Instrumentation and control of anaerobic digestion processes: a review and some research challenges

The final publication is available at Springer via http://dx.doi.org/10.1007/s11157-015-9382-6[EN] To enhance energy production from methane or resource recovery from digestate, anaerobic digestion processes require advanced instrumentation and control tools. Over the years, research on these topics has evolved and followed the main fields of application of anaerobic digestion processes: from municipal sewage sludge to liquid mainly industrial then municipal organic fraction of solid waste and agricultural residues. Time constants of the processes have also changed with respect to the treated waste from minutes or hours to weeks or months. Since fast closed loop control is needed for short time constant processes, human operator is now included in the loop when taking decisions to optimize anaerobic digestion plants dealing with complex solid waste over a long retention time. Control objectives have also moved from the regulation of key variables measured online to the prediction of overall process perfor- mance based on global off-line measurements to optimize the feeding of the processes. Additionally, the need for more accurate prediction of methane production and organic matter biodegradation has impacted the complexity of instrumentation and should include a more detailed characterization of the waste (e.g., biochemical fractions like proteins, lipids and carbohydrates)andtheirbioaccessibility andbiodegradability characteristics. However, even if in the literature several methodologies have been developed to determine biodegradability based on organic matter characterization, only a few papers deal with bioaccessibility assessment. In this review, we emphasize the high potential of some promising techniques, such as spectral analysis, and we discuss issues that could appear in the near future concerning control of AD processes.The authors acknowledge the financial support of INRA (the French National Institute for Agricultural Research), the French National Research Agency (ANR) for the "Phycover" project (project ANR-14-CE04-0011) and ADEME for Inter-laboratory assay financial support.Jimenez, J.; Latrille, E.; Harmand, J.; Robles Martínez, Á.; Ferrer Polo, J.; Gaida, D.; Wolf, C.... (2015). Instrumentation and control of anaerobic digestion processes: a review and some research challenges. Reviews in Environmental Science and Biotechnology. 14(4):615-648. doi:10.1007/s11157-015-9382-6S615648144Aceves-Lara CA, Latrille E, Steyer JP (2010) Optimal control of hydrogen production in a continuous anaerobic fermentation bioreactor. 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Municipal solid waste management system: decision support through systems analysis

Thesis submitted to the Universidade Nova de Lisboa, Faculdade de Ciências e Tecnologia for the degree of Doctor of Philosophy in Environmental EngineeringThe present study intends to show the development of systems analysis model applied to solid waste management system, applied into AMARSUL, a solid waste management system responsible for the management of municipal solid waste produced in Setúbal peninsula, Portugal. The model developed intended to promote sustainable decision making, covering the four columns: technical, environmental, economic and social aspects. To develop the model an intensive literature review have been conducted. To simplify the discussion, the spectrum of these systems engineering models and system assessment tools was divided into two broadly-based domains associated with fourteen categories although some of them may be intertwined with each other. The first domain comprises systems engineering models including cost-benefit analysis, forecasting analysis, simulation analysis, optimization analysis, and integrated modeling system whereas the second domain introduces system assessment tools including management information systems, scenario development, material flow analysis, life cycle assessment (LCA), risk assessment, environmental impact assessment, strategic environmental assessment, socio-economic assessment, and sustainable assessment. The literature performed have indicated that sustainable assessment models have been one of the most applied into solid waste management, being methods like LCA and optimization modeling (including multicriteria decision making(MCDM)) also important systems analysis methods. These were the methods (LCA and MCDM) applied to compose the system analysis model for solid waste. The life cycle assessment have been conducted based on ISO 14040 family of norms; for multicriteria decision making there is no procedure neither guidelines, being applied analytic hierarchy process (AHP) based Fuzzy Interval technique for order performance by similarity to ideal solution (TOPSIS). Multicriteria decision making have included several data from life cycle assessment to construct environmental, social and technical attributes, plus economic criteria obtained from collected data from stakeholders involved in the study. The results have shown that solutions including anaerobic digestion in mechanical biological treatment plant plus anaerobic digestion of biodegradable municipal waste from source separation, with energetic recovery of refuse derived fuel (RDF) and promoting pays-as-you-throw instrument to promote recycling targets compliance would be the best solutions to implement in AMARSUL system. The direct burning of high calorific fraction instead of RDF has not been advantageous considering all criteria, however, during LCA, the results were the reversal. Also it refers that aerobic mechanical biological treatment should be closed.Fundação para a Ciência e Tecnologia - SFRH/BD/27402/200

