Laser ignition of an optically sensitised secondary explosive by a diode laser

As a green technology, laser ignition of a relatively insensitive secondary explosive has been experimentally investigated. The explosive, hexanitrostilbene (HNS), was doped with one of two optical sensitizers, carbon black or a laser absorbing dye, and a continuous-wave (CW) infrared diode laser was used as the igniting source. The ignition sensitivities of HNS with each of the two optical sensitizers were analysed and compared in terms of: optical power threshold for ignition, ignition delay and full burn delay at various laser powers. The results have shown that both the chemical dye and carbon black optically sensitize the explosive with similar efficiencies. In contrast to the carbon black, the dye provides wavelength specificity and selectivity in the laser ignition process and its solubility in some specific solvents improves the coating of the explosive material. It was therefore concluded that the laser absorbing dye is a better candidate for optical sensitization in laser ignition than the commonly used carbon black. The combination of laser ignition sensitivity with wavelength selectivity potentially offers higher reliability and safety at a low optical power for future ignitors of secondary explosives

Ionic polarization-induced current-voltage hysteresis in ch3nh3pbx3 perovskite solar cells

CH3NH3PbX3 (MAPbX3) perovskites have attracted considerable attention as absorber materials for solar light harvesting, reaching solar to power conversion efficiencies above 20%. In spite of the rapid evolution of the efficiencies, the understanding of basic properties of these semiconductors is still ongoing. One phenomenon with so far unclear origin is the so-called hysteresis in the current–voltage characteristics of these solar cells. Here we investigate the origin of this phenomenon with a combined experimental and computational approach. Experimentally the activation energy for the hysteretic process is determined and compared with the computational results. First-principles simulations show that the timescale for MAþ rotation excludes a MA-related ferroelectric effect as possible origin for the observed hysteresis. On the other hand, the computationally determined activation energies for halide ion (vacancy) migration are in excellent agreement with the experimentally determined values, suggesting that the migration of this species causes the observed hysteretic behaviour of these solar cells

Coherent control of photocurrent in a strongly scattering photoelectrochemical system

A fundamental issue that limits the efficiency of many photoelectrochemical systems is that the photon absorption length is typically much longer than the electron diffusion length. Various photon management schemes have been developed to enhance light absorption; one simple approach is to use randomly scattering media to enable broadband and wide-angle enhancement. However, such systems are often opaque, making it difficult to probe photo-induced processes. Here we use wave interference effects to modify the spatial distribution of light inside a highly-scattering dye-sensitized solar cell to control photon absorption in a space-dependent manner. By shaping the incident wavefront of a laser beam, we enhance or suppress photocurrent by increasing or decreasing light concentration on the front side of the mesoporous photoanode where the collection efficiency of photoelectrons is maximal. Enhanced light absorption is achieved by reducing reflection through the open boundary of the photoanode via destructive interference, leading to a factor of two increase in photocurrent. This approach opens the door to probing and manipulating photoelectrochemical processes in specific regions inside nominally opaque media.Comment: 21 pages, 4 figures, in submission. The first two authors contributed equally to this paper, and should be regarded as co-first author

Electrochemical and photoelectrochemical properties of nickel oxide (NiO) with nanostructured morphology for photoconversion applications

The cost-effective production of chemicals in electrolytic cells and the conversion of the radiation energy into electrical energy in photoelectrochemical cells (PECs) require the use of electrodes with large surface area, which possess either electrocatalytic or photoelectrocatalytic properties. In this context nanostructured semiconductors are electrodic materials of great relevance because of the possibility of varying their photoelectrocatalytic properties in a controlled fashion via doping, dye-sensitization or modification of the conditions of deposition. Among semiconductors for electrolysers and PECs the class of the transition metal oxides (TMOs) with a particular focus on NiO interests for the chemical-physical inertness in ambient conditions and the intrinsic electroactivity in the solid state. The latter aspect implies the existence of capacitive properties in TMO and NiO electrodes which thus act as charge storage systems. After a comparative analysis of the (photo)electrochemical properties of nanostructured TMO electrodes in the configuration of thin film the use of NiO and analogs for the specific applications of water photoelectrolysis and, secondly, photoelectrochemical conversion of carbon dioxide will be discussed. © 2018 Bonomo, Dini and Decker

