Flexible and Stretchable Electronics

Flexible and stretchable electronics are receiving tremendous attention as future electronics due to their flexibility and light weight, especially as applications in wearable electronics. Flexible electronics are usually fabricated on heat sensitive flexible substrates such as plastic, fabric or even paper, while stretchable electronics are usually fabricated from an elastomeric substrate to survive large deformation in their practical application. Therefore, successful fabrication of flexible electronics needs low temperature processable novel materials and a particular processing development because traditional materials and processes are not compatible with flexible/stretchable electronics. Huge technical challenges and opportunities surround these dramatic changes from the perspective of new material design and processing, new fabrication techniques, large deformation mechanics, new application development and so on. Here, we invited talented researchers to join us in this new vital field that holds the potential to reshape our future life, by contributing their words of wisdom from their particular perspective

Additively Manufactured Shape-changing RF Devices Enabled by Origami-inspired Structures

The work to be presented in this dissertation explores the possibility of implementing origami-inspired shape-changing structures into RF designs to enable continuous performance tunability as well as deployability. The research not only experimented novel structures that have unique mechanical behaviour, but also developed automated additive manufacturing (AM) fabrication process that pushes the boundary of realizable frequency from Sub-6 GHz to mm-wave. High-performance origami-inspired reconfigurable frequency selective surfaces (FSSs) and reflectarray antennas are realized for the first time at mm-wave frequencies via AM techniques. The research also investigated the idea of combining mechanical tuning and active tuning methods in a hybrid manner to realize the first truly conformal beam-forming phased array antenna that can be applied onto any arbitrary surface and can be re-calibrated with a 3D depth camera.Ph.D

SMART MATERIALS FOR STRETCHABLE ELECTRONICS, SENSORS AND SOFT ACTUATION

Smart materials can be exploited to facilitate disruptive or transformative changes in several fields like stretchable electronics, soft robotics or to develop new class of sensors. They are innovative materials that interact with the environment and respond to external stimuli altering their physical properties in a controlled fashion. They are made integrating different materials at the nanoscale in a nanocomposite to obtain novel functionalities that are not showed from individual constituents. Polymers are the best candidates to be used in smart material fabrication because of their structural and functional properties that can be easily tuned. Moreover, they are low-cost, versatile and can be processed into any shape including thin films. In order to exploit smart materials for soft robotics or stretchable electronic applications, it is required that they should be electrically conductive, patternable, have good mechanical properties and need to be able to transduce an electrical signal in a mechanical response. In addition, their functionalities should remain unchanged over a long period of time. Thus polymers are combined with hard materials like metals, semiconductors or standard electronic components. It is challenging to fabricate technologically relevant smart materials combining hard and soft materials because of their intrinsic physical diversities. Standard manufacturing processes fail to achieve the needed requirements. Among different processes to fabricate smart materials based on polymers, Supersonic Cluster Beam Implantation (SCBI) and Supersonic Cluster Beam Deposition (SCBD) are effective techniques to realize smart materials based on metal/polymer nanocomposites. In my thesis work, I have demonstrated that it is possible to produce new robust smart materials, designing both their electrical and mechanical properties with sharp precision. Metal/polymer nanocomposites have been designed at the nanoscale level to obtain sensors, actuators and electronic devices. Their electrical and mechanical properties have been characterized and their performances have been tested under different stress conditions

