1,182 research outputs found

    SYNTHESIS AND CHARACTERIZATION OF NANOSCALE FLUORESCENT POLYMER FILMS

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    Performance of the chemical sensing devices is based sensitivity to the targeted analytes and accuracy of the measurements. Of many different types of chemical sensors, fluorescence based sensing devices draw much attention as efficient yet small and straightforward devices, capable of detection of various analytes at extremely small quantities. Polymeric materials provide support for the fluorescent materials and usually serve as a host for the chromophores, protecting them from harsh environments, and serve as a transport media for the analyte. In the present study thin fluorescent polymer films, sensitive to the environment are synthesized and studied. Poly(glycidyl methacrylate) was used as a host material and Rhodamine B (RhB) was used as a fluorescent material. PGMA-RhB polymer films deposited on the flat surface of silicon wafers and glass slides showed the ability to uptake vapor of organic solvents from the vapor phase. It was observed, that during the swelling of the film fluorescent emission of the RhB molecules changes. Those changes were attributed to the variations in the RhB immediate environment, therefore confirming the sensitivity of the PGMA-RhB layer to the environmental changes. The fluorescent response of the PGMA-RhB layer was unique for each analyte used in the study and could be tuned by grafting of non-fluorescent layer to the surface of PGMA-RhB. Four different polymers (polystyrene, poly(2-vinyl pyridine), polyacrylic acid, and polyethylene glycol) were grafted to the surface of PGMA-RhB and each of the polymers grafted induced unique changes of fluorescent response of the PGMA-RhB. The attachment of the sensitive fluorescent layers to the surface of silica nanoparticles and fibers of Polyethylene terephthalate fabrics was performed. The sensitivity of the PGMA-RhB layers of structures with high roughness was improved, while the ability to tune the fluorescent response of the system was retained. Overall the studies have shown, that proposed method of fluorescent response tuning could be used in sensing applications

    Printable stretchable interconnects

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    This article presents recent progress and a comprehensive overview of stretchable interconnects based on printable nanocomposites. Nanocomposite-based inks for printed stretchable interconnects have been categorized according to dispersed filler materials. They comprise of carbon-based fillers and metal-based fillers. Benefits in terms of excellent electrical performance and elastic properties make nanocomposites the ideal candidates for stretchable interconnect applications. Deeper analysis of nanocomposites-based stretchable interconnects includes the correlation between the size of fillers, percolation ratio, maximum electrical conductivity and mechanical elasticity. The key trends in the field have been highlighted using curve fitting methods on large data collected from the literature. Furthermore, a wide variety of applications for stretchable interconnects are presented

    Wearable sensors for respiration monitoring: a review

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    This paper provides an overview of flexible and wearable respiration sensors with emphasis on their significance in healthcare applications. The paper classifies these sensors based on their operating frequency distinguishing between high-frequency sensors, which operate above 10 MHz, and low-frequency sensors, which operate below this level. The operating principles of breathing sensors as well as the materials and fabrication techniques employed in their design are addressed. The existing research highlights the need for robust and flexible materials to enable the development of reliable and comfortable sensors. Finally, the paper presents potential research directions and proposes research challenges in the field of flexible and wearable respiration sensors. By identifying emerging trends and gaps in knowledge, this review can encourage further advancements and innovation in the rapidly evolving domain of flexible and wearable sensors.This work was supported by the Spanish Government (MICINN) under Projects TED2021-131209B-I00 and PID2021-124288OB-I00.Peer ReviewedPostprint (published version

    MICROCANTILEVER-BASED FORCE SENSING, CONTROL AND IMAGING

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    This dissertation presents a distributed-parameters base modeling framework for microcantilever (MC)-based force sensing and control with applications to nanomanipulation and imaging. Due to the widespread applications of MCs in nanoscale force sensing or atomic force microscopy with nano-Newton to pico-Newton force measurement requirements, precise modeling of the involved MCs is essential. Along this line, a distributed-parameters modeling framework is proposed which is followed by a modified robust controller with perturbation estimation to target the problem of delay in nanoscale imaging and manipulation. It is shown that the proposed nonlinear model-based controller can stabilize such nanomanipulation process in a very short time compared to available conventional methods. Such modeling and control development could pave the pathway towards MC-based manipulation and positioning. The first application of the MC-based (a piezoresistive MC) force sensors in this dissertation includes MC-based mass sensing with applications to biological species detection. MC-based sensing has recently attracted extensive interest in many chemical and biological applications due to its sensitivity, extreme applicability and low cost. By measuring the stiffness of MCs experimentally, the effect of adsorption of target molecules can be quantified. To measure MC\u27s stiffness, an in-house nanoscale force sensing setup is designed and fabricated which utilizes a piezoresistive MC to measure the force acting on the MC\u27s tip with nano-Newton resolution. In the second application, the proposed MC-based force sensor is utilized to achieve a fast-scan laser-free Atomic Force Microscopy (AFM). Tracking control of piezoelectric actuators in various applications including scanning probe microscopes is limited by sudden step discontinuities within time-varying continuous trajectories. For this, a switching control strategy is proposed for effective tracking of such discontinuous trajectories. A new spiral path planning is also proposed here which improves scanning rate of the AFM. Implementation of the proposed modeling and controller in a laser-free AFM setup yields high quality image of surfaces with stepped topographies at frequencies up to 30 Hz. As the last application of the MC-based force sensors, a nanomanipulator named here MM3A® is utilized for nanomanipulation purposes. The area of control and manipulation at the nanoscale has recently received widespread attention in different technologies such as fabricating electronic chipsets, testing and assembly of MEMS and NEMS, micro-injection and manipulation of chromosomes and genes. To overcome the lack of position sensor on this particular manipulator, a fused vision force feedback robust controller is proposed. The effects of utilization of the image and force feedbacks are individually discussed and analyzed for use in the developed fused vision force feedback control framework in order to achieve ultra precise positioning and optimal performance
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