CFD and neuro-fuzzy modelling of fuel cells

This thesis presents some model developments for the simulation and optimization of the design of fuel cells, in particular for the Solid Oxide Fuel Cell (SOFC) and Proton Exchange Membrane Fuel Cell (PEMFC). However, the approaches and models presented can be basically applied to any type of fuel cell. In this study, the multicomponent diffusion processes in the porous medium of a SOFC anode has been investigated through comparison of the Stefan Maxwell Model, Dusty Gas Model and Binary Friction Model in terms of their prediction performance of the concentration polarization of a SOFC anode to mainly investigate the effect of the Knudsen diffusion on the predictions. The model equations are first solved in 1 D using an in-house code developed in MATLAB. Then the diffusion models have been implemented into COMSOL to obtain 2D and 3D solutions. The model predictions have been evaluated for different parameters and operating condi- tions for an isothermal system and assuming that reaction kinetics are not rate limiting. The results show that the predictions of the models are similar and the differences in the predictions of the models reported previously are mainly due to the definition of the effective diffusion coefficient, i.e. the tortuosity parame- ter, and with a tortuosity parameter fitted for each model, the models that take into account the Knudsen diffusion and that do not predict similar concentration polarization. Moreover, in this research, the application of an Adaptive Neuro- Fuzzy Inference System (ANFIS) to predict the performance of an Intermediate Temperature Solid Oxide Fuel Cell and a Proton Exchange Membrane Fuel Cell (PEMFC) have been presented. The results show that a well trained and tested ANFIS model can be used as a viable tool to predict the performance of the fuel cell under different operational conditions to facilitate the understanding of the combined effect of various operational conditions on the performance of the fuel cell and this can assist in reducing the experimentation and associated costs

Proton exchange membrane fuel cell degradation prediction based on Adaptive Neuro-Fuzzy Inference Systems .

International audienceThis paper studies the prediction of the output voltage reduction caused by degradation during nominal operating condition of a PEM fuel cell stack. It proposes a methodology based on Adaptive Neuro-Fuzzy Inference Systems (ANFIS) which use as input the measures of the fuel cell output voltage during operation. The paper presents the architecture of the ANFIS and studies the selection of its parameters. As the output voltage cannot be represented as a periodical signal, the paper proposes to predict its temporal variation which is then used to construct the prediction of the output voltage. The paper also proposes to split this signal in two components: normal operation and external perturbations. The second component cannot be predicted and then it is not used to train the ANFIS. The performance of the prediction is evaluated on the output voltage of two fuel cells during a long term operation (1000 hours). Validation results suggest that the proposed technique is well adapted to predict degradation in fuel cell systems

Performance prediction of proton exchange membrane fuel cells (PEMFC) using adaptive neuro inference system (ANFIS)

This investigation explored the performance of PEMFC for varying ambient conditions with the aid of an adaptive neuro-fuzzy inference system. The experimental data obtained from the laboratory were initially trained using both the input and output parameters. The model that was trained was then evaluated using an independent variable. The training and testing of the model were then utilized in the prediction of the cell-characteristic performance. The model exhibited a perfect correlation between the predicted and experimental data, and this stipulates that ANFIS can predict characteristic behavior of fuel cell performance with very high accuracy

An intelligent power management system for unmanned earial vehicle propulsion applications

