714 research outputs found

    Analysis of relevant technical issues and deficiencies of the existing sensors and related initiatives currently set and working in marine environment. New generation technologies for cost-effective sensors

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    The last decade has seen significant growth in the field of sensor networks, which are currently collecting large amounts of environmental data. This data needs to be collected, processed, stored and made available for analysis and interpretation in a manner which is meaningful and accessible to end users and stakeholders with a range of requirements, including government agencies, environmental agencies, the research community, industry users and the public. The COMMONSENSE project aims to develop and provide cost-effective, multi-functional innovative sensors to perform reliable in-situ measurements in the marine environment. The sensors will be easily usable across several platforms, and will focus on key parameters including eutrophication, heavy metal contaminants, marine litter (microplastics) and underwater noise descriptors of the MSFD. The aims of Tasks 2.1 and 2.2 which comprise the work of this deliverable are: • To obtain a comprehensive understanding and an up-to-date state of the art of existing sensors. • To provide a working basis on “new generation” technologies in order to develop cost-effective sensors suitable for large-scale production. This deliverable will consist of an analysis of state-of-the-art solutions for the different sensors and data platforms related with COMMONSENSE project. An analysis of relevant technical issues and deficiencies of existing sensors and related initiatives currently set and working in marine environment will be performed. Existing solutions will be studied to determine the main limitations to be considered during novel sensor developments in further WP’s. Objectives & Rationale The objectives of deliverable 2.1 are: • To create a solid and robust basis for finding cheaper and innovative ways of gathering data. This is preparatory for the activities in other WPs: for WP4 (Transversal Sensor development and Sensor Integration), for WP(5-8) (Novel Sensors) to develop cost-effective sensors suitable for large-scale production, reducing costs of data collection (compared to commercially available sensors), increasing data access availability for WP9 (Field testing) when the deployment of new sensors will be drawn and then realized

    Electrochemical method for the rapid in situ screening of heavy metals in soil and water samples

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    The aim of this work has been to develop a field-based electrochemical sensor for the detection of cadmium (Cd), lead (Pb), copper (Cu), zinc (Zn), arsenic (As) and mercury (Hg) in soil and water samples. In situ analysis, using rapid sample screening tools, can facilitate monitoring and remediation processes by minimising delays and substantially reducing costs. Disposable screen-printed electrodes (SPEs) have been fabricated using low-cost thick film technology. Carbon SPEs, coupled with anodic stripping voltammetry (ASV), provided a rapid, inexpensive in situ electrochemical screening sensor capable of simultaneously detecting Cd, Pb and Cu in soil and water samples in the microgram per liter range (pg I*1). A simplified soil extraction procedure, using 1 mol I'1 aqua regia and a three minute ultrasonic sample agitation, was developed for use with the sensor, addressing the lack of existing field-based soil extraction protocol. Extraction efficiency was evaluated using a soil certified reference material (CRM). Recoveries of 64%, 52% and 57% for Cd, Pb and Cu respectively were obtained, with a relative standard deviation (RSD) of <8% for all analytes (n=10). 82 soil samples were tested using the combined extraction + ASV sensor and compared against standard ICP-MS analysis. Correlation coefficients of 0.9782, 0.9728 and 0.9869 for Cd, Pb and Cu, respectively, indicated a good linear relationship between the two methods. A novel gold (Au) SPE, fabricated using a curable Au ink, was next evaluated for the detection of As and Hg. This is an improvement in the current state-of the-art as no surface modification or subsequent electrode adulteration to facilitate metal analyte depositioning is required. Furthermore, the Au ink can be cured at a low temperature (130°C), permitting electrode fabrication using disposable, cheap, plastic substrates. A patent has been filed. A limit of detection (LOD) of 2.7 pg I"1 and 1 pg I"1 for As3+ and Hg2+, respectively, was obtained following a 30 s depositioning. Speciation measurements for As were performed by reducing As5+ effectively over a short (10 min) reduction time using cysteine. An LOD of 42 pg f 1 following a 30 s depositioning was obtained. Initial studies also indicated the possibility of using the Au SPEs for measuring Cd, Pb and Cu, providing an alterative Hg-free procedure.Ph

    Abstracts of Papers Presented at the 2008 Pittsburgh Conference

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    Sustainable Environmental Solutions

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    This book collects research activities focused on the development of new processes to replace obsolete practices that are often highly invasive, unsustainable, and socially unacceptable.Taking inspiration from real problems and the need to face real cases of contamination or prevent potentially harmful situations, the development and optimization of ‘smart’ solutions, i.e., sustainable not only from an environmental point of view but also economically, are discussed in order to encourage, as much as possible, their actual implementation

