, enriched lithospheric mantle sources (single-stage model) or melting triggered by young refertilization of subduction-related components derived from subducted sediments or oceanic crust (multi-stage model). These two models are tested for the Bulgarian K-rich rocks, based on new major, trace element and Sr-Nd-Hf-Pb isotope compositions. The single-stage model is evaluated by Sr-Nd isotope modelling assuming the presence of ancient lithospheric mantle domains whereas the multi-stage model is assessed by comparing compositions of the Bulgarian lavas with those of lavas from Santorini. Santorini Island lavas are thought to sample the current trace element and isotope inventory of the long-lived Aegean subduction-zone system. This northward facing system has been active since late Jurassic/Early Cretaceous and was potentially involved in refertilizing the mantle sources of the Bulgarian lavas. In addition to the Bulgarian lavas, we present new major, trace element and Sr-Nd-Hf-Pb isotope data for Santorini. Modelling of Sr-Nd isotope compositions of the Bulgarian lavas argues for a young (Meso- to Cenozoic) source enrichment. Therefore, single-stage models involving melting of ancient, > 1 Ga old lithospheric mantle can be confidently ruled out, in agreement with tectonic models for the region. The enriched isotope signatures found in the Bulgarian lavas, coupled with a pronounced enrichment in incompatible elements, instead indicate mantle refertilization by subduction components similar to presently subducted continent-derived sediments. Notably, the Bulgarian lavas record a predominant influx of fluid-like subduction components when compared to the Santorini lavas. Collectively, the data presented for the Bulgarian lavas are thus clearly in favour of a multi-stage model. The last part of this dissertation focuses on extended high-field-strength element (HFSE) systematics in the Bulgarian and Santorini lavas. The extended HFSE (Nb, Ta, Zr, Hf, W, Mo, and Sb) are of particular interest in magmatic rocks as their fractionations hint towards specific residual phases in their source regions, such as rutile, allanite, zircon, micas, and sulphides. Tungsten, Sb, and Mo are of particular importance in that they are mobilized in subduction zones by fluids and melts at distinct temperatures and redox conditions and might provide important insights into the conditions and magnitude of source enrichment. However, no significant fractionation of the HFSE ratios (Nb/Ta, Zr/Hf, Zr/Nb) compared to MORB were observed in the Santorini lavas and in the Bulgarian high-K rocks. An influence on the HFSE budget by residual phases like allanite, zircon, or phengite can be largely ruled out, whereas trace amounts of residual rutile in the source may account for the slightly lower Nb/Ta observed in the dataset than expected for bulk sediment addition. The W-Sb-Mo systematics of both sample suites furthermore confirm the predominance of subducted sediments on the incompatible trace element budget, which is dominated by more fluid-like components in the Bulgarian lavas and melt-like in the Santorini lavas

The Paleoarchean Buffalo River komatiites: Progressive melting of a single large mantle plume beneath the growing Kaapvaal craton

Several Archean granitoid-greenstone terranes are exposed on the southeastern Kaapvaal craton in South Africa, but they received little scientific attention compared to the archetypal greenstone belt successions of the Barberton Mountain Land at the eastern craton margin. This study reports on a detailed field and geochemical survey of the Buffalo River Greenstone Belt at the southern Kaapvaal craton margin in KwaZulu-Natal, with focus on hitherto unstudied komatiites and basaltic rocks from this volcanic succession. Cross-cutting relationships and new U-Pb zircon age determinations for several granitoid units establish a minimum age of 3.26 Ga for komatiitic volcanism, possibly as old as ca. 3.5 Ga if a 3.47 Ga granodiorite sheet is interpreted as ‘intrusive’ into the greenstone succession. Geochemical data reveal three types of Paleoarchean komatiites at Buffalo River. Spinifex textured lava flows represent Al-depleted komatiites, with subchondritic Al2O3/TiO2 ratios and enrichment of LREE over HREE. The second type comprises Al-undepleted komatiites that have chondritic Al2O3/TiO2 and flat REE patterns. The third type identified comprises Al-enriched komatiites that display suprachondritic Al2O3/TiO2 ratios, with significant LREE depletion. The Al-depleted and Al-undepleted komatiites from Buffalo River are geochemically similar to komatiites from the 3.48 Ga Komati and 3.26 Ga Weltevreden formations of the Barberton Supergroup respectively, whereas the Al-enriched komatiites resemble the 3.33 Ga Commondale komatiites on the southeastern Kaapvaal craton. To explain the co-occurrence of three discrete komatiite types within a single volcanic succession at Buffalo River, we suggest that each major komatiite magmatic pulse originated from the same upwelling mantle source, from which melt was extracted at different pressure but similarly hot temperature conditions. 187Os/188Os data for the Al-depleted komatiites suggest an ultimate magma origin from a primitive mantle reservoir. The contrasting γOs values for Kaapvaal craton komatiites (zero to positive) and peridotitic mantle xenoliths (zero to negative) support a complementary nature of these lithologies as high-degree melts and depleted residues linked by vigorous mantle plume activity at around 3.5 Ga. Such a relationship can explain the contrasting Re/Os systematics of komatiites and lithospheric mantle peridotites, which creates the contrasting γOs over time. The highly siderophile element patterns of the Al-depleted komatiites from Buffalo River are similar to those of Barberton-type komatiites, for which an origin from the deepest upper mantle with high melt retention in an upwelling plume source was suggested. We confirm that this ca. 3.5 Ga mantle source had only 60–80 % of the platinum-group element budget of the modern ambient mantle, which points indirectly to a location at great depth in the aftermath of the meteoritic late accretion. Progressive melting of such an upwelling mantle source, to the point of majoritic garnet exhaustion, may explain the Al-undepleted and Al-enriched komatiites at Buffalo River. The presence of all three major komatiite types within a single volcanic succession may be linked to deep critical melting of a large mantle plume associated with growth of the Kaapvaal ‘continent’ at 3.5 Ga