Development and integration of environmental evaluation tools for the ecodesign of sustainable processes and products

Industry is recognized as one of the main sources of environmental pollution and resource depletion, both causing environmental degradation; nonetheless, its contribution to development and wealth creation is also acknowledged. Therefore, the identification of sustainable options in this area is a key factor. Nowadays, the attitude towards pollution prevention and control and cleaner production is not just a response to emerging environmental laws and regulations (Registration, Evaluation, Authorization and Restriction of Chemicals -REACH-, Integrated Pollution Prevention and Control –IPPC- Law, Integrated Product Policy –IPP-), but also a matter of corporate responsibility. Further, it has proved to be a way to increase profits. The sustainability definition has received certain criticism for its vagueness, ambiguity and difficulty to translate this concept at different levels. To overcome the difficulties of its implementation, a wide variety of indicators have been developed and applied over the years, providing metrics essential at the action level. This thesis poses a contribution to the development of environmental evaluation tools adapted to particular production sectors, aiming at providing metrics to guide decision making for the ecodesign of sustainable processes and products. Integrative frameworks that combine methodologies of different nature were proposed as the most suitable way to achieve comprehensive evaluations. At the same time, the simplicity of tools was pursued to make its application easier and more attractive for enterprises, avoiding the need of in depth training

Experimental investigation and modelling of the heating value and elemental composition of biomass through artificial intelligence

Abstract: Knowledge advancement in artificial intelligence and blockchain technologies provides new potential predictive reliability for biomass energy value chain. However, for the prediction approach against experimental methodology, the prediction accuracy is expected to be high in order to develop a high fidelity and robust software which can serve as a tool in the decision making process. The global standards related to classification methods and energetic properties of biomass are still evolving given different observation and results which have been reported in the literature. Apart from these, there is a need for a holistic understanding of the effect of particle sizes and geospatial factors on the physicochemical properties of biomass to increase the uptake of bioenergy. Therefore, this research carried out an experimental investigation of some selected bioresources and also develops high-fidelity models built on artificial intelligence capability to accurately classify the biomass feedstocks, predict the main elemental composition (Carbon, Hydrogen, and Oxygen) on dry basis and the Heating value in (MJ/kg) of biomass...Ph.D. (Mechanical Engineering Science

Selection of novel geopolymeric mortars for sustainable construction applications using fuzzy topsis approach

Construction is recognized as one of the most polluting and energy consuming industries worldwide, especially in developing countries. Therefore, Research and Development (R&D) of novel manufacturing technologies and green construction materials is becoming extremely compelling. This study aims at evaluating the reuse of various wastes, originated in the Kraft pulp-paper industry, as raw materials in the manufacture of novel geopolymeric (GP) mortars whose properties fundamentally depend on the target application (e.g., insulating panel, partition wall, structural element, furnishing, etc.). Five different wastes were reused as filler: Two typologies of Biomass Fly Ash, calcareous sludge, grits, and dregs. The produced samples were characterized and a multi criteria analysis, able to take into account not only the engineering properties, but also the environmental and economic aspects, has been implemented. The criteria weights were evaluated using the Delphi methodology. The fuzzy Topsis approach has been used to consider the intrinsic uncertainty related to unconventional materials, as the produced GP-mortars. The computational analysis showed that adding the considered industrial wastes as filler is strongly recommended to improve the performance of materials intended for structural applications in construction. The results revealed that the formulations containing 5 wt.% of calcareous sludge, grits, and dregs and the one containing 7.5 wt.% of calcareous sludge, grits, dregs, and Biomass Fly Ash-1 have emerged as the best alternatives. Furthermore, it resulted that the Biomass Fly Ash-2 negatively influences the structural performance and relative rank of the material. Finally, this case study clearly shows that the fuzzy Topsis multi-criteria analysis represents a valuable and easy tool to investigate construction materials (either traditional and unconventional) when an intrinsic uncertainty is related to the measurement of the quantitative and qualitative characteristics

