Radiatively-driven processes in forest fire and desert dust plumes

The absorption of solar radiation by atmospheric aerosol particles is important for the climate effects of aerosols. Absorption by aerosol particles heats atmospheric layers, even though the net effect for the entire atmospheric column may still be a cooling. Most experimental studies on absorbing aerosols so far focussed mainly on the aerosol properties and did not consider the influence of the aerosols on the thermodynamic structure of the atmosphere. In this study, data from two international aircraft field experiments, the Intercontinental Transport of Ozone and Precursors study (ITOP) 2004 and the Saharan Mineral Dust Experiment (SAMUM) 2006 are investigated. The ITOP data were collected before the work on this thesis started, while the logistics and the instrument preparation of the SAMUM campaign, the weather forecast during SAMUM and the in-situ aerosol measurements during SAMUM were done within this thesis. The experimental data are used to explore the impact of layers containing absorbing forest fire and desert dust aerosol particles on the atmospheric stability and the implications of a changed stability on the development of the aerosol microphysical and optical properties during long-range transport. For the first time, vertical profiles of the Richardson number Ri are used to assess the stability and mixing in forest fire and desert dust plumes. Also for the first time, the conclusions drawn from the observations of forest fire and desert dust aerosol, at first glance apparently quite different aerosol types, are discussed from a common perspective. Two mechanisms, the self-stabilising and the sealed ageing effect, acting in both forest fire and desert dust aerosol layers, are proposed to explain the characteristic temperature structure as well as the aerosol properties observed in lofted forest fire and desert dust plumes. The proposed effects impact on the ageing of particles within the plumes and reduce the plume dilution, therefore extending the plume lifetime. This study combines experimental data, modelling of optical parameters and calculated heating rates to assess the role of forest fire and desert dust plumes. The microphysical, optical and chemical properties of forest fire and desert dust aerosol, and their vertical distribution, were measured with multiple instruments on the DLR Falcon 20-E5 research aircraft during ITOP and SAMUM. Aerosol size information and absorption data were analysed with respect to the aerosol mixing state, effective diameter and parameterisation of forest fire and dust size distributions. Altogether, about 90 size distributions for particles from different sources were extracted from multiple instruments and parameterised with multi-modal log-normal distributions. Subsequently, the optical properties were calculated for the different aerosol layers and compared with other independent measurements of the optical properties like the extinction coefficient determined with a High Spectral Resolution Lidar. The aerosol optical properties serve as the basis for the radiative transfer calculations with libRadtran (library for radiative transfer). Finally, the aerosol microphysical and optical properties, the meteorological data and the heating rates are examined to investigate the proposed self-stabilising and sealed ageing effects. The investigation of numerous forest fire and desert dust plumes in this study revealed characteristic aerosol properties: the aged (age: 4-13 days) forest fire aerosol is characterised by the absence of a nucleation mode, a depleted Aitken mode and an enhanced accumulation mode. In addition, more than 80% of the particles in the Aitken mode and nearly all particles in the accumulation mode of the forest fire plumes are internally mixed with a solid core. The desert dust aerosol exhibits two size regimes of different mixing states: below 0.5 µm, particles have a non-volatile core and a volatile coating; larger particles above 0.5 µm consist of non-volatile components and contain absorbing material. After regional-scale transport from the Sahara to South-western Europe, the volatile fraction in the dust plume did not significantly increase. The lofted forest fire plumes were found during ITOP at altitudes between 3 and 9 km above sea level (ASL), while the lofted desert dust plumes were found during SAMUM between 1 and 6 km ASL. The transition of the aerosol plumes to the free tropospheric background above and below the plumes was remarkably sharp and characterised by strong inversions. Within a height range of 200-300 m, the particle concentrations decreased by more than one order of magnitude. The results of plume dilution were evident only in the upper part of the lofted forest fire and desert dust plumes. The daily mean heating rates in the forest fire and desert dust plumes showed maximum values of ~0.2 K day-1 and ~0.24 K day-1, respectively. Vertical profiles of the heating rate suggest that the processes caused by the interaction between the aerosol particles and the solar radiation stabilise the plume itself and decelerate plume dilution. Apparently, the aerosol in such plumes ages in an almost “closed” system, where suppressed entrainment of condensable gases from the surface inhibits particle nucleation and the formation of coated particles inside the plume. The processes described tend to extend the lifetime of the layer allowing the transport over long distances