Magmatism and Metallogeny in the Crustal Evolution of Rio Grande do Sul Shield, Brazil

The State of Rio Grande do Sul has a complex Precambrian/Cambrian shield, which has been investigated for four decades. This complexity involves ages ranging from 2.55 Ga (possibly 3.3 Ga) to 550 Ma (and even 470 Ma). The three major juvenile accretionary episodes occurred at 2.55 Ga, 2.26-2.02 Ga and 900-700 Ma, while a continental-scale crustal reworking (collisional) orogeny occurred from 780 to 550 Ma. The three accretionary orogenies are known as the Jequié, Transamazonian and Brasiliano Cycles, respectively. The Brasiliano Cycle includes the collisional orogeny. Magmatism was tholeiitic low-K bimodal basic-acid in the Archean (Santa Maria Chico granulites), and evolved to tonalitic-trondhjemitic-granodioritic in the Paleoproterozoic (Encantadas Complex). During the Paleoproterozoic/Archean transition, komatiites and basalts were formed in greenstone belts (Passo Feio Sul Formation). The end of the Transamazonian Cycle was the beginning of a long period of tectonic quiescence, and the region remained in the interior of the Atlantica Supercontinent until the beginning of the Brasiliano Cycle at ca. 900 Ma (Passinho Diorite). This Neoproterozoic cycle displays two classical orogenic types, namely the São Gabriel accretionary orogeny in the western part of the State and Dom Feliciano collisional orogeny in its eastern part. Accretion generated juvenile tonalite-trondhjemite-granodiorite associations with related ophiolites (Cerro Mantiqueiras Ophiolite), while the collision formed the voluminous and mostly peraluminous and high-K calcalkaline granites of the Dom Feliciano orogeny. The waning stages of the orogeny were responsible for the outpouring of a very expressive silica-saturated volcanism and eventually finished with the Rodeio Velho basalts at 470 Ma. Comparable Paleoproterozoic/Neoproterozoic Precambrian terranes surround the shield in Uruguay, in Santa Catarina and in western Africa. Comparable Neoproterozoic juvenile and reworked terranes occur in NE Africa. Widespread indications of metals are a good sign of possible deposits, but the two major types of deposits are the orogenic epizonal Bossoroca gold deposit and the distal magmatichydrothermal Lavras/Camaquã copper-gold deposits

Dynamical Geochemistry: Mantle dynamics and its role in the formation of geochemical heterogeneity

Chemical geodynamics is a term coined nearly forty years ago to highlight the important link between Earth's geochemical evolution and plate tectonics & mantle convection. Significant progress in our understanding of this connection has taken place since then through advances in the analytical precision of geochemical measurements, dramatically improved geophysical imaging techniques, application of novel isotope systems, and great advances in computational power. Thee latter especially has improved geodynamical models and data interpretation techniques. We provide a review of these advances and their impact on chemical geodynamics, or perhaps, dynamical geochemistry. To focus this review we will address primarily the role of whole mantle convection and oceanic crust formation and recycling together with an update on our understanding of noble gas systematics