Occurrence of metolachlor and trifluralin losses in the Save river agricultural catchment during floods

Rising pesticide levels in streams draining intensively managed agricultural land have a detrimental effect on aquatic ecosystems and render water unfit for human consumption. The Soil and Water Assessment Tool (SWAT) was applied to simulate daily pesticide transfer at the outlet from an agriculturally intensive catchment of 1110 km2 (Save river, south-western France). SWAT reliably simulated both dissolved and sorbed metolachlor and trifluralin loads and concentrations at the catchment outlet from 1998 to 2009. On average, 17 kg of metolachlor and 1 kg of trifluralin were exported at outlet each year, with annual rainfall variations considered. Surface runoff was identified as the preferred pathway for pesticide transfer, related to the good correlation between suspended sediment exportation and pesticide, in both soluble and sorbed phases. Pesticide exportation rates at catchment outlet were less than 0.1% of the applied amount. At outlet, SWAT hindcasted that (i) 61% of metolachlor and 52% of trifluralin were exported during high flows and (ii) metolachlor and trifluralin concentrations exceeded European drinking water standards of 0.1 µg L−1 for individual pesticides during 149 (3.6%) and 17 (0.4%) days of the 1998–2009 period respectively. SWAT was shown to be a promising tool for assessing large catchment river network pesticide contamination in the event of floods but further useful developments of pesticide transfers and partition coefficient processes would need to be investigated

Rapid Assessment of Intertidal Wetland Sediments

Urbanization of coastal areas poses a severe threat to ecologically valuable intertidal wetlands. This paper presents a pragmatic approach called Rapid Assessment for Intertidal Wetland Sediments (RAITWS) for evaluating the sediment quality of intertidal wetlands. RAITWS involves construction of reference groups, selection of a subset of environmental variables, matching of test sites to reference groups, prediction of the benthic fauna community structure (e. g. of macroinvertebrates) at test sites, evaluation of the Observation to Expectation ratio (O/E ratio), quantification of environmental variables with series of dynamic numerical models, and interpretation of the O/E findings. The proposed method extends the existing rapid biological assessment approach from static to dynamic applications. In particular, RAITWS provides a fast method of assessing intertidal wetland sites which are undergoing ecological change due to nearby coastal development.Environmental SciencesSCI(E)EI0ARTICLE5574-5852

Quantifying temporal and spatial variations in sediment, nitrogen and phosphorus transport in stream inflows to a large eutrophic lake

High-frequency sampling of two major stream inflows to a large eutrophic lake (Lake Rotorua, New Zealand) was conducted to measure inputs of total suspended sediment (TSS), and fractions of nitrogen and phosphorus (P). A total of 17 rain events were sampled, including three during which both streams were simultaneously monitored to quantify how concentration–discharge (Q) relationships varied between catchments during similar hydrological conditions. Dissolved inorganic nitrogen (DIN) concentrations declined slightly during events, reflecting dilution of groundwater inputs by rainfall, whereas dissolved inorganic P (PO₄–P) concentrations were variable and unrelated to Q, suggesting dynamic sorptive behaviour. Event loads of total nitrogen (TN) were predominantly DIN, which is available for immediate uptake by primary producers, whereas total phosphorus (TP) loads predominantly comprised particulate P (less labile). Positive correlations between Q and concentrations of TP (and to a lesser extent TN) reflected increased particulate nutrient concentrations at high flows. Consequently, load estimates based on hourly Q during storm events and concentrations of routine monthly samples (mostly base flow) under-estimated TN and TP loads by an average of 19% and 40% respectively. Hysteresis with Q was commonly observed and inclusion of hydrological variables that reflect Q history in regression models improved predictions of TN and TP concentrations. Lorenz curves describing the proportions of cumulative load versus cumulative time quantified temporal inequality in loading. In the two study streams, 50% of estimated two-year loads of TN, TP and TSS were transported in 202–207, 76–126 and 1–8 days respectively. This study quantifies how hydrological and landscape factors can interact to influence pollutant flux at the catchment scale and highlights the importance of including storm transfers in lake loading estimates

Dynamics of suspended sediment transport and yield in a large agricultural catchment, southwest France