Overview of the 2010 Carbonaceous Aerosols and Radiative Effects Study (CARES)

Substantial uncertainties still exist in the scientific understanding of the possible interactions between urban and natural (biogenic) emissions in the production and transformation of atmospheric aerosol and the resulting impact on climate change. The US Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) program's Carbonaceous Aerosol and Radiative Effects Study (CARES) carried out in June 2010 in Central Valley, California, was a comprehensive effort designed to improve this understanding. The primary objective of the field study was to investigate the evolution of secondary organic and black carbon aerosols and their climate-related properties in the Sacramento urban plume as it was routinely transported into the forested Sierra Nevada foothills area. Urban aerosols and trace gases experienced significant physical and chemical transformations as they mixed with the reactive biogenic hydrocarbons emitted from the forest. Two heavily-instrumented ground sites – one within the Sacramento urban area and another about 40 km to the northeast in the foothills area – were set up to characterize the evolution of meteorological variables, trace gases, aerosol precursors, aerosol size, composition, and climate-related properties in freshly polluted and "aged" urban air. On selected days, the DOE G-1 aircraft was deployed to make similar measurements upwind and across the evolving Sacramento plume in the morning and again in the afternoon. The NASA B-200 aircraft, carrying remote sensing instruments, was also deployed to characterize the vertical and horizontal distribution of aerosols and aerosol optical properties within and around the plume. This overview provides: (a) the scientific background and motivation for the study, (b) the operational and logistical information pertinent to the execution of the study, (c) an overview of key observations and initial findings from the aircraft and ground-based sampling platforms, and (d) a roadmap of planned data analyses and focused modeling efforts that will facilitate the integration of new knowledge into improved representations of key aerosol processes and properties in climate models.United States. Dept. of Energy. Atmospheric System Research Program (Contract DE-AC06-76RLO 1830)United States. National Oceanic and Atmospheric AdministrationUnited States. National Aeronautics and Space Administration. HQ Science Mission Directorate Radiation Sciences ProgramUnited States. National Aeronautics and Space Administration. CALIPSO ProgramUnited States. Dept. of Energy. Atmospheric Radiation Measurement Program (Interagency Agreement No. DE-AI02-05ER63985

Channel Fading Statistics For Real-Time Data Transmission In Emergency Call Systems And Unmanned Aerial Systems

The Third Generation Partnership Project (3GPP) selected an in-band modem to transmit emergency data over cellular voice channel for the European Union emergency call (eCall) system. However, the road test results presented by the Harmonized eCall European Pilot project showed that the success rate of data delivery was only 71%, indicating that there is significant potential to improve its performance. In this dissertation, a testbed is designed for the eCall system that satisfies the 3GPP TS 26.267/268/269 standards. A method is proposed to measure the power of the received signal that passes through the in-band channel. Experiments are performed with the in-vehicle system testbed in a laboratory or a car travelling in city, suburb, country- side, or freeway. Fading statistics of the received signal after power control are found and discussed, together with cumulative distribution function (CDF), level crossing rate (LCR), and average fade duration (AFD). It is found that with probability less than or equal to 0.1%, fading and attenuation can vary from -19 dB for the continuous wave (CW) signal at 500 Hz to -9.5 dB for the CW signal at 2000 Hz. This dissertation recommends moving the CW signals at 500 Hz and 800 Hz for detection and synchronization in the 3GPP standard to 1500 Hz and 2000 Hz, respectively. This will give 9.5 dB improvement in detection and synchronization. The fading results are used to calculate the bit error rate (BER) performance for the eCall in-band modem. Synchronization detection probability are obtained by transmitting the synchronization preamble through various adaptive multi-rate vocoders and an additive white Gaussian noise channel. The testbed and proposed method are also used to measure the power of signals received by an unmanned aerial systems (UAS) and by the receiver in the operation center, respectively. Field experiments are carried out by flying the UAS above different locations. Statistics, including CDF, LCR, and AFD, are calculated for the six test-sites. The results of the fading statistics, synchronization detection probability, and BER can be directly applied to design real-time communication systems, including detection, delay estimation, modulation and coding