연성 및 생재흡수성 전자소자용 비휘발성 메모리 소자와 집적센서 구현

학위논문 (박사)-- 서울대학교 대학원 : 화학생물공학부, 2015. 8. 김대형.Over years, major advances in healthcare have been made through research in the fields of nanomaterials and microelectronics technologies. However, the mechanical and geometrical constraints inherent in the standard forms of rigid electronics have imposed challanges of unique integration and therapeutic delivery in non-invasive and minimally invasive medical devices. Here, we describe two types of multifunctional electronic systems. The first type is wearable-on-the-skin systems that address the challenges via monolithic integration of nanomembranes fabricated by top-down approach, nanotubes and nanoparticles assembled by bottom-up strategies, and stretchable electronics on tissue-like polymeric substrate. The system consists of physiological sensors, non-volatile memory, logic gates, and drug-release actuators. Some quantitative analyses on the operation of each electronics, mechanics, heat-transfer, and drug-diffusion characteristic validated their system-level multi-functionalities. The second type is a bioresorbable electronic stent with drug-infused functionalized nanoparticles that takes flow sensing, temperature monitoring, data storage, wireless power/data transmission, inflammation suppression, localized drug delivery, and photothermal therapy. In vivo and ex vivo animal experiments as well as in vitro cell researches demonstrate its unrecognized potential for bioresorbable electronic implants coupled with bioinert therapeutic nanoparticles in the endovascular system. As demonstrations of these technologies, we herein highlight two representative examples of multifunctional systems in order of increasing degree of invasiveness: electronically enabled wearable patch and endovascular electronic stent that incorporate onboard physiological monitoring, data storage, and therapy under moist and mechanically rigorous conditions.Contents Abstract Chapter 1. Introduction 1.1 Organic flexible and wearable electronics.................................................. 1 1.2 Inorganic flexible and wearable electronics............................................... 14 1.3 Flexible non-volatile memory devices.......................................................... 25 1.4 Bioresorbable materials and devices........................................................... 34 References Chapter 2. Multifunctional wearable devices for diagnosis and therapy of movement disorders 2.1 Introduction ................................................................................. 45 2.2 Experimental Section ......................................................................... 49 2.3 Result and Discussion ........................................................................ 65 2.4 Conclusion ................................................................................... 95 References Chapter 3. Stretchable Carbon Nanotube Charge-Trap Floating-Gate Memory and Logic Devices for Wearable Electronics 3.1 Introduction ................................................................................ 101 3.2 Experimental Section ........................................................................ 104 3.3 Result and Discussion ....................................................................... 107 3.4 Conclusion .................................................................................. 138 References Chapter 4. Bioresorbable Electronic Stent Integrated with Therapeutic Nanoparticles for Endovascular Diseases 4.1 Introduction ................................................................................ 148 4.2 Experimental Section ........................................................................ 151 4.3 Result and Discussion ....................................................................... 173 4.4 Conclusion .................................................................................. 219 References 국문 초록 (Abstract in Korean) .................................................................. 230Docto

Hybrid Nanomaterials

Two of the hottest research topics today are hybrid nanomaterials and flexible electronics. As such, this book covers both topics with chapters written by experts from across the globe. Chapters address hybrid nanomaterials, electronic transport in black phosphorus, three-dimensional nanocarbon hybrids, hybrid ion exchangers, pressure-sensitive adhesives for flexible electronics, simulation and modeling of transistors, smart manufacturing technologies, and inorganic semiconductors

Laser-assisted processing of multilayer films for inexpensive and flexible biomedical microsystems

Flexible/stretchable electronics offer ideal properties for emerging health monitoring devices that can seamlessly integrate with the soft, curvilinear, and dynamic surfaces of the human body. The resulting capabilities have allowed novel devices for monitoring physiological parameters, improving surgical procedures, and human-machine interfaces. While the attractiveness of these devices are indubitable, their fabrication by conventional cleanroom techniques makes them expensive and incompatible with rapid large-scale (e.g., roll-to-roll) production. The purpose of this research is to develop inexpensive fabrication technologies using low-cost commercial films such as polyimide, paper, and metalized paper that can be utilized for developing various flexible/stretchable physical and chemical sensors for wearable and lab-on-chip applications. The demonstrated techniques focus on an array of laser assisted surfaces modification and micromachining strategies with the two commonly used CO2 and Nd: YAG laser systems. The first section of this dissertation demonstrates the use of localized pulsed CO2 laser irradiation to selectively convert thermoset polymer films (e.g., polyimide) into electrically conductive highly porous carbon micro/nanostructures.Thisprocessprovidesauniqueandfacileapproachfordirect writing of carbonized conductive patterns on flexible polyimide sheets in ambient conditions, eliminating complexities of current methods such as expensive CVD processes and complicated formulation/preparation of conductive carbon based inks used in ink jet printing. The highly porous laser carbonized layer can be transferred to stretchable elastomer or further functionalized with various chemical substances such as ionic solutions, nanoparticles, and chemically conductive polymers to create different mechanical and chemical sensors. The second section of this dissertation describes the use of laser ablation for selective removal of material from multilayer films such as ITO-coated PET, parchment paper, and metalized paper to create disposable diagnostic platforms and in-vitro models for lab-on-chip based studies. The ablated areas were analyzed using electrical, mechanical, and surface analysis tools to understand change in physical structure and chemical properties of the laser ablated films. As proof-of-concept demonstrations of these technologies, four different devices are presented here: mechanical, electrochemical, and environmental sensors along with an in-vitro cell culture platform. All four devices are designed, fabricated, and characterized to highlight the capability of commercial laser processing systems in the production of the next generation, low-cost and flexible biomedical devices

