Advances in Middle Infrared Laser Crystals and Its Applications

In the last twenty years, there has been a growing interest in middle infrared (mid-IR) laser crystals and their application to achieve mid-IR laser radiations, which has benefited from the development of novel mid-infrared crystals and the improving quality of traditional mid-IR crystals. Moreover, these works have promoted the development of related technical applications. This Special Issue of the journal Crystals focuses on the most recent advances in mid-IR laser crystals, from materials to laser sources and applications. It aims to bring together the latest developments in novel mid-IR crystals, improvements in the quality of mid-IR crystals, mid-IR non-linear crystals and mid-IR lasers, as well as the application of mid-IR technology in spectroscopy, trace gas detection and remote sensing, optical microscopy and biomedicine. Aspiring authors are encouraged to submit their latest original research, as well as forward-looking review papers, to this Special Issue

Low Noise And Low Repetition Rate Semiconductor-based Mode-locked Lasers

The topic of this dissertation is the development of low repetition rate and low noise semiconductor-based laser sources with a focus on linearly chirped pulse laser sources. In the past decade chirped optical pulses have found a plethora of applications such as photonic analogto-digital conversion, optical coherence tomography, laser ranging, etc. This dissertation analyzes the aforementioned applications of linearly chirped pulses and their technical requirements, as well as the performance of previously demonstrated chirped pulse laser sources. Moreover, the focus is shifted to a specific application of the linearly chirped pulses, timestretched photonic analog-to-digital conversion (TS ADC). The challenges of surpassing the speeds of current electronic converters are discussed, while the need for low noise linearly chirped pulse lasers becomes apparent for the realization of TS ADC. The experimental research addresses the topic of low noise chirped pulse generation in three distinct ways. First, a chirped pulse (Theta) laser with an intra-cavity Fabry-Pérot etalon and a long-term referencing mechanism is developed that results in the reduction of the pulse-topulse energy noise. Noise suppression of \u3e 15 times is demonstrated. Moreover, an optical frequency comb with spacing equal to the repetition rate (≈100 MHz) is generated using the etalon, resulting in the first reported demonstration of a system operating in the sub-GHz regime based on semiconductor gain. The path for the development of the Theta laser was laid by the precise characterization of the etalon used in this laser cavity design. A narrow linewidth laser is used in conjunction with an acousto-optic modulator externally swept for measuring the etalon\u27s iv free spectral range with a sub-Hz precision, or 10 parts per billion. Furthermore, the measurement of the etalon long-term drift and birefringence lead to the development of a modified intra-cavity Hänsch-Couillaud locking mechanism for the Theta laser. Moreover, an external feed-forward system was demonstrated that aimed at increasing the temporal/spectral uniformity of the optical pulses. A complete characterization of the system is demonstrated. On a different series of experiments, the pulses emitted by an ultra-low noise but high repetition rate mode-locked laser were demultiplexed resulting in a low repetition rate pulse train. Experimental investigation of the noise properties of the laser proved that they are preserved during the demultiplexing process. The noise of the electrical gate used in this experiment is also investigated which led into the development of a more profound understanding of the electrical noise of periodical pulses and a mechanism of measuring their noise. The appendices in this dissertation provide additional material used for the realization of the main research focus of the dissertation. Measurements of the group delay of the etalon used in the Theta laser are presented in order to demonstrate the limiting factors for the development of this cavity design. The description of a balancing routine is presented, that was used for expanding the dynamic range of intra-cavity active variable delay. At last, the appendix presents the calculations regarding the contribution of various parameters in the limitations of analog-todigital conversion

Scientific Opportunities with an X-ray Free-Electron Laser Oscillator

An X-ray free-electron laser oscillator (XFELO) is a new type of hard X-ray source that would produce fully coherent pulses with meV bandwidth and stable intensity. The XFELO complements existing sources based on self-amplified spontaneous emission (SASE) from high-gain X-ray free-electron lasers (XFEL) that produce ultra-short pulses with broad-band chaotic spectra. This report is based on discussions of scientific opportunities enabled by an XFELO during a workshop held at SLAC on June 29 - July 1, 2016Comment: 21 pages, 12 figure

XUV Frequency Combs via Femtosecond Enhancement Cavities

We review the current state of tabletop extreme ultraviolet (XUV) sources based on high harmonic generation (HHG) in femtosecond enhancement cavities (fsEC). Recent developments have enabled generation of high photon flux (1014 photons/sec) in the XUV, at high repetition rates (>50 MHz) and spanning the spectral region from 40 nm - 120 nm. This level of performance has enabled precision spectroscopy with XUV frequency combs and promises further applications in XUV spectroscopic and photoemission studies. We discuss the theory of operation and experimental details of the fsEC and XUV generation based on HHG, including current technical challenges to increasing the photon flux and maximum photon energy produced by this type of system. Current and future applications for these sources are also discussed.Comment: invited review article, 38 page