Aircraft study of the impact of lake-breeze circulations on trace gases and particles during BAQS-Met 2007

High time-resolved aircraft data, concurrent surface measurements and air quality model simulations were explored to diagnose the processes influencing aerosol chemistry under the influence of lake-breeze circulations in a polluted region of southwestern Ontario, Canada. The analysis was based upon horizontal aircraft transects conducted at multiple altitudes across an entire lake-breeze circulation. Air mass boundaries due to lake-breeze fronts were identified in the aircraft meteorological and chemical data, which were consistent with the frontal locations determined from surface analyses. Observations and modelling support the interpretation of a lake-breeze circulation where pollutants were lofted at a lake-breeze front, transported in the synoptic flow, caught in a downdraft over the lake, and then confined by onshore flow. The detailed analysis led to the development of conceptual models that summarize the complex 3-D circulation patterns and their interaction with the synoptic flow. The identified air mass boundaries, the interpretation of the lake-breeze circulation, and the air parcel circulation time in the lake-breeze circulation (3.0 to 5.0 h) enabled formation rates of organic aerosol (OA/ΔCO) and SO<sub>4</sub><sup>2−</sup> to be determined. The formation rate for OA (relative to excess CO in ppmv) was found to be 11.6–19.4 μg m<sup>−3</sup> ppmv<sup>−1</sup> h<sup>−1</sup> and the SO<sub>4</sub><sup>2−</sup> formation rate was 5.0–8.8% h<sup>−1</sup>. The formation rates are enhanced relative to regional background rates implying that lake-breeze circulations are an important dynamic in the formation of SO<sub>4</sub><sup>2−</sup> and secondary organic aerosol. The presence of cumulus clouds associated with the lake-breeze fronts suggests that these enhancements could be due to cloud processes. Additionally, the effective confinement of pollutants along the shoreline may have limited pollutant dilution leading to elevated oxidant concentrations

Reconciling Assumptions in Bottom-Up and Top-Down Approaches for Estimating Aerosol Emission Rates From Wildland Fires Using Observations From FIREX-AQ

Accurate fire emissions inventories are crucial to predict the impacts of wildland fires on air quality and atmospheric composition. Two traditional approaches are widely used to calculate fire emissions: a satellite-based top-down approach and a fuels-based bottom-up approach. However, these methods often considerably disagree on the amount of particulate mass emitted from fires. Previously available observational datasets tended to be sparse, and lacked the statistics needed to resolve these methodological discrepancies. Here, we leverage the extensive and comprehensive airborne in situ and remote sensing measurements of smoke plumes from the recent Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) campaign to statistically assess the skill of the two traditional approaches. We use detailed campaign observations to calculate and compare emission rates at an exceptionally high-resolution using three separate approaches: top-down, bottom-up, and a novel approach based entirely on integrated airborne in situ measurements. We then compute the daily average of these high-resolution estimates and compare with estimates from lower resolution, global top-down and bottom-up inventories. We uncover strong, linear relationships between all of the high-resolution emission rate estimates in aggregate, however no single approach is capable of capturing the emission characteristics of every fire. Global inventory emission rate estimates exhibited weaker correlations with the high-resolution approaches and displayed evidence of systematic bias. The disparity between the low-resolution global inventories and the high-resolution approaches is likely caused by high levels of uncertainty in essential variables used in bottom-up inventories and imperfect assumptions in top-down inventories

Aerospace Medicine and Biology: A continuing bibliography with indexes, supplement 192

This bibliography lists 247 reports, articles, and other documents introduced into the NASA scientific and technical information system in March 1979

An overview of the MILAGRO 2006 Campaign: Mexico City emissions and their transport and transformation

