16,694 research outputs found
Hybrid time-dependent Ginzburg-Landau simulations of block copolymer nanocomposites: nanoparticle anisotropy
Block copolymer melts are perfect candidates to template the position of colloidal nanoparticles in the nanoscale, on top of their well-known suitability for lithography applications. This is due to their ability to self-assemble into periodic ordered structures, in which nanoparticles can segregate depending on the polymer-particle interactions, size and shape. The resulting coassembled structure can be highly ordered as a combination of both the polymeric and colloidal properties. The time-dependent Ginzburg-Landau model for the block copolymer was combined with Brownian dynamics for nanoparticles, resulting in an efficient mesoscopic model to study the complex behaviour of block copolymer nanocomposites. This review covers recent developments of the time-dependent Ginzburg-Landau/Brownian dynamics scheme. This includes efforts to parallelise the numerical scheme and applications of the model. The validity of the model is studied by comparing simulation and experimental results for isotropic nanoparticles. Extensions to simulate nonspherical and inhomogeneous nanoparticles are discussed and simulation results are discussed. The time-dependent Ginzburg-Landau/Brownian dynamics scheme is shown to be a flexible method which can account for the relatively large system sizes required to study block copolymer nanocomposite systems, while being easily extensible to simulate nonspherical nanoparticles
Self-Ordering Point Clouds
In this paper we address the task of finding representative subsets of points
in a 3D point cloud by means of a point-wise ordering. Only a few works have
tried to address this challenging vision problem, all with the help of hard to
obtain point and cloud labels. Different from these works, we introduce the
task of point-wise ordering in 3D point clouds through self-supervision, which
we call self-ordering. We further contribute the first end-to-end trainable
network that learns a point-wise ordering in a self-supervised fashion. It
utilizes a novel differentiable point scoring-sorting strategy and it
constructs an hierarchical contrastive scheme to obtain self-supervision
signals. We extensively ablate the method and show its scalability and superior
performance even compared to supervised ordering methods on multiple datasets
and tasks including zero-shot ordering of point clouds from unseen categories
A direct-laser-written heart-on-a-chip platform for generation and stimulation of engineered heart tissues
In this dissertation, we first develop a versatile microfluidic heart-on-a-chip model to generate 3D-engineered human cardiac microtissues in highly-controlled microenvironments. The platform, which is enabled by direct laser writing (DLW), has tailor-made attachment sites for cardiac microtissues and comes with integrated strain actuators and force sensors. Application of external pressure waves to the platform results in controllable time-dependent forces on the microtissues. Conversely, oscillatory forces generated by the microtissues are transduced into measurable electrical outputs. After characterization of the responsivity of the transducers, we demonstrate the capabilities of this platform by studying the response of cardiac microtissues to prescribed mechanical loading and pacing.
Next, we tune the geometry and mechanical properties of the platform to enable parametric studies on engineered heart tissues. We explore two geometries: a rectangular seeding well with two attachment sites, and a stadium-like seeding well with six attachment sites. The attachment sites are placed symmetrically in the longitudinal direction. The former geometry promotes uniaxial contraction of the tissues; the latter additionally induces diagonal
fiber alignment. We systematically increase the length for both configurations and observe a positive correlation between fiber alignment at the center of the microtissues and tissue length. However, progressive thinning and âneckingâ is also observed, leading to the failure of longer tissues over time. We use the DLW technique to improve the platform, softening
the mechanical environment and optimizing the attachment sites for generation of stable microtissues at each length and geometry. Furthermore, electrical pacing is incorporated into the platform to evaluate the functional dynamics of stable microtissues over the entire range of physiological heart rates. Here, we typically observe a decrease in active force and contraction duration as a function of frequency.