Soft Electronics and Sensors for Wearable Healthcare Applications

Wearable electronics are becoming increasingly essential to personalized medicine by collecting and analyzing massive amounts of biological signals from internal organs, muscles, and blood vessels. Conventional rigid electronics may lead to motion artifacts and errors in collected data due to the mismatches in mechanical properties between human skin. Instead, soft wearable electronics provide a better platform and interface that can form intimate contact and conformably adapt to human skin. In this respect, this thesis focuses on new materials formulation, fabrication, characterization of low-cost, high sensitivity and reliable sensors for wearable health monitoring applications. More specifically, we have studied the silver nanoparticles (AgNPs) inkjet-printed on a polydimethylsiloxane (PDMS) substrate that offers great pressure sensitivity for aterial pulse monitoring. In addition, we have investigated the conducting polymer poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) and poly(ethylene oxide) PEO polymer blends that exhibit low sheet resistance and can resist up to 50\% of tensile strain. The highly stretchable thin film can serve as interconnects between electronic components and dry electrodes for photoplethysmography (PPG) and electrocardiography (ECG) recordings. Based on the developed PEDOT:PSS solution with high conductivity, we fabricated a porous PDMS sponge coated with conductive PEDOT:PSS to make electrodes with reduced electrode-skin contact impedance, improved signal-to-noise ratio and is suited for long-term and motion-artifact-tolerant recording of high quality biopotential signals including ECG and electromyography (EMG). Finally, we demonstrated a multimodal sensor based on the porous PEDOT:PSS/PDMS sponge for sensing and distinguishing of pressure, strain and temperature from different trends in resistance and capacitance response. Applications including object detection, gesture recognition and temperature sensing have all been demonstrated. In this thesis, the proposed materials, sensor design, low-cost inkjet printing and dip-coating fabrication process open the possibility for more complex epidermal wearable health monitoring electronic systems

Automated Roll-To-Roll Fluidic Self-Assembly Of Microscopic Inorganic Semiconductor Chips For Applications Of Macroelectronics

University of Minnesota Ph.D. dissertation. June 2015. Major: Electrical Engineering. Advisor: Heiko Jacobs. 1 computer file (PDF); vii, 115 pages.This paper presents the implementation of an automated roll-to-roll fluidic self-assembly system based on surface tension driven self-assembly with applications in the field of macroelectronics. The reported system incorporates automated agitation, web motion, component dispensing, and recycling. The process enables the assembly and electrical connection of semiconductor dies/chips in a continuous and parallel fashion over wide area substrates. At present the method achieves an assembly rate of 15,000 chips per hour and an assembly yield exceeding 99%. The identification and modeling of the relationship between process parameters and forces on one side and assembly rates, detachment rates, error rates, and yield on the other is discussed as it lead to the discovery of the reported design. As an application we demonstrate the realization of a solid state lighting module. This particular application requires the assembly of a conductive multilayer sandwich structure which is achieved by combining the introduced assembly process with a novel lamination step. We also have demonstrated rubber-like solid-state-lighting module using developed process

A low cost direct writing process for flexible circuit and interconnect fabrication

This thesis investigates the development of a low cost fabrication process for flexible electronics and interconnects. By using a ‘direct writing’ process, the use of vacuum-­‐based metal evaporation and photoresist steps is not necessary and so less complex equipment is needed. The process forms silver embedded on top of a polyimide substrate and was first tested using a UV laser to perform writing before switching to a blue laser due to excessive substrate degradation observed from UV exposures. The blue light was combined with a biologically friendly photo reducing agent, which was found to be much more efficient at the creation of silver. The methods of silver formation by various means are the main focus of investigation in this thesis but process expansion and improvement were the main goals. To this end, a chemical, rather than light-­‐based, process for silver creation was found to produce more consistent silver coatings, however the patterning by this method was found to be more challenging. The process was also extended to a different substrate in polyetherimide