Erosion of gadolinia doped EB-PVD TBCs

Gadolinia additions have been shown to significantly reduce the thermal conductivity of EB-PVD TBCs. The aim of this paper is to further the understanding on the effects of dopants on the erosion resistance of EB-PVD TBCs by studying the effects of 2 mol% Gd2O3 additions on the room and high temperature erosion resistance of as received and aged EB-PVD TBCs. Previously it has been reported that gadolinia additions increased the erosion rate of EB- PVD TBCs, this is indeed the case for room temperature erosion, however under high temperature (825 à °C) erosion conditions this is not the case and the doped TBCs have a slightly lower erosion rate than the standard YSZ EB-PVD TBCs. This has been attributed to a change in the erosion mechanisms that operate at the different temperatures. This change in mechanism was not expected under the impact conditions used and has been attributed to a change in the column diameter, and how this influences the dynamics of particle impactio

Effects of Microstructure Formation on the Stability of Vapor Deposited Glasses

Glasses formed by physical vapor deposition (PVD) are an interesting new class of materials, exhibiting properties thought to be equivalent to those of glasses aged for thousands of years. Exerting control over the structure and properties of PVD glasses formed with different types of glass-forming molecules is now an emerging challenge. In this work, we study coarse grained models of organic glass formers containing fluorocarbon tails of increasing length, corresponding to an increased tendency to form microstructures. We use simulated PVD to examine how the presence of the microphase separated domains in the supercooled liquid influences the ability to form stable glasses. This model suggests that increasing molecule tail length results in decreased thermodynamic and kinetic stability of the molecules in PVD films. The reduced stability is further linked to the reduced ability of these molecules to equilibrate at the free surface during PVD. We find that as the tail length is increased, the relaxation time near the surface of the supercooled equilibrium liquid films of these molecules are slowed and become essentially bulk-like, due to the segregation of the fluorocarbon tails to the free surface. Surface diffusion is also markedly reduced due to clustering of the molecules at the surface. Based on these results, we propose a trapping mechanism where tails are unable to move between local phase separated domains on the relevant deposition time scales

The dependence of the pairwise velocity dispersion on galaxy properties

(abridged) We present measurements of the pairwise velocity dispersion (PVD) for different classes of galaxies in the Sloan Digital Sky Survey. For a sample of about 200,000 galaxies, we study the dependence of the PVD on galaxy properties such as luminosity, stellar mass (M_*), colour (g-r), 4000A break strength (D4000), concentration index (C), and stellar surface mass density (\mu_*). The luminosity dependence of the PVD is in good agreement with the results of Jing & B\"orner (2004) for the 2dFGRS catalog. The value of \sigma_{12} measured at k=1 h/Mpc decreases as a function of increasing galaxy luminosity for galaxies fainter than L*, before increasing again for the most luminous galaxies in our sample. Each of the galaxy subsamples selected according to luminosity or stellar mass is divided into two further subsamples according to colour, D4000, C and \mu_*. We find that galaxies with redder colours and higher D4000, C, and \mu_* values have larger PVDs on all scales and at all luminosities/stellar masses. The dependence of the PVD on parameters related to recent star formation(colour, D4000) is stronger than on parameters related to galaxy structure (C, \mu_*), especially on small scales and for faint galaxies. The reddest galaxies and galaxies with high surface mass densities and intermediate concentrations have the highest pairwise peculiar velocities, i.e. these move in the strongest gravitational fields. We conclude that the faint red population located in rich clusters is responsible for the high PVD values that are measured for low-luminosity galaxies on small scales.Comment: 14 pages, 13 figures; reference updated and text slightly changed to match the published version; data of measurements of power spectrum and PVD available at http://www.mpa-garching.mpg.de/~leech/papers/clustering

Bar Diagnostics in Edge-On Spiral Galaxies. I. The Periodic Orbits Approach

We develop diagnostics to detect the presence and orientation of a bar in an edge-on disk, using its kinematical signature in the position-velocity diagram (PVD) of a spiral galaxy observed edge-on. Using a well-studied barred spiral galaxy mass model, we briefly review the orbital properties of two-dimensional non-axisymmetric disks and identify the main families of periodic orbits. We use those families as building blocks to model real galaxies and calculate the PVDs obtained for various realistic combinations of periodic orbit families and for a number of viewing angles with respect to the bar. We show that the global structure of the PVD is a reliable bar diagnostic in edge-on disks. Specifically, the presence of a gap between the signatures of the families of periodic orbits in the PVD follows directly from the non-homogeneous distribution of the orbits in a barred galaxy. Similarly, material in the two so-called forbidden quadrants of the PVD results from the elongated shape of the orbits. We show how the shape of the signatures of the dominant x1 and x2 families of periodic orbits in the PVD can be used efficiently to determine the viewing angle with respect to the bar and, to a lesser extent, to constrain the mass distribution of an observed galaxy. We also address the limitations of the models when interpreting observational data.Comment: 22 pages, 9 figures (AASTeX, aaspp4.sty). Accepted for publication in The Astrophysical Journa

The influence of surface treatment of PVD coating on its quality and wear resistant