Lastly, we use a more traditional ?TUG platform to demonstrate the effects of subthreshold electrical pacing on the rhythm of the spontaneously contracting cardiac microtissues. Here, we observe periodic M:N patterns, in which there are ? cycles of stimulation for every ? tissue contractions. Using electric field amplitude, pacing frequency, and homeostatic beating frequencies of the tissues, we provide an empirical map for predicting the emergence of these rhythms
Donor-anion interactions in quarter-filled low-dimensional organic conductors
Anions have often been considered to act essentially as electron donors or acceptors in molecular conductors. However there is now growing evidence that they play an essential role in directing the structural and hence electronic properties of many of these systems. After reviewing the basic interactions and different ground states occurring in molecular conductors we consider in detail how anions influence the structure of donor stacks and often guide them toward different types of transitions. Consideration of the Bechgaard and Fabre salts illustrates how anions play a crucial role in directing these salts through complex phase diagrams where different conducting and localized states are in competition. We also emphasize the important role of hydrogen bonding and conformational flexibility of donors related to BEDT-TTF and we discuss how anions have frequently a strong control of the electronic landscape of these materials. Charge ordering, metal to metal and metal to insulator transitions occurring in these salts are considered
Behavior of branched buried MDPE gas distribution pipes under relative axial ground movements
The performance of medium density polyethylene (MDPE) gas distribution pipes subjected to relative ground movements has been a significant concern to the utility owners and companies. The tee-joints (tapping tee) and the lateral branches, common in gas distribution piping systems, may increase the effects of ground movement caused by various geohazards such as landslides, earthquakes etc. Most ground movement scenarios depict leak/stress concentration near the tapping tee of the branched pipe system. However, limited studies are currently available in the literature on the soil-pipe interaction of branched pipes during ground movement. Thus, the complex interactions of the pipe, the tee-junction, and the branch with surrounding soil are not well-understood. This thesis presents an experimental investigation of different configurations of 42.2-mm and 60.3-mm diameter branched buried MDPE pipes under relative axial ground movement. Tests with different positions of the tee-joint with respect to the pulling end of the pipe and varying densities of sand are conducted using the laboratory facility at Memorial University of Newfoundland. Pipe wall strains and soil pressures around the pipes are measured during the tests to capture the mechanism of soil-pipe interaction. Subsequently, an additional test is done with the tapping tee only (without the branch pipe) to identify the contribution of the branch pipe to soil resistance and pipe wall strain. The study explores the contribution of the trunk pipe, the tapping tee, and the branch pipe separately on the axial pulling force. Test results reveal the possibility of localized strain occurring on the trunk pipe near the tee. The anchoring effects of the tee and the branch significantly affect the soil resistance and the strain distribution on the trunk pipes
Annals [...].
Pedometrics: innovation in tropics; Legacy data: how turn it useful?; Advances in soil sensing; Pedometric guidelines to systematic soil surveys.Evento online. Coordenado por: Waldir de Carvalho Junior, Helena Saraiva Koenow Pinheiro, Ricardo SimĂŁo Diniz Dalmolin
Flexible pressure sensors via engineering microstructures for wearable human-machine interaction and health monitoring applications
Flexible pressure sensors capable of transducing pressure stimuli into electrical signals have drawn extensive attention owing to their potential applications for human-machine interaction and healthcare monitoring. To meet these application demands, engineering microstructures in the pressure sensors are an efficient way to improve key sensing performances, such as sensitivity, linear sensing range, response time, hysteresis, and durability. In this review, we provide an overview of the recent advances in the fabrication and application of high-performance flexible pressure sensors via engineering microstructures. The implementation mechanisms and fabrication strategies of microstructures including micropatterned, porous, fiber-network, and multiple microstructures are systematically presented. The applications of flexible pressure sensors with microstructures in the fields of wearable human-machine interaction, and ex vivo and in vivo healthcare monitoring are comprehensively discussed. Finally, the outlook and challenges in the future improvement of flexible pressure sensors toward practical applications are presented
Search for third generation vector-like leptons with the ATLAS detector
The Standard Model of particle physics provides a concise description of the building blocks of our universe in terms of fundamental particles and their interactions. It is an extremely successful theory, providing a plethora of predictions that precisely match experimental observation. In 2012, the Higgs boson was observed at CERN and was the last particle predicted by the Standard Model that had yet-to-be discovered. While this added further credibility to the theory, the Standard Model appears incomplete. Notably, it only accounts for 5% of the energy density of the universe (the rest being ``dark matter'' and ``dark energy''), it cannot resolve the gravitational force with quantum theory, it does not explain the origin of neutrino masses and cannot account for matter/anti-matter asymmetry. The most plausible explanation is that the theory is an approximation and new physics remains.
