4,484 research outputs found

    KYT2022 Finnish Research Programme on Nuclear Waste Management 2019–2022 : Final Report

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    KYT2022 (Finnish Research Programme on Nuclear Waste Management 2019–2022), organised by the Ministry of Economic Affairs and Employment, was a national research programme with the objective to ensure that the authorities have sufficient levels of nuclear expertise and preparedness that are needed for safety of nuclear waste management. The starting point for public research programs on nuclear safety is that they create the conditions for maintaining the knowledge required for the continued safe and economic use of nuclear energy, developing new know-how and participating in international collaboration. The content of the KYT2022 research programme was composed of nationally important research topics, which are the safety, feasibility and acceptability of nuclear waste management. KYT2022 research programme also functioned as a discussion and information-sharing forum for the authorities, those responsible for nuclear waste management and the research organizations, which helped to make use of the limited research resources. The programme aimed to develop national research infrastructure, ensure the continuing availability of expertise, produce high-level scientific research and increase general knowledge of nuclear waste management

    A Decision Support System for Economic Viability and Environmental Impact Assessment of Vertical Farms

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    Vertical farming (VF) is the practice of growing crops or animals using the vertical dimension via multi-tier racks or vertically inclined surfaces. In this thesis, I focus on the emerging industry of plant-specific VF. Vertical plant farming (VPF) is a promising and relatively novel practice that can be conducted in buildings with environmental control and artificial lighting. However, the nascent sector has experienced challenges in economic viability, standardisation, and environmental sustainability. Practitioners and academics call for a comprehensive financial analysis of VPF, but efforts are stifled by a lack of valid and available data. A review of economic estimation and horticultural software identifies a need for a decision support system (DSS) that facilitates risk-empowered business planning for vertical farmers. This thesis proposes an open-source DSS framework to evaluate business sustainability through financial risk and environmental impact assessments. Data from the literature, alongside lessons learned from industry practitioners, would be centralised in the proposed DSS using imprecise data techniques. These techniques have been applied in engineering but are seldom used in financial forecasting. This could benefit complex sectors which only have scarce data to predict business viability. To begin the execution of the DSS framework, VPF practitioners were interviewed using a mixed-methods approach. Learnings from over 19 shuttered and operational VPF projects provide insights into the barriers inhibiting scalability and identifying risks to form a risk taxonomy. Labour was the most commonly reported top challenge. Therefore, research was conducted to explore lean principles to improve productivity. A probabilistic model representing a spectrum of variables and their associated uncertainty was built according to the DSS framework to evaluate the financial risk for VF projects. This enabled flexible computation without precise production or financial data to improve economic estimation accuracy. The model assessed two VPF cases (one in the UK and another in Japan), demonstrating the first risk and uncertainty quantification of VPF business models in the literature. The results highlighted measures to improve economic viability and the viability of the UK and Japan case. The environmental impact assessment model was developed, allowing VPF operators to evaluate their carbon footprint compared to traditional agriculture using life-cycle assessment. I explore strategies for net-zero carbon production through sensitivity analysis. Renewable energies, especially solar, geothermal, and tidal power, show promise for reducing the carbon emissions of indoor VPF. Results show that renewably-powered VPF can reduce carbon emissions compared to field-based agriculture when considering the land-use change. The drivers for DSS adoption have been researched, showing a pathway of compliance and design thinking to overcome the ‘problem of implementation’ and enable commercialisation. Further work is suggested to standardise VF equipment, collect benchmarking data, and characterise risks. This work will reduce risk and uncertainty and accelerate the sector’s emergence

    The Adirondack Chronology

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    The Adirondack Chronology is intended to be a useful resource for researchers and others interested in the Adirondacks and Adirondack history.https://digitalworks.union.edu/arlpublications/1000/thumbnail.jp

    Synthesis and Characterisation of Low-cost Biopolymeric/mineral Composite Systems and Evaluation of their Potential Application for Heavy Metal Removal

