種々の表面処理を行った鉛フリーハンダ接合部の機械的性質と信頼性

Tohoku University小池淳一課

Properties and behaviour of Pb-free solders in flip-chip scale solder interconnections

Due to pending legislations and market pressure, lead-free solders will replace Sn–Pb solders in 2006. Among the lead-free solders being studied, eutectic Sn–Ag, Sn–Cu and Sn–Ag–Cu are promising candidates and Sn–3.8Ag–0.7Cu could be the most appropriate replacement due to its overall balance of properties. In order to garner more understanding of lead-free solders and their application in flip-chip scale packages, the properties of lead free solders, including the wettability, intermetallic compound (IMC) growth and distribution, mechanical properties, reliability and corrosion resistance, were studied and are presented in this thesis. [Continues.

The automated array assembly task of the low-cost silicon solar array project, phase 2

Several specific processing steps as part of a total process sequence for manufacturing silicon solar cells were studied. Ion implantation was identified as the preferred process step for impurity doping. Unanalyzed beam ion implantation was shown to have major cost advantages over analyzed beam implantation. Further, high quality cells were fabricated using a high current unanalyzed beam. Mechanically masked plasma patterning of silicon nitride was shown to be capable of forming fine lines on silicon surfaces with spacings between mask and substrate as great as 250 micrometers. Extensive work was performed on advances in plated metallization. The need for the thick electroless palladium layer was eliminated. Further, copper was successfully utilized as a conductor layer utilizing nickel as a barrier to copper diffusion into the silicon. Plasma etching of silicon for texturing and saw damage removal was shown technically feasible but not cost effective compared to wet chemical etching techniques

Peripheral soldering of flip chip joints on passive RFID tags

Flip chip is the main component of a RFID tag. It is used in billions each year in electronic packaging industries because of its small size, high performance and reliability as well as low cost. They are used in microprocessors, cell phones, watches and automobiles. RFID tags are applied to or incorporated into a product, animal, or person for identification and tracking using radio waves. Some tags can be read from several meters away or even beyond the line of sight of the reader. Passive RFID tags are the most common type in use that employ external power source to transmit signals. Joining chips by laser beam welding have wide advantages over other methods of joining, but they are seen limited to transparent substrates. However, connecting solder bumps with anisotropic conductive adhesives (ACA) produces majority of the joints. A high percentage of them fail in couple of months, particularly when exposed to vibration. In the present work, failure of RFID tags under dynamic loading or vibration was studied; as it was identified as one of the key issue to explore. Earlier investigators focused more on joining chip to the bump, but less on its assembly, i.e., attaching to the substrate. Either of the joints, between chip and bump or between antenna and bump can fail. However, the latter is more vulnerable to failure. Antenna is attached to substrate, relatively fixed when subjected to oscillation. It is the flip chip not the antenna moves during vibration. So, the joint with antenna suffers higher stresses. In addition to this, the strength of the bonding agent i.e., ACA also much smaller compared to the metallic bond at the other end of the bump. Natural frequency of RFID tags was calculated both analytically and numerically, found to be in kilohertz range, high enough to cause resonance. Experimental investigations were also carried out to determine the same. However, the test results for frequency were seen to be in hundred hertz range, common to some applications. It was recognized that the adhesive material, commonly used for joining chips, was primarily accountable for their failures. Since components to which the RFID tags are attached to experience low frequency vibration, chip joints fail as they face resonance during oscillation. Adhesives having much lower modulus than metals are used for attaching bumps to the substrate antennas, and thus mostly responsible for this reduction in natural frequency. Poor adhesive bonding strength at the interface and possible rise in temperature were attributed to failures under vibration. In order to overcome the early failure of RFID tag joints, Peripheral Soldering, an alternative chip joining method was devised. Peripheral Soldering would replace the traditional adhesive joining by bonding the peripheral surface of the bump to the substrate antenna. Instead of joining solder bump directly to the antenna, holes are to be drilled through antenna and substrate. S-bond material, a less familiar but more compatible with aluminum and copper, would be poured in liquid form through the holes on the chip pad. However, substrates compatible to high temperature are to be used; otherwise temperature control would be necessary to avoid damage to substrate. This S-bond would form metallic joints between chip and antenna. Having higher strength and better adhesion property, S-bond material provides better bonding capability. The strength of a chip joined by Peripheral Soldering was determined by analytical, numerical and experimental studies. Strength results were then compared to those of ACA. For a pad size of 60 micron on a 0.5 mm square chip, the new chip joints with Sbond provide an average strength of 0.233N analytically. Numerical results using finite element analysis in ANSYS 11.0 were about 1% less than the closed form solutions. Whereas, ACA connected joints show the maximum strength of 0.113N analytically and 0.1N numerically. Both the estimates indicate Peripheral Soldering is more than twice stronger than adhesive joints. Experimental investigation was carried out to find the strength attained with S-bond by joining similar surfaces as those of chip pad and antenna, but in larger scale due to limitation in facilities. Results obtained were moderated to incorporate the effect of size. Findings authenticate earlier predictions of superior strengths with S-bond. A comparison with ACA strength, extracted from previous investigations, further indicates that S-bond joints are more than 10 times stronger. Having higher bonding strength than in ACA joints, Peripheral Soldering would provide better reliability of the chip connections, i.e., RFID tags. The benefits attained would pay off complexities involved in tweaking

Study of intermetallic compound layer formation, growth and evaluation of shear strength of lead-free solder joints