    Biosensors for Environmental Monitoring

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    Real-time and reliable detection of molecular compounds and bacteria is essential in modern environmental monitoring. For rapid analyses, biosensing devices combining high selectivity of biomolecular recognition and sensitivity of modern signal-detection technologies offer a promising platform. Biosensors allow rapid on-site detection of pollutants and provide potential for better understanding of the environmental processes, including the fate and transport of contaminants.This book, including 12 chapters from 37 authors, introduces different biosensor-based technologies applied for environmental analyses

    Field methods for rapidly characterizing contaminant mobility in paint waste during bridge rehabilitation

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    Currently, the New York State Department of Transportation (NYSDOT) uses a conservative approach of classifying all paint waste as hazardous from bridges undergoing rehabilitation which were constructed before 1989. This practice stems from the fact that there is no approved reliable, fast, and efficient method for classifying paint waste in-situ as non-hazardous. The main objective of this study was to develop a model that can predict the leachability of trace metals in paint waste generated during bridge rehabilitation. A statistically significant number of bridge sites were sampled based on hypothesis testing. Samples were then evaluated for total concentration of Resource Conservation and Recovery Act (RCRA) metals (i.e., Ag, As, Ba, Cd, Cr, Hg, Pb, and Se), iron as well as zinc. Leaching studies included the U.S. Environmental Protection Agency (U.S. EPA) toxicity characteristic leaching procedure (TCLP) and the multiple extraction procedure (MEP). Interestingly, although elevated Pb (5 to 168,090 mg kg-1) and other metal concentrations were observed in the paint samples, leaching results revealed only up to 22.6 mg L-1 for Pb and 9.52 mg L-1 for Cr. The relatively low concentrations observed are attributed to the use of iron-based abrasives (steel grit) in the paint removal process. In New York State, steel grit is typically applied as an abrasive material to remove paint during bridge rehabilitation. Although magnetic separation is applied to collect and reuse the steel grit, the fraction remaining in the paint waste ranges from 5 to 80% by weight. Using the suite of analyses, ferrihyidrite was observed to be an important mineral surface on the steel grit; spherical particle aggregates ranged from 20 to 200 nm in diameter. In addition, sequential extraction revealed trace metal sorption to the iron oxide surface may be the dominant mechanism responsible for the reduced leaching observed. The sorption process was further modeled using the diffuse layer model. Based on an understanding of mechanistic processes along with a demonstrated analysis of variables through principal component analysis (PCA), statistically-based models for leaching from paint waste were developed. Results of this work assist in better understanding and predicting the mobility of trace metals as well as in addressing disposal and management of paint waste during bridge rehabilitation

    Olive Oil Traceability

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    Time for a Nappy Change: beliefs and attitudes towards modern cloth nappies.

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    The United Nations Environment Programme highlights how the use of disposable nappies has become unsustainable, yet the practice of using modern cloth nappies (MCN) is niche. This study uses mixed methods of survey, story completion and focus group methods to explore how behaviour beliefs and attitudes to behaviour contribute to families’ decision making regarding the nappy system they use for their children. 1588 responded to the survey; 38 completed story completion activity; 24 participated in groups. This study finds that beliefs about the performance as a nappy, environmental credentials, financial considerations, laundry, effort, and hygiene differ according to the level of personal experience of using MCN. While beliefs about the environmentalcredentials of MCN create powerful drivers for the intention to use MCN, other beliefs about the upfront costs, laundry and effort contribute a negative attitude to MCN overall if their support network of other MCN users is not established. Current MCN users found using cloth nappy retailer websites, nappy libraries, and social media groups, including pre-loved and-sell groups, to be beneficial in improving attitude to MCN. This study concludes that interventions that simultaneously reduce or remove perceived barriers such as upfront costs, financial risks and too much effort, paired with campaigns which increase the likelihood of finding support, are more likely, than individual interventions, to be effective in increasing the number of families using MCN.Further study is needed to investigate the potential of interventions which reduce the financial risks such as, easy to access hire kits, spread the cost of MCN and pre-natal and newborn public services such as midwives and health visitors being well informed and encouraging of the use of MCN.<br/

    Biosensors

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    A biosensor is defined as a detecting device that combines a transducer with a biologically sensitive and selective component. When a specific target molecule interacts with the biological component, a signal is produced, at transducer level, proportional to the concentration of the substance. Therefore biosensors can measure compounds present in the environment, chemical processes, food and human body at low cost if compared with traditional analytical techniques. This book covers a wide range of aspects and issues related to biosensor technology, bringing together researchers from 11 different countries. The book consists of 16 chapters written by 53 authors. The first four chapters describe several aspects of nanotechnology applied to biosensors. The subsequent section, including three chapters, is devoted to biosensor applications in the fields of drug discovery, diagnostics and bacteria detection. The principles behind optical biosensors and some of their application are discussed in chapters from 8 to 11. The last five chapters treat of microelectronics, interfacing circuits, signal transmission, biotelemetry and algorithms applied to biosensing

    Laboratory Directed Research and Development Annual Report - Fiscal Year 2000

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