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    Heavy metal pollution and waste management are two major environmental problems faced in the world today. Anthropogenic sources of heavy metals, especially effluent from industries, are serious environmental and health concerns by polluting surface and ground waters. Similarly, on a global scale, thousands of tonnes of industrial and agricultural waste are discarded into the environment annually. There are several conventional methods to treat industrial effluents, including reverse osmosis, oxidation, filtration, flotation, chemical precipitation, ion exchange resins and adsorption. Among them, adsorption and ion exchange are known to be effective mechanisms for removing heavy metal pollution, especially if low-cost materials can be used. This thesis was a study into materials that can be used to remove heavy metals from water using low-cost feedstock materials. The synthesis of low-cost composite matrices from agricultural and industrial by-products and low-cost organic and mineral sources was carried out. The feedstock materials being considered include chitosan (generated from industrial seafood waste), coir fibre (an agricultural by-product), spent coffee grounds (a by-product from coffee machines), hydroxyapatite (from bovine bone), and naturally sourced aluminosilicate minerals such as zeolite. The novel composite adsorbents were prepared using commercially sourced HAp and bovine sourced HAp, with two types of adsorbents being synthesized, including two- and three-component composites. Standard synthetic methods such as precipitation were developed to synthesize these materials, followed by characterization of their structural, physical, and chemical properties (by using FTIR, TGA, SEM, EDX and XRD). The synthesized materials were then evaluated for their ability to remove metal ions from solutions of heavy metals using single-metal ion type and two-metal ion type solution systems, using the model ion solutions, with quantification of their removal efficiency. It was followed by experimentation using the synthesized adsorbents for metal ion removal in complex systems such as an industrial input stream solution system obtained from a local timber treatment company. Two-component composites were considered as control composites to compare the removal efficiency of the three-component composites against. The heavy metal removal experiments were conducted under a range of experimental conditions (e.g., pH, sorbent dose, initial metal ion concentration, time of contact). Of the four metal ion systems considered in this study (Cd2+, Pb2+, Cu2+ and Cr as chromate ions), Pb2+ ion removal by the composites was found to be the highest in single-metal and two-metal ion type solution systems, while chromate ion removal was found to be the lowest. The bovine bone-based hydroxyapatite (bHAp) composites were more efficient at removing the metal cations than composites formed from a commercially sourced hydroxyapatite (cHAp). In industrial input stream solution systems (containing Cu, Cr and As), the Cu2+ ion removal was the highest, which aligned with the observations recorded in the single and two-metal ion type solution systems. Arsenate ion was removed to a higher extent than chromate ion using the three-component composites, while the removal of chromate ion was found to be higher than arsenate ion when using the two-component composites (i.e., the control system). The project also aimed to elucidate the removal mechanisms of these synthesized composite materials by using appropriate adsorption and kinetic models. The adsorption of metal ions exhibited a range of adsorption behaviours as both the models (Langmuir and Freundlich) were found to fit most of the data recorded in different adsorption systems studied. The pseudo-second-order model was found to be the best fitted to describe the kinetics of heavy metal ion adsorption in all the composite adsorbent systems studied, in single-metal ion type and two-metal ion type solution systems. The ion-exchange mechanism was considered as one of the dominant mechanisms for the removal of cations (in single-metal and two-metal ion type solution systems) and arsenate ions (in industrial input stream solution systems) along with other adsorption mechanisms. In contrast, electrostatic attractions were considered to be the dominant mechanism of removal for chromate ions

    Diversity, Importance and Decline of Pollinating Insects in Present Era

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    Pollination is a multi-million-year-old co-evolutionary process involving flowering plants and pollinators. It is one of the most important mechanisms in preservation and promotion of biodiversity as well as life on Earth. Pollinator diversity is essential for maintaining overall biological diversity in many habitats including agro-ecosystems. Pollinators are responsible for assisting reproduction in over 80% of the world’s flowering plants. In their absence, humans and wildlife would go hungry. Insects are the most efficient pollinators as they play a crucial part in pollination ecology. Pollinators and their habitats have ecological, economic, cultural and social benefits. Pollination efficiency is highly dependent on certain attributes and characteristics of pollinators such as vision, anatomy, food preferences, olfaction, behaviour and learning ability. With the rapid growth of human population, our demand for food has also risen. Our agricultural systems will need to produce more food in a sustainable manner in the future to cope with this. Pollinators play an important role in these ecosystems and will continue to do so in the future. Because pollinators are so important to agriculture, we need to learn more about which crops require specific pollinators and how to best maintain and promote both wild and controlled species. Their diversity needs protection because there are specific relationships between certain crops and pollinators. Pollinator communities are suffering as a result of man-made habitat disruptions, including severe biodiversity loss. This diversity must be protected by combining conservation measures with sustainable farming practices which could increase crop yields while protecting insect pollinator species

    To what extent can de-extinction be theologically and morally justified?