Vector-like leptons are well-motivated by a number of theories that seek to provide closure on the Standard Model. They are a simple addition to the Standard Model and can help to resolve a number of discrepancies without disturbing precisely measured observables. This thesis presents a search for vector-like leptons that preferentially couple to tau leptons. The search was performed using proton-proton collision data from the Large Hadron Collider collected by the ATLAS experiment from 2015 to 2018 at center-of-mass energy of 13 TeV, corresponding to an integrated luminosity of 139 inverse femtobarns. Final states of various lepton multiplicities were considered to isolate the vector-like lepton signal against Standard Model and instrumental background. The major backgrounds mimicking the signal are from WZ, ZZ, tt+Z production and from mis-identified leptons. A number of boosted decision trees were used to improve rejection power against background where the signal was measured using a binned-likelihood estimator. No excess relative to the Standard Model was observed. Exclusion limits were placed on vector-like leptons in the mass range of 130 to 898 GeV
FiabilitĂ© de lâunderfill et estimation de la durĂ©e de vie dâassemblages microĂ©lectroniques
Abstract : In order to protect the interconnections in flip-chip packages, an underfill material layer
is used to fill the volumes and provide mechanical support between the silicon chip and
the substrate. Due to the chip corner geometry and the mismatch of coefficient of thermal
expansion (CTE), the underfill suffers from a stress concentration at the chip corners when
the temperature is lower than the curing temperature. This stress concentration leads
to subsequent mechanical failures in flip-chip packages, such as chip-underfill interfacial
delamination and underfill cracking. Local stresses and strains are the most important
parameters for understanding the mechanism of underfill failures. As a result, the industry
currently relies on the finite element method (FEM) to calculate the stress components, but
the FEM may not be accurate enough compared to the actual stresses in underfill. FEM
simulations require a careful consideration of important geometrical details and material
properties. This thesis proposes a modeling approach that can accurately estimate the underfill delamination
areas and crack trajectories, with the following three objectives. The first
objective was to develop an experimental technique capable of measuring underfill deformations
around the chip corner region. This technique combined confocal microscopy and
the digital image correlation (DIC) method to enable tri-dimensional strain measurements
at different temperatures, and was named the confocal-DIC technique. This techique was
first validated by a theoretical analysis on thermal strains. In a test component similar
to a flip-chip package, the strain distribution obtained by the FEM model was in good
agreement with the results measured by the confocal-DIC technique, with relative errors
less than 20% at chip corners. Then, the second objective was to measure the strain near
a crack in underfills. Artificial cracks with lengths of 160 ÎŒm and 640 ÎŒm were fabricated
from the chip corner along the 45° diagonal direction. The confocal-DIC-measured
maximum hoop strains and first principal strains were located at the crack front area for
both the 160 ÎŒm and 640 ÎŒm cracks. A crack model was developed using the extended
finite element method (XFEM), and the strain distribution in the simulation had the same
trend as the experimental results. The distribution of hoop strains were in good agreement
with the measured values, when the model element size was smaller than 22 ÎŒm to
capture the strong strain gradient near the crack tip. The third objective was to propose
a modeling approach for underfill delamination and cracking with the effects of manufacturing
variables. A deep thermal cycling test was performed on 13 test cells to obtain the
reference chip-underfill delamination areas and crack profiles. An artificial neural network
(ANN) was trained to relate the effects of manufacturing variables and the number of
cycles to first delamination of each cell. The predicted numbers of cycles for all 6 cells in