The dynamics of suspended sediment transport were monitored continuously in a large agricultural catchment in southwest France from January 2007 to March 2009. The objective of this paper is to analyse the temporal variability in suspended sediment transport and yield in that catchment. Analyses were also undertaken to assess the relationships between precipitation, discharge and suspended sediment transport, and to interpret sediment delivery processes using suspended sediment-discharge hysteresis patterns. During the study period, we analysed 17 fl ood events, with high resolution suspended sediment data derived from continuous turbidity and automatic sampling. The results revealed strong seasonal, annual and inter-annual variability in suspended sediment transport. Sediment was strongly transported during spring, when frequent fl ood events of high magnitude and intensity occurred. Annual sediment transport in 2007 yielded 16 614 tonnes, representing 15 t km−2 (85% of annual load transport during fl oods for 16% of annual duration), while the 2008 sediment yield was 77 960 tonnes, representing 70 t km−2 (95% of annual load transport during fl oods for 20% of annual duration). Analysis of the relationships between precipitation, discharge and suspended sediment transport showed that there were signifi cant correlations between total precipitation, peak discharge, total water yield, fl ood intensity and sediment variables during the fl ood events, but no relationship with antecedent conditions. Flood events were classifi ed in relation to suspended sediment concentration (SSC)–discharge hysteretic loops, complemented with temporal dynamics of SSC–discharge ranges during rising and falling fl ow. The hysteretic shapes obtained for all flood events refl ected the distribution of probable sediment sources throughout the catchment. Regarding the sediment transport during all fl ood events, clockwise hysteretic loops represented 68% from river deposited sediments and nearby source areas, anticlockwise 29% from distant source areas, and simultaneity of SSC and discharge 3%

Assessment of hydrology, sediment and particulate organic carbon yield in a large agricultural catchment using the SWAT model

The Soil and Water Assessment Tool (SWAT, 2005) was used to simulate discharge and sediment transport at daily time steps within the intensively farmed Save catchment in south-west France (1110 km2). The SWAT model was applied to evaluate catchment hydrology and sediment and associated particulate organic carbon yield using historical flow and meteorological data for a 10-years (January 1999–March 2009). Daily data on sediment (27 months, January 2007–March 2009) and particular organic carbon (15 months, January 2008–March 2009) were used to calibrate the model. Data on management practices (crop rotation, planting date, fertiliser quantity and irrigation) were included in the model during the simulation period of 10 years. Simulated daily discharge, sediment and particulate carbon values matched the observed values satisfactorily. The model predicted that mean annual catchment precipitation for the total study period (726 mm) was partitioned into evapotranspiration (78.3%), percolation/groundwater recharge (14.1%) and abstraction losses (0.5%), yielding 7.1% surface runoff. Simulated mean total water yield for the whole simulation period amounted to 138 mm, comparable to the observed value of 136 mm. Simulated annual sediment yield ranged from 4.3 t km−2 y−1 to 110 t km−2 y−1 (annual mean of 48 t km−2 y−1). Annual yield of particulate organic carbon ranged from 0.1 t km−2 y−1 to 2.8 t km−2 y−1 (annual mean of 1.2 t km−2 y−1). Thus, the highest annual sediment and particulate carbon yield represented 25 times the minimum annual yield. However, the highest annual water yield represented five times the minimum (222 mm and 51 mm, respectively). An empirical correlation between annual water yield and annual sediment and organic carbon yield was developed for this agricultural catchment. Potential source areas of erosion were also identified with the model. The range of the annual contributing erosive zones varied spatially from 0.1 to 6 t ha−1 according to the slope and agricultural practices at the catchment scale

Quantifying stream phosphorus dynamics and total suspended sediment export in forested watersheds in Vermont

Globally the quantity of reactive phosphorus (P) in soils, streams and groundwater has greatly increased throughout the 20th and early 21st centuries. This phenomenon is problematic in Vermont, evidenced by the repeated cyanobacteria blooms in shallow bays in Lake Champlain. While many studies have focused on P dynamics in agricultural watersheds, there is limited information on P dynamics in forested watersheds. Current remediation plans under the Lake Champlain total maximum daily loads (TMDL) call for substantial reductions in P loadings from forested areas of the basin. However, the lack of information and knowledge regarding forest P dynamics limits management and remediation plans. This study was conducted in three small forested watersheds, ranging in size from 2.5 to 8.3 square kilometers that have been managed under varying practices, including logging and maple sugaring. All three watersheds drain into Missisquoi Bay, a shallow bay in Lake Champlain that consistently has seasonal algal blooms. Streams in the forested watersheds were instrumented with turbidity sensors and pressure transducers to measure stage. A rating curve was developed during field visits to relate stage to discharge. Water samples were collected from May through November 2017 using ISCO Automated Samplers. A total of twenty storm events were captured, along with periodic baseflow sampling, and these data were used to characterize P concentrations and calculate seasonal P loadings. Results indicate that there is a strong positive relationship between turbidity, total suspended sediment and total phosphorus concentrations (R2 ranging from 0.64 to 0.83). The results of this project provide insight into transport of P and total suspended sediment within forested catchments of Lake Champlain tributaries. In particular, the research shows that fluxes in total phosphorus are linked to fluxes in total suspended sediment and that the overall monthly totals of P being exported from forested catchments are low, relative to urban, suburban and agricultural areas

