Loss of control in pattern-directed nucleation: a theoretical study

The properties of template-directed nucleation are studied close to the transition where full nucleation control is lost and additional nucleation occurs beyond the pre-patterned regions. First, kinetic Monte Carlo simulations are performed to obtain information on a microscopic level. Here the experimentally relevant cases of 1D stripe patterns and 2D square lattice symmetry are considered. The nucleation properties in the transition region depend in a complex way on the parameters of the system, i.e. the flux, the surface diffusion constant, the geometric properties of the pattern and the desorption rate. Second, the properties of the stationary concentration field in the fully controlled case are studied to derive the remaining nucleation probability and thus to characterize the loss of nucleation control. Using the analytically accessible solution of a model system with purely radial symmetry, some of the observed properties can be rationalized. A detailed comparison to the Monte Carlo data is included

Mean curvature flow with free boundary outside a hypersphere

The purpose of this paper is twofold: firstly, to establish sufficient conditions under which the mean curvature flow supported on a hypersphere with exterior Dirichlet boundary exists globally in time and converges to a minimal surface, and secondly, to illustrate the application of Killing vector fields in the preservation of graphicality for the mean curvature flow with free boundary. To this end we focus on the mean curvature flow of a topological annulus with inner boundary meeting a standard n-sphere in \R^{n+1} perpendicularly and outer boundary fixed to an (n-1)-sphere with radius R>1 at a fixed height h. We call this the \emph{sphere problem}. Our work is set in the context of graphical mean curvature flow with either symmetry or mean concavity/convexity restrictions. For rotationally symmetric initial data we obtain, depending on the exact configuration of the initial graph, either long time existence and convergence to a minimal hypersurface with boundary or the development of a finite-time curvature singularity. With reflectively symmetric initial data we are able to use Killing vector fields to preserve graphicality of the flow and uniformly bound the mean curvature pointwise along the flow. Finally we prove that the mean curvature flow of an initially mean concave/convex graphical surface exists globally in time and converges to a piece of a minimal surface.Comment: 23 page

Spectral Theory of Infinite Quantum Graphs

We investigate quantum graphs with infinitely many vertices and edges without the common restriction on the geometry of the underlying metric graph that there is a positive lower bound on the lengths of its edges. Our central result is a close connection between spectral properties of a quantum graph and the corresponding properties of a certain weighted discrete Laplacian on the underlying discrete graph. Using this connection together with spectral theory of (unbounded) discrete Laplacians on infinite graphs, we prove a number of new results on spectral properties of quantum graphs. Namely, we prove several self-adjointness results including a Gaffney type theorem. We investigate the problem of lower semiboundedness, prove several spectral estimates (bounds for the bottom of spectra and essential spectra of quantum graphs, CLR-type estimates) and study spectral types.Comment: Dedicated to the memory of M. Z. Solomyak (16.05.1931 - 31.07.2016

Vector-valued optimal Lipschitz extensions

Consider a bounded open set $U$ in $R^n$ and a Lipschitz function g from the boundary of $U$ to $R^m$. Does this function always have a canonical optimal Lipschitz extension to all of $U$? We propose a notion of optimal Lipschitz extension and address existence and uniqueness in some special cases. In the case $n=m=2$, we show that smooth solutions have two phases: in one they are conformal and in the other they are variants of infinity harmonic functions called infinity harmonic fans. We also prove existence and uniqueness for the extension problem on finite graphs.Comment: 24 pages, 10 figure

A symmetrization result for a class of anisotropic elliptic problems

We prove estimates for weak solutions to a class of Dirichlet problems associated to anisotropic elliptic equations with a zero order term.Comment: arXiv admin note: text overlap with arXiv:1607.0721