モンゴル国ウランバートル市の持続的廃棄物管理の改善のためのLCAと多基準意思決定分析

In last years, as the lifestyle and socio-economic situation of the citizens is changing, in this regards amount of the municipal waste and type of waste are also increasing in the Ulaanbaatar city. This research analyzed each of the four waste disposal methods, to develop and select the waste management best option. To estimates economic efficiency Life cycle cost analysis methods based on the municipal waste disposal budget data; used tool a Cost-benefit analysis of each scenario explores opportunities to increase waste revenues and reduce annual costs. Also analyzes Life cycle impact assessment for each waste treatment option and includes a Life cycle assessment that considers direct and indirect GHG emissions during landfilling, waste incineration, composting, recycling, or energy consumption from waste treatment in Ulaanbaatar city. This research was conducted based on the Multi criteria decision analysis method for evaluating the performance of each scenario considered hereafter as well as interviews with experts. These interviews were used to identify key ideas related to waste management. These issues have been considered using Technique for order preference by similarity to ideal solution analysis to determine the potential impacts of environmental, economic, technical, and social factors, which were analyzed for each waste disposal method to develop and select the best option. As the result, MBT plant has not been advantageous considering all criteria. However, waste incineration is the most cost-effective option in Ulaanbaatar city in terms of saving coal resources and reducing coal production.北九州市立大

Inexact fuzzy-stochastic constraint-softened programming - A case study for waste management

In this study, an inexact fuzzy-stochastic constraint-softened programming method is developed for municipal solid waste (MSW) management under uncertainty, The developed method can deal with multiple uncertainties presented in terms of fuzzy sets, interval values and random variables. Moreover, a number of violation levels for the system constraints are allowed. This is realized through introduction of violation variables to soften system constraints, such that the model's decision space can be expanded under demanding conditions. This can help generate a range of decision alternatives under various conditions, allowing in-depth analyses of tradeoffs among economic objective, satisfaction degree, and constraint-violation risk. The developed method is applied to a case study of planning a MSW management system. The uncertain and dynamic information can be incorporated within a multi-layer scenario tree; revised decisions are permitted in each time period based on the realized values of uncertain events. Solutions associated with different satisfaction degree levels have been generated, corresponding to different constraint-violation risks. They are useful for supporting decisions of waste flow allocation and system-capacity expansion within a multistage context. (C) 2008 Elsevier Ltd. All rights reserved

A life cycle optimization framework for the sustainable design of circular municipal solid waste management systems

RESUMEN: Los objetivos de esta tesis son desarrollar un marco metodológico para determinar la configuración óptima de los sistemas integrados de gestión de residuos bajo una perspectiva del ciclo de vida, e investigar si la economía circular contribuye a la reducción del consumo de recursos y los impactos ambientales y al crecimiento económico. El marco metodológico propuesto se aplicó a la gestión de residuos municipales orgánicos en la Comunidad Autónoma de Cantabria. El modelo del sistema se construyó combinando análisis de flujo de materiales y análisis de ciclo de vida (ambiental y económico). Se formuló un problema de optimización multi-objetivo para maximizar la circularidad de los nutrientes y minimizar el uso de recursos, los impactos ambientales y los costes de gestión de residuos. Los resultados sugieren que mejorar la circularidad de los recursos no implica necesariamente una reducción de costes, del consumo de recursos o de la emisión de cargas ambientales.ABSTRACT: The objectives of this dissertation are twofold: to develop a methodological framework to select the optimal configuration of integrated waste management systems under a life cycle perspective, and to investigate whether adopting a circular economy is an effective measure to attain increased economic benefits and a reduction in resource consumption and environmental impacts. The proposed framework – based the expansion of the boundaries of linear waste management systems – was applied to the management of municipal organic waste in the Spanish region of Cantabria. The system model was constructed combining material flow analysis, life cycle assessment and life cycle costing tools. A multi-objective optimization problem was formulated to maximize nutrient circularity and minimize resource use, environmental impacts and waste management costs. The results suggest that improving resource circularity can lead to increased costs and does not necessarily entail a decrease in the consumption of natural resources or the emission of environmental burdens.The author has been the recipient of two predoctoral fellowships granted by the University of Cantabria and the Spanish Ministry of Education (code FPU 15/01771). Her visit to NCSU was funded by a predoctoral mobility scholarship awarded by the University of Cantabria and by the research project CTQ2016-76231-C2-1-R, whereas her research at Cornell University was sponsored by the FPU program (code EST18/00007). She gratefully acknowledges this financial support

A System Dynamics Model to Predict Municipal Waste Generation and Management Costs in Developing Areas