The article deals with a determination of the influence of a cutting edge preparation on the quality and wear resistance of coated cutting tools. Cutting inserts made from a sintered carbide with a deposited layer of PVD coating were selected for measurement. Non-homogeneity caused by the creation of droplets arises in the application layer during the process of applying the coating by the PVD method. These droplets make the surface roughness of the PVD coating worse, increase the friction and thereby the thermal load of the cutting tool as well. Also, the droplets could be the cause of the creation and propagation of droplets in the coating and they can cause quick cutting tool wear during machining. Cutting edge preparations were suggested for the improvement of the surface integrity of deposited layers of PVD coating, namely the technology of drag finishing and abrasive jet machining. After their application, the areal surface roughness was measured on the surface of coated cutting inserts, the occurrence of droplets was tracked and the surface structure was explored. A tool-life test of cutting inserts was carried out for verification of the influence of surface treatment on the wear resistance of cutting inserts during the milling process. The cutting inserts with a layer of PVD coatings termed as samples A, B, and C were used for the tool-life test. The first sample, A, represented the coating before the application of cutting edge preparations and samples B and C were after the application of the cutting edge preparation. A carbon steel termed C45 was used for the milling process and cutting conditions were suggested. The visual control of surface of cutting inserts, intensity of wear and occurrence of thermal cracks in deposited PVD layers were the criterion for the evaluation of the individual tests.Web of Science97art. no. 43

Clinical Utility of Echocardiography in Former Preterm Infants with Bronchopulmonary Dysplasia.

BackgroundThe clinical utility of echocardiography for the diagnosis of pulmonary vascular disease (PVD) in former preterm infants with bronchopulmonary dysplasia (BPD) is not established. Elevated pulmonary vascular resistance (PVR) rather than pulmonary artery pressure (PAP) is the hallmark of PVD. We evaluated the utility of echocardiography in infants with BPD in diagnosing pulmonary hypertension and PVD (PVR >3 Wood units × m2) assessed by cardiac catheterization.MethodsA retrospective single center study of 29 infants born ≤29 weeks of gestational age with BPD who underwent cardiac catheterization and echocardiography was performed. PVD was considered present by echocardiography if the tricuspid valve regurgitation jet peak velocity was >2.9 m/sec, post-tricuspid valve shunt systolic flow velocity estimated a right ventricular systolic pressure >35 mm Hg, or systolic septal flattening was present. The utility (accuracy, sensitivity, and positive predictive value [PPV]) of echocardiography in the diagnosis of PVD was tested. Subgroup analysis in patients without post-tricuspid valve shunts was performed. Echocardiographic estimations of right ventricular pressure, dimensions, function, and pulmonary flow measurements were evaluated for correlation with PVR.ResultsThe duration between echocardiography and cardiac catheterization was a median of 1 day (interquartile range, 1-4 days). Accuracy, sensitivity, and PPV of echocardiography in diagnosing PVD were 72%, 90.5%, and 76%, respectively. Accuracy, sensitivity, and PPV increased to 93%, 91.7%, and 100%, respectively, when infants with post-tricuspid valve shunts were excluded. Echocardiography had poor accuracy in estimating the degree of PAP elevation by cardiac catheterization. In infants without post-tricuspid valve shunts, there was moderate to good correlation between indexed PVR and right ventricular myocardial performance index (rho = 0.89, P = .005), systolic to diastolic time index (0.84, P < .001), right to left ventricular diameter ratio at end systole (0.66, P = .003), and pulmonary artery acceleration time (0.48, P = .05).ConclusionsEchocardiography performs well in screening for PVD in infants with BPD and may be diagnostic in the absence of a post-tricuspid valve shunt. However, cardiac catheterization is needed to assess the degree of PAP elevation and PVR. The diagnostic utility of echocardiographic measurements that correlate with PVR should be evaluated prospectively in this patient population

Extracts from the test plan for in-flight evaluation of the NT-33A peripheral vision display

The Peripheral Vision Display (PVD) which presents the pilot with a gyro stabilized artificial horizon projected onto his instrument panel by a laser light source is outlined. During instrument flight conditions, such a display allows the pilot to gain attitude awareness by sensing the horizon line through his peripheral vision. The pilot can detect changes to aircraft attitude without continuously referring back to his flight instruments. A second generation PVD unit was installed in the USAF/Calspan NT-33A during late 1982. An NT-33A flight evaluation of the display provides a unique opportunity to utilize a Workload Assessment Device (WAD) to obtain quantitative data regarding the utility of the PVD in reducing pilot workload. The experimental design and procedures for a two phase NT-33 PVD flight evaluation program is described

A multi-protein receptor-ligand complex underlies combinatorial dendrite guidance choices in C. elegans.

Ligand receptor interactions instruct axon guidance during development. How dendrites are guided to specific targets is less understood. The C. elegans PVD sensory neuron innervates muscle-skin interface with its elaborate dendritic branches. Here, we found that LECT-2, the ortholog of leukocyte cell-derived chemotaxin-2 (LECT2), is secreted from the muscles and required for muscle innervation by PVD. Mosaic analyses showed that LECT-2 acted locally to guide the growth of terminal branches. Ectopic expression of LECT-2 from seam cells is sufficient to redirect the PVD dendrites onto seam cells. LECT-2 functions in a multi-protein receptor-ligand complex that also contains two transmembrane ligands on the skin, SAX-7/L1CAM and MNR-1, and the neuronal transmembrane receptor DMA-1. LECT-2 greatly enhances the binding between SAX-7, MNR-1 and DMA-1. The activation of DMA-1 strictly requires all three ligands, which establishes a combinatorial code to precisely target and pattern dendritic arbors