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    No longer condemned to the realms of science-fiction, de-extinction projects across the globe continue to excavate the very real possibilities for restoring lost creatures to the biosphere. From ambitious endeavours to resurrect the mammoth to the manipulation of genetic codes in order to ‘back-breed’ other species, it is clear to see why such projects capture the imagination. This thesis will seek to address the key concerns raised by the issue from a theological standpoint as well as engaging with the ethical dimension elicited by such engagement. The theology of de-extinction is an area that has not seen overly extensive research in the discipline and one of the aims of this project will be to establish a framework for the theological vocation in relation to the restoration of lost species. This will be guided by an engagement with thinkers from across the Christian theological spectrum such as Schaefer, Southgate, McLaughlin and Jenkins. Additionally, a survey and critical engagement with theological ethics will argue that a theocentric approach, akin to that developed by James Gustafson, offers the most attractive and adaptable approach to the issue, as well as to our relationship to the wider creation. The project will conclude that whilst de-extinction could well be sanctioned under the theological vocation, theocentric ethics would counsel restraint, for the time being

    THE DREAM OF A ZERO WASTE SOCIETY: EXPLORING THE PRACTICES AND BEHAVIOURS OF WASTE GENERATION IN GREATER MEXICO CITY

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    This research aims to re-conceptualise consumption and waste generation through a broader set of theoretical questions and analytical methodologies to establish a more holistic theoretical framework for comprehending the global South's "waste crisis." This thesis is primarily based on the following question: "why do we dispose of things?". By focusing on practices and behaviours of consumption and disposal by citizens of GMC, this thesis seeks to unpack the networks, symbols, skills, and meanings of these practices. This moves the conceptualisation of waste generation away from being conceived as an irremediable consequence of population growth or as primary responsibility on the consumers' shoulders. Therefore, this thesis proposes that consumers are embedded in a "throwaway environment" that pushes them toward unsustainable practices. However, this does not mean that the consumers have a "throwaway culture"; consumers might be "carriers" of practices, but they are still active participants. By unravelling the multiple layers of framing that aggregate into the consumption and disposal of citizens in GMC, we shall see how GMC society's historical, social, and political framework serves as dispositions that guide an individual to act. This study focuses on modifying the narrative of considering consumers as careless, lazy, or consumption-driven. It also sheds light on how ignoring these behaviours and practices will only bring temporary and reactionary solutions when dealing with waste. This dissertation also offers an analytical framework that explores how consumers' elements interrelate and are synergetic. By re-conceptualising consumption and waste generation, I propose not focusing on the insidious moral narrative of whether consumption and disposal are acceptable and to what degree. Instead, we should concentrate on a policy strategy that will help reduce the flow of materials. As a result, we might be able to curve a waste crisis by accepting shared responsibility (mostly borne by governments and businesses

    Examining the Potential for Isotope Analyses of Carbon, Nitrogen, and Sulphur in Burned Bone from Experimental and Archaeological Contexts.

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    The aim of this project was to determine whether isotope analyses of carbon, nitrogen and sulphur can be conducted on collagen extracted from burned bone. This project was conducted in two phases: a controlled heating experiment and an archaeological application. The controlled heating experiment used cow (Bos taurus) bone to test the temperature thresholds for the conservation of δ13C, δ15N, and δ34S values. These samples were also used to test the efficacy of Fourier Transform Infrared spectroscopy (FTIR) and colour analysis, for determining the burning intensities experienced by bone burned in unknown conditions. The experiment showed that δ13C values were relatively unchanged up to 400°C (<2‰ variation), while δ15N values were relatively stable up to 200°C (0.5‰ variation). Values of δ34S were also relatively stable up to 200°C (1.4‰ variation). Colour change and FTIR data were well correlated with the change in isotope ratios. Models estimating burning intensities were created from the FTIR data. For the archaeological application, samples were selected from two early Anglo-Saxon cemetery sites: Elsham and Cleatham. Samples were selected from both inhumed and cremated individuals. Among the inhumed individuals δ13C values suggested a C3 terrestrial diet and δ15N values suggested protein derived largely from terrestrial herbivores, as expected for the early Anglo-Saxon period. However, δ34S values suggested the consumption of freshwater resources and that this consumption was related to both the age and sex of the individual. The experimental data shows that there is potential for isotope analyses of cremated remains, as during the cremation process heat exposures are not uniform across the body. The samples selected for the archaeological application, however, were not successful. Bone samples heated in controlled conditions produced viable collagen for isotope analysis; however, there are several differences between experiments conducted in a muffle furnace and open-air pyre cremation that need to be investigated further. Additionally, the influence of taphonomy on collagen survival in burned bone needs to be quantified. Finally, methods of sample selection need to be improved to find bone samples from archaeologically cremated remains that are most likely to retain viable collagen. While there is significant research that must be conducted before this research can be widely applied there are a multitude of cultures that practised cremation throughout history and around the world that could be investigated through the analyses proposed in this project
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