二周波数注入同期連続発振チタンサファイアレーザーの開発とその非線形光学現象への応用

This thesis describes the development of dual-frequency injection-locked (DFIL) continuous-wave titanium-sapphire laser and its applications in the study of cavity based stimulated Raman scattering and also in the generation of phase locked harmonics by optical frequency division technology to demonstrate the continuous wave based arbitrary optical wave form synthesis. At first, the DFIL laser fundamental properties such as single longitudinal mode profile, single transverse mode, and practical power stability were characterized. The DFIL laser delivers a maximum of 2.8 W total output power at a 10 W pump power. As the advanced abilities, desirable two frequency separation (1 THz to 10 THz) and well controlled relative output power ratios as a function of injection seed powers over a wide dynamic range were demonstrated. As an application of the DFIL laser, CW laser based stimulated Raman scattering in the para- H2 gas medium was studied. For this purpose, Ti: sapphire laser output was coupled to the high finesse optical cavity and observed multiple Stokes and anti-Stokes rotational Raman components of the para-H2 J=0 to J=2 rotational transition. Efficient anti-Stokes generation through four wave mixing process was obtained by controlling the gas density for a fixed mirror dispersion which was introduced from its dielectric coating. The output of the Ti: sapphire laser was coupled to an array of periodically poled lithium niobate (PPLN) wave guides, together with another IR frequency and generated phase locked five harmonics with a frequency spacing of 125 THz by the optical division technology. These phase locked harmonics were synthesized to obtain the arbitrary optical wave form by utilizing the novel technique of the freely controlled optical phases and amplitudes by controlling the thickness of the transparent dispersive media in the optical path. In this way, an ultrashort pulse train with a repetition rate of 125 THz and a pulse duration of 1.6 fs was obtained.電気通信大学201

Mechanical Properties of Low Dimensional Materials

Recent advances in low dimensional materials (LDMs) have paved the way for unprecedented technological advancements. The drive to reduce the dimensions of electronics has compelled researchers to devise newer techniques to not only synthesize novel materials, but also tailor their properties. Although micro and nanomaterials have shown phenomenal electronic properties, their mechanical robustness and a thorough understanding of their structure-property relationship are critical for their use in practical applications. However, the challenges in probing these mechanical properties dramatically increase as their dimensions shrink, rendering the commonly used techniques inadequate. This Dissertation focuses on developing techniques for accurate determination of elastic modulus of LDMs and their mechanical responses under tensile and shear stresses. Fibers with micron-sized diameters continuously undergo tensile and shear deformations through many phases of their processing and applications. Significant attention has been given to their tensile response and their structure-tensile properties relations are well understood, but the same cannot be said about their shear responses or the structure-shear properties. This is partly due to the lack of appropriate instruments that are capable of performing direct shear measurements. In an attempt to fill this void, this Dissertation describes the design of an inexpensive tabletop instrument, referred to as the twister, which can measure the shear modulus (G) and other longitudinal shear properties of micron-sized individual fibers. An automated system applies a pre-determined twist to the fiber sample and measures the resulting torque using a sensitive optical detector. The accuracy of the instrument was verified by measuring G for high purity copper and tungsten fibers. Two industrially important fibers, IM7 carbon fiber and Kevlar® 119, were found to have G = 17 and 2.4 GPa, respectively. In addition to measuring the shear properties directly on a single strand of fiber, the technique was automated to allow hysteresis, creep and fatigue studies. Zinc oxide (ZnO) semiconducting nanostructures are well known for their piezoelectric properties and are being integrated into several nanoelectro-mechanical (NEMS) devices. In spite of numerous studies on the mechanical response of ZnO nanostructures, there is not a consensus in its measured bending modulus (E). In this Dissertation, by employing an all-electrical Harmonic Detection of Resonance (HDR) technique on ZnO nanowhisker (NW) resonators, the underlying origin for electrically-induced mechanical oscillations in a ZnO NW was elucidated. Based on visual detection and electrical measurement of mechanical resonances under a scanning electron microscope (SEM), it was shown that the use of an electron beam as a resonance detection tool alters the intrinsic electrical character of the ZnO NW, and makes it difficult to identify the source of the charge necessary for the electrostatic actuation. A systematic study of the amplitude of electrically actuated as-grown and gold-coated ZnO NWs in the presence (absence) of an electron beam using an SEM (dark-field optical microscope) suggests that the oscillations seen in our ZnO NWs are due to intrinsic static charges. In experiments involving mechanical resonances of micro and nanostructured resonators, HDR is a tool for detecting transverse resonances and E of the cantilever material. To add to this HDR capability, a novel method of measuring the G using HDR is presented. We used a helically coiled carbon nanowire (HCNW) in singly-clamped cantilever configuration, and analyzed the complex (transverse and longitudinal) resonance behavior of the nonlinear geometry. Accordingly, a synergistic protocol was developed which (i) integrated analytical, numerical (i.e., finite element using COMSOL ®) and experimental (HDR) methods to obtain an empirically validated closed form expression for the G and resonance frequency of a singly-clamped HCNW, and (ii) provided an alternative for solving 12th order differential equations. A visual detection of resonances (using in situ SEM) combined with HDR revealed intriguing non-planar resonance modes at much lower driving forces relative to those needed for linear carbon nanotube cantilevers. Interestingly, despite the presence of mechanical and geometrical nonlinearities in the HCNW resonance behavior, the ratio of the first two transverse modes f2/f1 was found to be similar to the ratio predicted by the Euler-Bernoulli theorem for linear cantilevers

Study of resonance light scattering for remote optical probing

Enhanced scattering and fluorescence processes in the visible and UV were investigated which will enable improved remote measurements of gas properties. The theoretical relationship between scattering and fluorescence from an isolated molecule in the approach to resonance is examined through analysis of the time dependence of re-emitted light following excitation of pulsed incident light. Quantitative estimates are developed for the relative and absolute intensities of fluorescence and resonance scattering. New results are obtained for depolarization of scattering excited by light at wavelengths within a dissociative continuum. The experimental work was performed in two separate facilities. One of these utilizes argon and krypton lasers, single moded by a tilted etalon, and a 3/4 meter double monochromator. This facility was used to determine properties of the re-emission from NO2, I2 and O3 excited by visible light. The second facility involves a narrow-line dye laser, and a 3/4 meter single monochromator. The dye laser produces pulsed light with 5 nsec pulse duration and 0.005 nm spectral width