This paper utilized system dynamics modeling as a new analytical approach to predict both the municipal waste generated and the associated disposal costs in developing areas. This approach facilitates the decomposition of general waste into its main components to enable municipalities to manage recyclables and find out the feasibility of performing recycling better rather than disposal by performing comparative disposal cost analysis. This study is different from previous work as it only considers population as a factor to predict the total waste generated and recycled, together with the associated expenditure and disposal cost savings. The approach is verified by applying it to a case study in Nablus and demonstrates the evaluation of the quantity and composition of generated waste by considering population as the main influencing factor. The quantity and composition of municipal solid waste was evaluated to identify opportunities for waste recycling in the Nablus municipality. Municipal solid waste was collected and classified into eight main physical categories. The system dynamics model enable the quantity of each generated component such as plastic and metals to be anticipated together with the cost of recycling or disposal

Hydrothermal processing of biogenic residues in Germany: A technology assessment considering development paths by 2030

The mining, processing, and use of finite natural resources is associated with significant interventions in the natural environment. Thus, these and other negative consequences make it necessary to reduce resource consumption. An important field of action is the more efficient use of biogenic residues as secondary raw materials. However, high water containing biomasses are still a problem since they need an energy- and cost-intensive pre-treatment for many conversion processes, which can make their use uneconomical. Hydrothermal processes (HTP) seem to be promising, since they require an aqueous environment for optimal processing anyway. Although technological progress within the industry is recognisable, however, to date HTP have not been established in industrial continuous operation in Germany. The core of this work is identifying reasons for this sluggish development and deriving appropriate recommendations for action. Based on the hypothesis that HTP can contribute to the efficient utilisation of biogenic residues in the future, potentials and obstacles for the development of HTP in Germany are identified using a literature review, expert survey, expert workshop, and SWOT analysis. To estimate the future potential of HTP in a systematic and structured way, a multi-criteria technology assessment approach is developed based on the results. To this end, assessment criteria for HTP are derived, weighted by expert judgment, and integrated into a transparent and structured procedure. In addition, mainly based on a Delphi-survey key factors of HTP development by 2030 in Germany are identified and three development alternatives for HTP in Germany by 2030 are derived. Using a system analysis and a comparative multi-criteria analysis at plant level, these scenarios are analysed for their possible future impact. Based on this methodology, the work shows that the production costs for the end products, the energy efficiency of the process, and the proportion of recycled phosphorus are of high relevance to the techno-economic success of HTP compared to reference systems, and they are therefore of high importance for its future development on the plant level. In addition, further key factors for the future development of HTP in Germany on the system level are found to be mainly in the political-legal (e.g. legal waste status of products from HTP) and techno-economic (e.g. cost-effective process water treatment) areas. According to this, important fields of action are the identification and use of cost reduction potentials (e.g. heat waste use), the development of system integrated decentralised plant concepts with integrated nutrient recycling (e.g. phosphorus), and the development of cost-effective ways to treat process water. System integration, cost-effective process water treatment, and nutrient recycling are all closely linked to production costs, investment costs, and potential revenues, and can contribute to improved process economics. For these areas, there is promising future potential to achieve higher competitiveness with reference technologies that are currently more economical.:Bibliographic description Curriculum Vitae Selbstständigkeitserklärung Danksagung List of Publications Contribution to the Publications Contents List of Acronyms List of Tables List of Figures Part I Introductory Chapters 1 Introduction and Background Hydrothermal processes: Introduction and status quo State of the art in the research field and knowledge gaps Objective and research framework Expected value added of this work 2 Materials and methods Derivation of HTP evaluation metrics and technology assessment tool Derivation of key HTP development factors and scenarios Performing the