Clarification Of Aqueous Suspensions With A High Content Of Suspended Solids In Rapid Sand Filters

The presented work is devoted to solving the actual problem of increasing the efficiency of rapid sand filters with granular filling, which operate at a constant filtration rate when cleaning suspensions with a relatively high concentration of contaminants. The proposed mathematical model for clarifying the suspension by filtration consists of three interconnected blocks: clarified, filtration, and hydraulic. Convenient dimensionless mathematical dependencies are obtained for calculating the concentrations of contaminants and sediment from the height of the filter and suspension in the filtrate; head loss in the filter loading; the effective time of the filter (the duration of the filter cycle). The design of the experimental setup and the methodology for conducting experimental studies and mathematical processing of the results are valid. The results of experimental studies of the suspension filtering process through the granular loading are presented, and the obtained data is analyzed. Measurement of pressure losses in the filter loading is performed when a suspension is passed with a relatively high concentration of contaminants at various filtration rates. The nature of the change in the filtration rate with time and height (length) loading at various filtration rates and initial contamination concentrations is determined. Measured variable concentration of suspended matter in filtered water and retained contamination over time. As a result of the experiments, it is confirmed that an increase in the concentration of retained contaminants S leads to an increase in the parameter Δn/n. Upon reaching a certain value of the concentration of the retained sediment S (in our case S=30 g/dm3), an increase in the relative specific volume of the sediment greater than Δn/n0=0.65 is not observed. It is established that an important characteristic of the retained sediment is the ratio of the volume concentration of the sediment to the volume concentration of solid particles in this sediment γ=Csd/Сs. The values of the adhesion and detachment of particles of contaminant in the particles of the material loading =4,9; =0,009. The results of experimental studies in general confirm the correctness and reliability of the obtained analytical dependencies

A rainfall simulation study on the relationships between soil test P versus dissolved and potentially bioavailable particulate phosphorus forms in runoff

Runoff from clayey soils often contains abundant particulate phoshorus (PP), part of which may solubilize in surface waters. Monitoring losses of potentially bioavailable forms of PP is expensive, calling for other ways to predict them. Such predictions could be based on soil loss and available soil P indices, e.g., agronomic P status. To study correlations between P pools in runoff versus soil P saturation (by Mehlich 3 extraction; DPSM3) and acetate soil test P (PAc), 15 clayey soils of south Finland were subjected to laboratory rainfall simulation. Runoff from these simulations was analyzed for concentrations of suspended soil (TSS), dissolved molybdate-reactive P (DRP), total P (TP), and, as normalized to soil loss, potentially bioavailable forms of PP: desorbable (anion exchange resin-extractable, AER-PP/TSS) and redox-labile PP (bicarbonate- dithionite-extractable, BD-PP/TSS). Correlation coefficients (r2) between DPSM3 and DRP, AER-PP/ TSS, and BD-PP/TSS equaled 0.92, 0.77, and 0.45, respectively. Runoff P forms were also correlated to soil PAc with r2 values of 0.84, 0.56, and 0.58 for DRP, AER-PP/TSS, and BD-PP/TSS, respectively. Prediction of soil loss-normalized concentrations of potentially bioavailable PP by the agronomic PAc test was considered possible. However, such predictions have a high degree of uncertainty, evidenced by comparison to published field data. Acceptably accurate predictive equations would require a large material as a basis for their construction, and soils should probably also be grouped according to other soil properties that would account for variation in P sorption capacity

Development of Great Lakes algorithms for the Nimbus-G coastal zone color scanner

A series of experiments in the Great Lakes designed to evaluate the application of the Nimbus G satellite Coastal Zone Color Scanner (CZCS) were conducted. Absorption and scattering measurement data were reduced to obtain a preliminary optical model for the Great Lakes. Available optical models were used in turn to calculate subsurface reflectances for expected concentrations of chlorophyll-a pigment and suspended minerals. Multiple nonlinear regression techniques were used to derive CZCS water quality prediction equations from Great Lakes simulation data. An existing atmospheric model was combined with a water model to provide the necessary simulation data for evaluation of the preliminary CZCS algorithms. A CZCS scanner model was developed which accounts for image distorting scanner and satellite motions. This model was used in turn to generate mapping polynomials that define the transformation from the original image to one configured in a polyconic projection. Four computer programs (FORTRAN IV) for image transformation are presented

A New Soil Conservation Methodology and Application to Cropping Systems in Tropical Steeplands: A comparative synthesis of results obtained in ACIAR Project PN 9201

Land Economics/Use,