4,842 research outputs found
Strong coupling theory for tunneling and vibrational relaxation in driven bistable systems
A study of the dynamics of a tunneling particle in a driven bistable
potential which is moderately-to-strongly coupled to a bath is presented. Upon
restricting the system dynamics to the Hilbert space spanned by the M lowest
energy eigenstates of the bare static potential, a set of coupled non-Markovian
master equations for the diagonal elements of the reduced density matrix,
within the discrete variale representation, is derived. The resulting dynamics
is in good agreement with predictions of ab-initio real-time path integral
simulations. Numerous results, analytical as well as numerical, for the quantum
relaxation rate and for the asymptotic populations are presented. Our method is
particularly convenient to investigate the case of shallow, time-dependent
potential barriers and moderate-to-strong damping, where both a semi-classical
and a Redfield-type approach are inappropriate.Comment: 37 pages, 23 figure
Silicon carbide technology for extreme environments
PhD ThesisWith mankind’s ever increasing curiosity to explore the unknown, including a variety of
hostile environments where we cannot tread, there exists a need for machines to do
work on our behalf. For applications in the most extreme environments and applications
silicon based electronics cannot function, and there is a requirement for circuits and
sensors to be built from wide band gap materials capable of operation in these domains.
This work addresses the initial development of silicon carbide circuits to monitor
conditions and transmit information from such hostile environments. The
characterisation, simulation and implementation of silicon carbide based circuits
utilising proprietary high temperature passives is explored.
Silicon carbide is a wide band gap semiconductor material with highly suitable
properties for high-power, high frequency and high temperature applications. The
bandgap varies depending on polytype, but the most commonly used polytype 4H, has a
value of 3.265 eV at room temperature, which reduces as the thermal ionization of
electrons from the valence band to the conduction band increases, allowing operation in
ambient up to 600°C.
Whilst silicon carbide allows for the growth of a native oxide, the quality has limitations
and therefore junction field effect transistors (JFETs) have been utilised as the switch in
this work. The characteristics of JFET devices are similar to those of early thermionic
valve technology and their use in circuits is well known. In conjunction with JFETs,
Schottky barrier diodes (SBDs) have been used as both varactors and rectifiers.
Simulation models for high temperature components have been created through their
characterisation of their electrical parameters at elevated temperatures.
The JFETs were characterised at temperatures up to 573K, and values for TO V , β , λ ,
IS , RS and junction capacitances were extracted and then used to mathematically
describe the operation of circuits using SPICE. The transconductance of SiC JFETs at
high temperatures has been shown to decrease quadratically indicating a strong
dependence upon carrier mobility in the channel. The channel resistance also decreased
quadratically as a direct result of both electric field and temperature enhanced trap
emission. The JFETs were tested to be operational up to 775K, where they failed due to
delamination of an external passivation layer.
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Schottky diodes were characterised up to 573K, across the temperature range and values
for ideality factor, capacitance, series resistance and forward voltage drop were
extracted to mathematically model the devices. The series resistance of a SiC SBD
exhibited a quadratic relationship with temperature indicating that it is dominated by
optical phonon scattering of charge carriers. The observed deviation from a temperature
independent ideality factor is due to the recombination of carriers in the depletion
region affected by both traps and the formation of an interfacial layer at the SiC/metal
interface.
To compliment the silicon carbide active devices utilised in this work, high temperature
passive devices and packaging/circuit boards were developed. Both HfO2 and AlN
materials were investigated for use as potential high temperature capacitor dielectrics in
metal-insulator-metal (MIM) capacitor structures. The different thicknesses of HfO2
(60nm and 90nm) and 300nm for AlN and the relevance to fabrication techniques are
examined and their effective capacitor behaviour at high temperature explored. The
HfO2 based capacitor structures exhibited high levels of leakage current at temperatures
above 100°C. Along with elevated leakage when subjected to higher electric fields. This
current leakage is due to the thin dielectric and high defect density and essentially turns
the capacitors into high value resistors in the order of MΩ. This renders the devices
unsuitable as capacitors in hostile environments at the scales tested. To address this
issue AlN capacitors with a greater dielectric film thickness were fabricated with
reduced leakage currents in comparison even at an electric field of 50MV/cm at 600K.
The work demonstrated the world’s first high temperature wireless sensor node powered
using energy harvesting technology, capable of operation at 573K. The module
demonstrated the world’s first amplitude modulation (AM) and frequency modulation
(FM) communication techniques at high temperature. It also demonstrated a novel high
temperature self oscillating boost converter cable of boosting voltages from a
thermoelectric generator also operating at this temperature.