Solder joints play a very important role in electronic products as the integrity of electronics packaging and assembly rests on the quality of these connections. The increasing demands for higher performance, lower cost, and miniaturisation in hand-held and consumer electronic products have led to the use of dense interconnections. This miniaturization trend means that solder joint reliability remains an important challenge with surface mount electronics assembly, especially those used in hostile environments, and applications such as automobile, aerospace and other safety critical operations. One of the most important factors which are known to affect solder joint reliability is the thickness of intermetallic compound (IMC) layer formed between the solder and the substrate. Although the formation of an IMC layer signifies good bonding between the solder and substrate, its main disadvantage is that it is also known to be the most brittle part of the solder joint. Thus as the miniaturisation trend continues, and solder joints become even smaller in size, the nature and impact of IMC layer thickness on solder joint reliability becomes even more of a concern with the introduction of new lead-free soldering. Other factors which are known to affect solder joint reliability include the bonding strength, the voiding percentage in joints, the size of the voids and their location within the joint. The work reported in this thesis on formation and growth of intermetallic compound layer, and evaluation of the shear strength of lead-free solder joints is divided into four main parts. The first part of the study is concerned with understanding of the effect of pad sizes on Inter-metallic compound layer formation and growth for lead-free solder joints. The second part concerns the study of the effect of temperature cycling and reflow profiles on intermetallic growth between Sn-Ag-Cu alloy and Cu substrate. The third part of the study concerns the investigation of the effect of reflow soldering profile optimization on solder volumes using design of experiment technique. The focus of the final part of the study is the investigation of the effect of Inter-metallic Compound thickness on shear strength of 1206 surface mount chip resistor. The results from the experimental work showed that the pad size has very little influence on the growth of the IMC. The result also shows that the growth of IMC depends on diffusion rate, temperature and time according to the power-law model; and that the IMC layer thickness is independent of pad size. The significance of this result is that with further reductions in joint size (with IMC layer thickness remaining the same), the ratio of the IMC layer thickness to solder joint size will increase and adversely impact the joint reliability. The work carried out on ageing temperatures and reflow profiles of Sn-Ag-Cu alloy and Cu substrate also showed the reaction-diffusion mechanism of intermetallic compound formation and growth in solder joints. The study also showed that the most significant factor in achieving lower IMC layer thickness and fine microstructures is the time to peak temperature of the reflow soldering process. The effect of IMC layer thickness on the shear strength of Sn-Ag-Cu solder joints was investigated. The relationship of shear strength, interfacial microstructures and fracture surfaces was considered. It is clear that formation of continuous Cu-Sn and SnNiCu layers are the reason for the weak interface strength. The results show that the shear strength of solder joints decreases with increasing ageing time. The results of this study have been disseminated through journal and conference publications and will be of interest to R&D personnel working in the area of high temperature electronics and in particular those working in the field of automotive electronics

Electrodeposition and characterisation of nickel-niobium-based diffusion barrier metallisations for high temperature electronics interconnections

The control of interfacial microstructural stability is of utmost importance to the reliability of liquid solder interconnects in high temperature electronic assemblies. This is primarily due to excessive intermetallic compounds (IMCs) that can form and continuously grow during high temperature operation, which practically renders conventional barrier metallisations inadequate. In this study, electrically conducting, NbOx containing Ni coatings were developed using electrodeposition. Their suitability as a solder diffusion barrier layer was assessed in terms of the electrical conductivity and barrier property. The present work explores a novel electrochemical route to produce Ni-NbOx composite coatings of good uniformity, compactness and purity, from non-aqueous glycol-based electrolytes consisting of NiCl2 and NbCl5 as metal precursors. The effects of cathodic current density and NaBH4 concentrations on the surface morphology, composition and thickness of the coatings were examined. A combined study of Scanning Transmission Electron Microscopy (STEM) and Electrochemical Quartz Crystal Microbalance (EQCM) was conducted to understand the fundamental aspects of this novel electrodeposition process. The composite coatings generally exhibited good electrical conductivity. The reaction behaviour between a liquid 52In-48Sn solder and Ni-NbOx, with Nb contents up to 6 at.%, were studied at 200ºC. The results indicate that, Ni-NbOx with sufficient layer thickness and higher Nb content, offered longer service lifetime. Nb enrichment was generally observed at or close to the reaction front after high temperature storage, which suggests evident effectiveness of the enhanced diffusion barrier characteristics

PCB Quality Metrics that Drive Reliability (PD 18)

Risk based technology infusion is a deliberate and systematic process which defines the analysis and communication methodology by which new technology is applied and integrated into existing and new designs, identifies technology development needs based on trends analysis and facilitates the identification of shortfalls against performance objectives. This presentation at IPC Works Asia Aerospace 2019 Events provides the audience a snapshot of quality variations in printed wiring board quality, as assessed, using experiences in processing and risk analysis of PWB structural integrity coupons. The presentation will focus on printed wiring board quality metrics used, the relative type and number of non-conformances observed and trend analysis using statistical methods. Trend analysis shows the top five non-conformances observed across PWB suppliers, the root cause(s) behind these non-conformance and suggestions of mitigation plans. The trends will then be matched with the current state of the PWB supplier base and its challenges and opportunities. The presentation further discusses the risk based SMA approaches and methods being applied at GSFC for evaluating candidate printed wiring board technologies which promote the adoption of higher throughput and faster processing technology for GSFC missions