MILAGRO (Megacity Initiative: Local And Global Research Observations) is an international collaborative project to examine the behavior and the export of atmospheric emissions from a megacity. The Mexico City Metropolitan Area (MCMA) – one of the world's largest megacities and North America's most populous city – was selected as the case study to characterize the sources, concentrations, transport, and transformation processes of the gases and fine particles emitted to the MCMA atmosphere and to evaluate the regional and global impacts of these emissions. The findings of this study are relevant to the evolution and impacts of pollution from many other megacities. The measurement phase consisted of a month-long series of carefully coordinated observations of the chemistry and physics of the atmosphere in and near Mexico City during March 2006, using a wide range of instruments at ground sites, on aircraft and satellites, and enlisting over 450 scientists from 150 institutions in 30 countries. Three ground supersites were set up to examine the evolution of the primary emitted gases and fine particles. Additional platforms in or near Mexico City included mobile vans containing scientific laboratories and mobile and stationary upward-looking lidars. Seven instrumented research aircraft provided information about the atmosphere over a large region and at various altitudes. Satellite-based instruments peered down into the atmosphere, providing even larger geographical coverage. The overall campaign was complemented by meteorological forecasting and numerical simulations, satellite observations and surface networks. Together, these research observations have provided the most comprehensive characterization of the MCMA's urban and regional atmospheric composition and chemistry that will take years to analyze and evaluate fully. In this paper we review over 120 papers resulting from the MILAGRO/INTEX-B Campaign that have been published or submitted, as well as relevant papers from the earlier MCMA-2003 Campaign, with the aim of providing a road map for the scientific community interested in understanding the emissions from a megacity such as the MCMA and their impacts on air quality and climate. This paper describes the measurements performed during MILAGRO and the results obtained on MCMA's atmospheric meteorology and dynamics, emissions of gases and fine particles, sources and concentrations of volatile organic compounds, urban and regional photochemistry, ambient particulate matter, aerosol radiative properties, urban plume characterization, and health studies. A summary of key findings from the field study is presented.Mexico. Comisión Ambiental MetropolitanaMexico. Ministry of the EnvironmentConsejo Nacional de Ciencia y Tecnología (Mexico)Petróleos MexicanosNational Science Foundation (U.S.). Atmospheric Chemistry ProgramAtmospheric Sciences Program (U.S.)United States. National Aeronautics and Space Administration. Radiation Science Progra

Airborne Characterization of Regional Aerosol Origins and Optical Properties

The ubiquity of air pollution in the Mid-Atlantic and northeastern U.S. is a major concern for human and ecological health as well as the climate. Between February 2001 and February 2004, 160 flights on a light aircraft outfitted for atmospheric research were conducted over the region to characterize the factors that lead to severe air pollution episodes and how the pollutants impact the radiation budget. One salient discovery was that the chemistry and physics of multi-day haze and ozone episodes over the Mid-Atlantic and northeastern U.S. may be accurately represented by a two-reservoir system composed of the planetary boundary layer (PBL) and the lower free troposphere (LFT). Primary pollutants are typically emitted in the PBL, where they are subject to greater humidification effects and surface deposition. Pollutants in the LFT are not subject to direct deposition and photochemical processes are accelerated, which appears to play a larger role in particle growth processes than relative humidity. Measurements of a smoke plume from Canadian forest fires showed that the plume was separated from the underlying layer by a morning subsidence inversion. Absorption of solar radiation within the optically thick plume nearly equaled the total amount attenuated at the surface, creating a feedback loop that sustained the vertical stability and protracted the lifetime of the plume. Satellite reflectances were used to calculate the optical depth of the smoke plume with two sets of inputs; AERONET retrieved optical properties and optical properties measured aboard the aircraft. The optical depths calculated using the AERONET optical properties were the lowest, while retrievals using the in-situ values were 22-43% larger, due to greater absorption measured in-situ. Radiative forcings calculated with the in-situ optical properties matched surface and TOA measurements more closely than those calculated with the AERONET retrievals. Measurements made downwind of power plants during the North American electrical blackout showed reductions in SO2 (>90%), O3 (~50%), and light scattered by particles (~70%). These observations indicate the central role power plants play in regional air quality. Finally, statistical analyses of all flights point to the dominance of photochemical and meteorological processes in determining aerosol optical properties