the test dataset were located in the intervals of experimental observations. The growth
of delamination was carried out on FEM by evaluating the strain energy amplitude at
the interface elements between the chip and underfill. For 5 out of 6 cells in validation,
the delamination growth model was consistent with the experimental observations. The
cracks in bulk underfill were modelled by XFEM without predefined paths. The directions of edge cracks were in good agreement with the experimental observations, with an error
of less than 2.5°. This approach met the goal of the thesis of estimating the underfill
initial delamination, areas of delamination and crack paths in actual industrial flip-chip
assemblies.Afin de protĂ©ger les interconnexions dans les assemblages, une couche de matĂ©riau dâunderfill est utilisĂ©e pour remplir le volume et fournir un support mĂ©canique entre la puce de silicium et le substrat. En raison de la gĂ©omĂ©trie du coin de puce et de lâĂ©cart du coefficient de dilatation thermique (CTE), lâunderfill souffre dâune concentration de contraintes dans les coins lorsque la tempĂ©rature est infĂ©rieure Ă la tempĂ©rature de cuisson. Cette concentration de contraintes conduit Ă des dĂ©faillances mĂ©caniques dans les encapsulations de flip-chip, telles que la dĂ©lamination interfaciale puce-underfill et la fissuration dâunderfill. Les contraintes et dĂ©formations locales sont les paramĂštres les plus importants pour comprendre le mĂ©canisme des ruptures de lâunderfill. En consĂ©quent, lâindustrie utilise actuellement la mĂ©thode des Ă©lĂ©ments finis (EF) pour calculer les composantes de la contrainte, qui ne sont pas assez prĂ©cises par rapport aux contraintes actuelles dans lâunderfill. Ces simulations nĂ©cessitent un examen minutieux de dĂ©tails gĂ©omĂ©triques importants et des propriĂ©tĂ©s des matĂ©riaux. Cette thĂšse vise Ă proposer une approche de modĂ©lisation permettant dâestimer avec prĂ©cision les zones de dĂ©lamination et les trajectoires des fissures dans lâunderfill, avec les trois objectifs suivants. Le premier objectif est de mettre au point une technique expĂ©rimentale capable de mesurer la dĂ©formation de lâunderfill dans la rĂ©gion du coin de puce. Cette technique, combine la microscopie confocale et la mĂ©thode de corrĂ©lation des images numĂ©riques (DIC) pour permettre des mesures tridimensionnelles des dĂ©formations Ă diffĂ©rentes tempĂ©ratures, et a Ă©tĂ© nommĂ©e le technique confocale-DIC. Cette technique a dâabord Ă©tĂ© validĂ©e par une analyse thĂ©orique en dĂ©formation thermique. Dans un Ă©chantillon similaire Ă un flip-chip, la distribution de la dĂ©formation obtenues par le modĂšle EF Ă©tait en bon accord avec les rĂ©sultats de la technique confocal-DIC, avec des erreurs relatives infĂ©rieures Ă 20% au coin de puce. Ensuite, le second objectif est de mesurer la dĂ©formation autour dâune fissure dans lâunderfill. Des fissures artificielles dâune longueuer de 160 ÎŒm et 640 ÎŒm ont Ă©tĂ© fabriquĂ©es dans lâunderfill vers la direction diagonale de 45°. Les dĂ©formations circonfĂ©rentielles maximales et principale maximale Ă©taient situĂ©es aux pointes des fissures correspondantes. Un modĂšle de fissure a Ă©tĂ© dĂ©veloppĂ© en utilisant la mĂ©thode des Ă©lĂ©ments finis Ă©tendue (XFEM), et la distribution des contraintes dans la simuation a montrĂ© la mĂȘme tendance que les rĂ©sultats expĂ©rimentaux. La distribution des dĂ©formations circonfĂ©rentielles maximales Ă©tait en bon accord avec les valeurs mesurĂ©es lorsque la taille des Ă©lĂ©ments Ă©tait plus petite que 22 ÎŒm, assez petit pour capturer le grand gradient de dĂ©formation prĂšs de la pointe de fissure. Le troisiĂšme objectif Ă©tait dâapporter une approche de modĂ©lisation de la dĂ©lamination et de la fissuration de lâunderfill avec les effets des variables de fabrication. Un test de cyclage thermique a dâabord Ă©tĂ© effectuĂ© sur 13 cellules pour obtenir les zones dĂ©laminĂ©es entre la puce et lâunderfill, et les profils de fissures dans lâunderfill, comme rĂ©fĂ©rence. Un rĂ©seau neuronal artificiel (ANN) a Ă©tĂ© formĂ© pour Ă©tablir une liaison entre les effets des variables de fabrication et le nombre de cycles Ă la dĂ©lamination pour chaque cellule. Les nombres de cycles prĂ©dits pour les 6 cellules de lâensemble de test Ă©taient situĂ©s dans les intervalles dâobservations