system-level scenario analysis Plant-level scenario analysis and test application of the assessment tool Derivation of core recommendations 3 Results and discussion Key development factors for HTP in Germany and scenarios System-level scenario analysis Test application of the assessment tool on plant level scenarios Recommendations Discussion 4 Conclusion and outlook Future research Further fields for the application of the developed methods 5 References Part II Appended Articles Paper I Paper II Paper III Paper IV Paper V Paper VIDer Abbau, die Verarbeitung und die Nutzung endlicher natürlicher Ressourcen sind mit erheblichen Eingriffen in die natürliche Umwelt verbunden. Diese und andere negative Folgen machen es daher erforderlich, den Ressourcenverbrauch zu senken. Ein wichtiges Handlungsfeld ist die effizientere Nutzung biogener Reststoffe als Sekundärrohstoffe. Stark wasserhaltige Biomassen sind jedoch ein Problem, da sie für viele Umwandlungsprozesse eine energie- und kostenintensive Vorbehandlung benötigen, was ihre Verwendung unwirtschaftlich machen kann. Hydrothermale Prozesse (HTP) scheinen für diese Reststoffe allerdings vielversprechend zu sein, da sie ohnehin eine wässrige Umgebung für eine optimale Verarbeitung benötigen. Obwohl der technologische Fortschritt innerhalb der Branche erkennbar ist, wurde HTP in Deutschland bisher nicht im industriellen Dauerbetrieb etabliert. Der Kern dieser Arbeit besteht darin, Gründe für diese schleppende Entwicklung zu ermitteln und geeignete Handlungsempfehlungen abzuleiten. Basierend auf der Hypothese, dass HTP in Zukunft zur effizienten Nutzung biogener Reststoffe beitragen können, werden Potenziale und Hindernisse für deren Entwicklung in Deutschland anhand einer Literaturrecherche, einer Expertenumfrage, eines Expertenworkshops und einer SWOT-Analyse ermittelt. Um das zukünftige Potenzial von HTP systematisch und strukturiert abzuschätzen, wird basierend auf den Ergebnissen ein multi-kriterieller Technologiebewertungsansatz entwickelt. Zu diesem Zweck werden Bewertungskriterien für HTP abgeleitet, nach Expertenmeinung gewichtet und in ein transparentes und strukturiertes Verfahren integriert. Darüber hinaus werden hauptsächlich auf der Grundlage einer Delphi-Umfrage Schlüsselfaktoren für die HTP-Entwicklung bis 2030 in Deutschland identifiziert und drei Entwicklungsalternativen für HTP in Deutschland bis 2030 abgeleitet. Mithilfe einer Systemanalyse und einer vergleichenden multi-kriteriellen Analyse auf Anlagenebene werden diese Szenarien auf ihre möglichen zukünftigen Auswirkungen hin analysiert. Basierend auf dieser Methodik zeigen sich als Ergebnisse, dass die Produktionskosten für die Endprodukte, die Energieeffizienz der Prozesse und der Anteil an recyceltem Phosphor für den techno-ökonomischen Erfolg von HTP im Vergleich zu Referenzsystemen von hoher Relevanz und daher auch von hoher Bedeutung für die zukünftige Entwicklung auf Anlagenebene sind. Darüber hinaus liegen weitere Schlüsselfaktoren für die künftige Entwicklung von HTP in Deutschland auf Systemebene hauptsächlich im politisch-rechtlichen (z. B. legalen Abfallstatus von Produkten aus HTP) und techno-ökonomischen (z. B. kostengünstige Prozesswasseraufbereitung)) Bereichen. Wichtige Handlungsfelder sind demnach die Ermittlung und Nutzung von Kostensenkungspotentialen (zB Abwärmenutzung), die Entwicklung systemintegrierter dezentraler Anlagenkonzepte mit integriertem Nährstoffrecycling (z.B. Phosphor) und die Entwicklung kostengünstiger Wege zur Prozesswasserbehandlung. Systemintegration, kostengünstige Prozesswasseraufbereitung und Nährstoffrecycling hängen eng mit Produktionskosten, Investitionskosten und potenziellen Einnahmen zusammen und können zu einer verbesserten Wirtschaftlichkeit der Prozesse beitragen. Für diese Bereiche besteht ein vielversprechendes Zukunftspotenzial für eine höhere Wettbewerbsfähigkeit zu Referenztechnologien, die derzeit noch wirtschaftlicher sind.:Bibliographic description Curriculum Vitae Selbstständigkeitserklärung Danksagung List of Publications Contribution to the Publications Contents List of Acronyms List of Tables List of Figures Part I Introductory Chapters 1 Introduction and Background Hydrothermal processes: Introduction and status quo State of the art in the research field and knowledge gaps Objective and research framework Expected value added of this work 2 Materials and methods Derivation of HTP evaluation metrics and technology assessment tool Derivation of key HTP development factors and scenarios Performing the system-level scenario analysis Plant-level scenario analysis and test application of the assessment tool Derivation of core recommendations 3 Results and discussion Key development factors for HTP in Germany and scenarios System-level scenario analysis Test application of the assessment tool on plant level scenarios Recommendations Discussion 4 Conclusion and outlook Future research Further fields for the application of the developed methods 5 References Part II Appended Articles Paper I Paper II Paper III Paper IV Paper V Paper V