A multiscale constitutive model for intergranular stress corrosion cracking in type 304 austenitic stainless steel

Intergranular stress corrosion cracking (IGSCC) is a fracture mechanism in sensitised austenitic stainless steels exposed to critical environments where the intergranular cracks extends along the network of connected susceptible grain boundaries. A constitutive model is presented to estimate the maximum intergranular crack growth by taking into consideration the materials mechanical properties and microstructure characters distribution. This constitutive model is constructed based on the assumption that each grain is a two phase material comprising of grain interior and grain boundary zone. The inherent micro-mechanisms active in the grain interior during IGSCC is based on crystal plasticity theory, while the grain boundary zone has been modelled by proposing a phenomenological constitutive model motivated from cohesive zone modelling approach. Overall, response of the representative volume is calculated by volume averaging of individual grain behaviour. Model is assessed by performing rigorous parametric studies, followed by validation and verification of the proposed constitutive model using representative volume element based FE simulations reported in the literature. In the last section, model application is demonstrated using intergranular stress corrosion cracking experiments which shows a good agreement

A multiscale constitutive model for intergranular stress corrosion cracking in type 304 austenitic stainless steel

Peer reviewedPublisher PD

A multiscale constitutive model for intergranular stress corrosion cracking in type 304 austenitic stainless steel

Intergranular stress corrosion cracking (IGSCC) is a fracture mechanism in sensitised austenitic stainless steels exposed to critical environments where the intergranular cracks extends along the network of connected susceptible grain boundaries. A constitutive model is presented to estimate the maximum intergranular crack growth by taking into consideration the materials mechanical properties and microstructure characters distribution. This constitutive model is constructed based on the assumption that each grain is a two phase material comprising of grain interior and grain boundary zone. The inherent micro-mechanisms active in the grain interior during IGSCC is based on crystal plasticity theory, while the grain boundary zone has been modelled by proposing a phenomenological constitutive model motivated from cohesive zone modelling approach. Overall, response of the representative volume is calculated by volume averaging of individual grain behaviour. Model is assessed by performing rigorous parametric studies, followed by validation and verification of the proposed constitutive model using representative volume element based FE simulations reported in the literature. In the last section, model application is demonstrated using intergranular stress corrosion cracking experiments which shows a good agreement

Ignorance is Almost Bliss: Near-Optimal Stochastic Matching With Few Queries

The stochastic matching problem deals with finding a maximum matching in a graph whose edges are unknown but can be accessed via queries. This is a special case of stochastic $k$-set packing, where the problem is to find a maximum packing of sets, each of which exists with some probability. In this paper, we provide edge and set query algorithms for these two problems, respectively, that provably achieve some fraction of the omniscient optimal solution. Our main theoretical result for the stochastic matching (i.e., $2$-set packing) problem is the design of an \emph{adaptive} algorithm that queries only a constant number of edges per vertex and achieves a $(1-\epsilon)$ fraction of the omniscient optimal solution, for an arbitrarily small $\epsilon>0$. Moreover, this adaptive algorithm performs the queries in only a constant number of rounds. We complement this result with a \emph{non-adaptive} (i.e., one round of queries) algorithm that achieves a $(0.5 - \epsilon)$ fraction of the omniscient optimum. We also extend both our results to stochastic $k$-set packing by designing an adaptive algorithm that achieves a $(\frac{2}{k} - \epsilon)$ fraction of the omniscient optimal solution, again with only $O(1)$ queries per element. This guarantee is close to the best known polynomial-time approximation ratio of $\frac{3}{k+1} -\epsilon$ for the \emph{deterministic} $k$-set packing problem [Furer and Yu, 2013] We empirically explore the application of (adaptations of) these algorithms to the kidney exchange problem, where patients with end-stage renal failure swap willing but incompatible donors. We show on both generated data and on real data from the first 169 match runs of the UNOS nationwide kidney exchange that even a very small number of non-adaptive edge queries per vertex results in large gains in expected successful matches