Electrical characterization of the soft breakdown failure mode in MgO layers

The soft breakdown (SBD) failure mode in 20 nm thick MgO dielectric layers grown on Si substrates was investigated. We show that during a constant voltage stress, charge trapping and progressive breakdown coexist, and that the degradation dynamics is captured by a power-law time dependence. We also show that the SBD current-voltage (I-V) characteristics follow the power-law model I = aVb typical of this conduction mechanism but in a wider voltage window than the one reported in the past for SiO2. The relationship between the magnitude of the current and the normalized differential conductance was analyzed

Nanowire Transistors and RF Circuits for Low-Power Applications

The background of this thesis is related to the steadily increasing demand of higher bandwidth and lower power consumption for transmitting data. The work aims at demonstrating how new types of structures, at the nanoscale, combined with what is referred to as exotic materials, can help benefit in electronics by lowering the consumed power, possibly by an order of magnitude, compared to the industry standard, silicon (Si), used today. Nanowires are semiconductor rods, with two dimensions at the nanoscale, which can be either grown with a bottom-up technique, or etched out with a top-down approach. The research interest concerning nanowires has gradually increasing for over two decades. Today, few have doubts that nanowires represent an attractive alternative, as scaling of planar structures has reached fundamental limits. With the enhanced electrostatics of a surrounding gate, nanowires offer the possibility of continued miniaturization, giving semiconductors a prolonged window of performance improvements. As a material choice, compound semiconductors with elements from group III and V (III-Vs), such as indium arsenide (InAs), have the possibility to dramatically decrease power consumption. The reason is the inherent electron transport properties of III-Vs, where an electron can travel, in the order of, 10 times faster than in Si. In the projected future, inclusion of III-Vs, as an extension to the Si-CMOS platform, seems almost inevitable, with many of the largest electronics manufacturing companies showing great interest. To investigate the technology potential, we have fabricated InAs nanowire metal-oxide-semiconductor field effect transistors (NW-FETs). The performance has been evaluated measuring both RF and DC characteristics. The best devices show a transconductance of 1.36 mS/µm (a device with a single nanowire, normalized to the nanowire circumference) and a maximum unilateral power gain at 57 GHz (for a device with several parallel nanowires), both values at a drive voltage of 0.5 V. The performance metrics are found to be limited by the capacitive load of the contact pads as well as the resistance in the non-gated segments of the nanowires. Using computer models, we have also been able to extract intrinsic transport properties, quantifying the velocity of charge carrier injection, which is the limiting property of semi-ballistic and ballistic devices. The value for our 45-nm-in-diameter nanowires, with 200 nm channel length, is determined to 1.7∙107 cm/s, comparable to other state-of-the-art devices at the same channel length. To demonstrate a higher level of functionality, we have connected several NW-FETs in a circuit. The fabricated circuit is a single balanced differential direct conversion mixer and is composed of three stages; transconductance, mixing, and transimpedance. The basic idea of the mixer circuit is that an information signal can either be extracted from or inserted into a carrier wave at a higher frequency than the information wave itself. It is the relative size of the first and the third stage that accounts for the circuit conversion gain. Measured circuits show a voltage conversion gain of 6 dB and a 3-dB bandwidth of 2 GHz. A conversion mixer is a vital component when building a transceiver, like those found in a cellphone and any other type of radio signal transmitting device. For all types of signals, noise imposes a fundamental limitation on the minimal, distinguishable amplitude. As transistors are scaled down, fewer carriers are involved in charge transport, and the impact of frequency dependent low-frequency noise gets relatively larger. Aiming towards low power applications, it is thus of importance to minimize the amount of transistor generated noise. Included in the thesis are studies of the level and origin of low-frequency 1/f-noise generated in NW-FETs. The measured noise spectral density is comparable to other non-planar devices, including those fabricated in Si. The data suggest that the level of generated noise can be substantially lowered by improving the high-k dielectric film quality and the channel interface. One significant discovery is that the part of the noise originating from the bulk nanowire, identified as mobility fluctuations, is comparably much lower than the measured noise level related to the nanowire surface. This result is promising as mobility fluctuations set the lower limit of what is achievable within a material system

Probing Electronic and Thermoelectric Properties of Single Molecule Junctions

In an effort to further understand electronic and thermoelectric phenomenon at the nanometer scale, we have studied the transport properties of single molecule junctions. To carry out these transport measurements, we use the scanning tunneling microscope-break junction (STM-BJ) technique, which involves the repeated formation and breakage of a metal point contact in an environment of the target molecule. Using this technique, we are able to create gaps that can trap the molecules, allowing us to sequentially and reproducibly create a large number of junctions. By applying a small bias across the junction, we can measure its conductance and learn about the transport mechanisms at the nanoscale. The experimental work presented here directly probes the transmission properties of single molecules through the systematic measurement of junction conductance (at low and high bias) and thermopower. We present measurements on a variety of molecular families and study how conductance depends on the character of the linkage (metal-molecule bond) and the nature of the molecular backbone. We start by describing a novel way to construct single molecule junctions by covalently connecting the molecular backbone to the electrodes. This eliminates the use of linking substituents, and as a result, the junction conductance increases substantially. Then, we compare transport across silicon chains (silanes) and saturated carbon chains (alkanes) while keeping the linkers the same and find a stark difference in their electronic transport properties. We extend our studies of molecular junctions by looking at two additional aspects of quantum transport - molecular thermopower and molecular current-voltage characteristics. Each of these additional parameters gives us further insight into transport properties at the nanoscale. Evaluating the junction thermopower allows us to determine the nature of charge carriers in the system and we demonstrate this by contrasting the measurement of amine-terminated and pyridine-terminated molecules (which exhibit hole transport and electron transport, respectively). We also report the thermopower of the highly conducting, covalently bound molecular junctions that we have recently been able to form, and learn that, because of their unique transport properties, the junction power factors, GS2, are extremely high. Finally, we discuss the measurement of molecular current-voltage curves and consider the electronic and physical effects of applying a large bias to the system. We conclude with a summary of the work discussed and an outlook on related scientific studies

Crystal growth of device quality GaAs in space

The apparatus and techniques used in effort to determine the relationships between crystal growth and electronic properties are described with emphasis on electroepitaxy and melt-grown gallium aresenide crystal. Applications of deep level transient spectroscopy, derivative photocapitance spectroscopy, and SEM-cathodoluminescene in characterizing wide bandgap semiconductors; determining photoionization in MOS, Schottky barriers, and p-n junctions; and for identifying inhomogeneities are examined, as well as the compensation of indium phosphide