expĂ©rimentaux. La croissance de la dĂ©lamination a Ă©tĂ© rĂ©alisĂ©e par lâEF en Ă©valuant lâĂ©nergie de la dĂ©formation au niveau des Ă©lĂ©ments interfaciaux entre la puce et lâunderfill. Pour 5 des 6 cellules de la validation, le modĂšle de croissance du dĂ©laminage Ă©tait conforme aux observations expĂ©rimentales. Les fissures dans lâunderfill ont Ă©tĂ© modĂ©lisĂ©es par XFEM sans chemins prĂ©dĂ©finis. Les directions des fissures de bord Ă©taient en bon accord avec les observations expĂ©rimentales, avec une erreur infĂ©rieure Ă 2,5°. Cette approche a rĂ©pondu Ă la problĂ©matique qui consiste Ă estimer lâinitiation des dĂ©lamination, les zones de dĂ©lamination et les trajectoires de fissures dans lâunderfill pour des flip-chips industriels
Structure and adsorption properties of gas-ionic liquid interfaces
Supported ionic liquids are a diverse class of materials that have been considered
as a promising approach to design new surface properties within solids for gas
adsorption and separation applications. In these materials, the surface morphology and
composition of a porous solid are modified by depositing ionic liquid. The resulting
materials exhibit a unique combination of structural and gas adsorption properties
arising from both components, the support, and the liquid. Naturally, theoretical and
experimental studies devoted to understanding the underlying principles of exhibited
interfacial properties have been an intense area of research. However, a complete
understanding of the interplay between interfacial gas-liquid and liquid-solid
interactions as well as molecular details of these processes remains elusive.
The proposed problem is challenging and in this thesis, it is approached from
two different perspectives applying computational and experimental techniques. In
particular, molecular dynamics simulations are used to model gas adsorption in films
of ionic liquids on a molecular level. A detailed description of the modeled systems is
possible if the interfacial and bulk properties of ionic liquid films are separated. In this
study, we use a unique method that recognizes the interfacial and bulk structures of
ionic liquids and distinguishes gas adsorption from gas solubility. By combining
classical nitrogen sorption experiments with a mean-field theory, we study how liquid-solid interactions influence the adsorption of ionic liquids on the surface of the porous
support.
The developed approach was applied to a range of ionic liquids that feature
different interaction behavior with gas and porous support. Using molecular
simulations with interfacial analysis, it was discovered that gas adsorption capacity
can be directly related to gas solubility data, allowing the development of a predictive
model for the gas adsorption performance of ionic liquid films. Furthermore, it was
found that this CO2 adsorption on the surface of ionic liquid films is determined by the
specific arrangement of cations and anions on the surface. A particularly important
result is that, for the first time, a quantitative relation between these structural and
adsorption properties of different ionic liquid films has been established. This link
between two types of properties determines design principles for supported ionic
liquids.
However, the proposed predictive model and design principles rely on the
assumption that the ionic liquid is uniformly distributed on the surface of the porous
support. To test how ionic liquids behave under confinement, nitrogen physisorption
experiments were conducted for microâ and mesopore analysis of supported ionic
liquid materials. In conjunction with mean-field density functional theory applied to
the lattice gas and pore models, we revealed different scenarios for the pore-filling
mechanism depending on the strength of the liquid-solid interactions.
In this thesis, a combination of computational and experimental studies provides
a framework for the characterization of complex interfacial gas-liquid and liquid-solid
processes. It is shown that interfacial analysis is a powerful tool for studying
molecular-level interactions between different phases. Finally, nitrogen sorption
experiments were effectively used to obtain information on the structure of supported
ionic liquids
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