The AM oscillator operated at a maximum temperature of 553K and at a frequency of
19.4MHz with a signal amplitude 65dB above background noise. Realised from JFETs
and HfO2 capacitors, modulation of the output signal was achieved by varying the load
resistance by use of a second SiC JFET. By applying a negative signal voltage of
between -2.5 and -3V, a 50% reduction in the signal amplitude and therefore Amplitude
Modulation was achieved by modulating the power within the oscillator through the use
of this secondary JFET. Temperature drift in the characteristics were also observed,
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with a decrease in oscillation frequency of almost 200 kHz when the temperature
changed from 300K to 573K. This decrease is due to the increase in capacitance density
of the HfO2 MIM capacitors and increasing junction capacitances of the JFET used as
the amplifier within the oscillator circuit.
Direct frequency modulation of a SiC Voltage Controlled Oscillator was demonstrated
at a temperature of 573K with a oscillation frequency of 17MHz. Realised from an SiC
JFET, AlN capacitors and a SiC SBD used as a varactor. It was possible to vary the
frequency of oscillations by 100 kHz with an input signal no greater than 1.5V being
applied to the SiC SBD. The effects of temperature drift were more dramatic in
comparison to the AM circuit at 400 kHz over the entire temperature range, a result of
the properties of the AlN film which causes the capacitors to increase in capacitance
density by 10%.
A novel self oscillating boost converter was commissioned using a counter wound
transformer on high temperature ferrite, a SiC JFET and a SiC SBD. Based upon the
operation of a free running blocking oscillator, oscillatory behaviour is a result of the
electric and magnetic variations in the winding of the transformer and the amplification
characteristics of a JFET. It demonstrated the ability to boost an input voltage of 1.3
volts to 3.9 volts at 573K and exhibited an efficiency of 30% at room temperature. The
frequency of operation was highly dependent upon the input voltage due to the
increased current flow through the primary coil portion of the transformer and the
ambient temperature causing an increase in permeability of the ferrite, thus altering the
inductance of both primary and secondary windings. However due its simplicity and its
ability to boost the input voltage by 250% meant it was capable of powering the
transmitters and in conjunction with a Themoelectric Generator so formed the basis for
a self powered high temperature silicon carbide sensor node.
The demonstration of these high temperature circuits provide the initial stages of being
able to produce a high temperature wireless sensor node capable of operation in hostile
environments. Utilising the self oscillating boost converter and a high temperature
Thermoelectric Generator these prototype circuits were showed the ability to harvest
energy from the high temperature ambient and power the silicon carbide circuitry.
Along with appropriate sensor technology it demonstrated the feasibility of being able
to monitor and transmit information from hazardous locations which is currently
unachievable
Hyperfine Spectroscopy of Optically Trapped Atoms
We perform spectroscopy on the hyperfine splitting of Rb atoms trapped
in far-off-resonance optical traps. The existence of a spatially dependent
shift in the energy levels is shown to induce an inherent dephasing effect,
which causes a broadening of the spectroscopic line and hence an inhomogeneous
loss of atomic coherence at a much faster rate than the homogeneous one caused
by spontaneous photon scattering. We present here a number of approaches for
reducing this inhomogeneous broadening, based on trap geometry, additional
laser fields, and novel microwave pulse sequences. We then show how hyperfine
spectroscopy can be used to study quantum dynamics of optically trapped atoms.Comment: Review/Tutoria
Stimulating uncertainty: Amplifying the quantum vacuum with superconducting circuits
The ability to generate particles from the quantum vacuum is one of the most
profound consequences of Heisenberg's uncertainty principle. Although the
significance of vacuum fluctuations can be seen throughout physics, the
experimental realization of vacuum amplification effects has until now been
limited to a few cases. Superconducting circuit devices, driven by the goal to
achieve a viable quantum computer, have been used in the experimental
demonstration of the dynamical Casimir effect, and may soon be able to realize
the elusive verification of analogue Hawking radiation. This article describes
several mechanisms for generating photons from the quantum vacuum and
emphasizes their connection to the well-known parametric amplifier from quantum
optics. Discussed in detail is the possible realization of each mechanism, or
its analogue, in superconducting circuit systems. The ability to selectively
engineer these circuit devices highlights the relationship between the various
amplification mechanisms.Comment: 27 pages, 10 figures, version published in Rev. Mod. Phys. as a
Colloquiu
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