Electric powered Unmanned Aerial Vehicles (UAVs) have emerged as a promi- nent aviation concept due to the advantageous such as stealth operation and zero emission. In addition, fuel cell powered electric UAVs are more attrac- tive as a result of the long endurance capability of the propulsion system. This dissertation investigates novel power management architecture for fuel cell and battery powered unmanned aerial vehicle propulsion application. The research work focused on the development of a power management system to control the hybrid electric propulsion system whilst optimizing the fuel cell air supplying system performances. The multiple power sources hybridization is a control challenge associated with the power management decisions and their implementation in the power electronic interface. In most applications, the propulsion power distribu- tion is controlled by using the regulated power converting devices such as unidirectional and bidirectional converters. The amount of power shared with the each power source is depended on the power and energy capacities of the device. In this research, a power management system is developed for polymer exchange membrane fuel cell and Lithium-Ion battery based hybrid electric propulsion system for an UAV propulsion application. Ini- tially, the UAV propulsion power requirements during the take-off, climb, endurance, cruising and maximum velocity are determined. A power man- agement algorithm is developed based on the UAV propulsion power re- quirement and the battery power capacity. Three power states are intro- duced in the power management system called Start-up power state, High power state and Charging power state. The each power state consists of the power management sequences to distribute the load power between the battery and the fuel cell system. A power electronic interface is developed Electric powered Unmanned Aerial Vehicles (UAVs) have emerged as a promi- nent aviation concept due to the advantageous such as stealth operation and zero emission. In addition, fuel cell powered electric UAVs are more attrac- tive as a result of the long endurance capability of the propulsion system. This dissertation investigates novel power management architecture for fuel cell and battery powered unmanned aerial vehicle propulsion application. The research work focused on the development of a power management system to control the hybrid electric propulsion system whilst optimizing the fuel cell air supplying system performances. The multiple power sources hybridization is a control challenge associated with the power management decisions and their implementation in the power electronic interface. In most applications, the propulsion power distribu- tion is controlled by using the regulated power converting devices such as unidirectional and bidirectional converters. The amount of power shared with the each power source is depended on the power and energy capacities of the device. In this research, a power management system is developed for polymer exchange membrane fuel cell and Lithium-Ion battery based hybrid electric propulsion system for an UAV propulsion application. Ini- tially, the UAV propulsion power requirements during the take-off, climb, endurance, cruising and maximum velocity are determined. A power man- agement algorithm is developed based on the UAV propulsion power re- quirement and the battery power capacity. Three power states are intro- duced in the power management system called Start-up power state, High power state and Charging power state. The each power state consists of the power management sequences to distribute the load power between the battery and the fuel cell system. A power electronic interface is developed with a unidirectional converter and a bidirectional converter to integrate the fuel cell system and the battery into the propulsion motor drive. The main objective of the power management system is to obtain the controlled fuel cell current profile as a performance variable. The relationship between the fuel cell current and the fuel cell air supplying system compressor power is investigated and a referenced model is developed to obtain the optimum compressor power as a function of the fuel cell current. An adaptive controller is introduced to optimize the fuel cell air supplying system performances based on the referenced model. The adaptive neuro-fuzzy inference system based controller dynamically adapts the actual compressor operating power into the optimum value defined in the reference model. The online learning and training capabilities of the adaptive controller identify the nonlinear variations of the fuel cell current and generate a control signal for the compressor motor voltage to optimize the fuel cell air supplying system performances. The hybrid electric power system and the power management system were developed in real time environment and practical tests were conducted to validate the simulation results

Development of solid oxide fuel cell stack models for monitoring, diagnosis and control applications

2011 - 2012In the present thesis different SOFC stack models have been presented. The results shown were obtained in the general framework of the GENIUS project (GEneric diagNosis Instrument for SOFC systems), funded by the European Union (grant agreement n° 245128). The objective of the project is to develop “generic” diagnostic tools and methodologies for SOFC systems. The “generic” term refers to the flexibility of diagnosis tools to be adapted to different SOFC systems. In order to achieve the target of the project and to develop stack models suitable for monitoring, control and diagnosis applications for SOFC systems, different modeling approaches have been proposed. Particular attention was given to their implementability into computational tools for on-board use. In this thesis one-dimensional (1-D), grey-box and blackbox stack models, both stationary and dynamic were developed. The models were validated with experimental data provided by European partners in the frame of the GENIUS project. A 1-D stationary model of a planar SOFC in co-flow and counter-flow configurations was presented. The model was developed starting from a 1- D model proposed by the University of Salerno for co-flow configuration (Sorrentino, 2006). The model was cross-validated with similar models developed by the University of Genoa and by the institute VTT. The crossvalidation results underlined the suitability of the 1-D model developed. A possible application of the 1-D model for the estimation of stack degradation was presented. The results confirmed the possibility to implement such a model for fault detection. A lumped gray-box model for the simulation of TOPSOE stack thermal dynamics was developed for the SOFC stack of TOPSOE, whose experimental data were made available in the frame of the GENIUS project. Particular attention was given to the problem of heat flows between stack and surrounding and a dedicated model was proposed. The black-box approach followed for the implementation of the heat flows and its reliability and accuracy was shown to be satisfactory for the purpose of its applications. The procedure adopted turned out to be fast and applicable to other SOFC stacks with different geometries and materials. The good results obtained and the limited calculation time make this model suitable for implementation in diagnostic tools. Another field of application is that of virtual sensors for stack temperature control. Black-box models for SOFC stack were also developed. In particular, a stationary Neural Network for the simulation of the HEXIS stack voltage was developed. The analyzed system was a 5-cells stack operated up to 10 thousand hours at constant load. The neural network exhibited very good prediction accuracy, even for systems with different technology from the one used for training the model. Beyond showing excellent prediction capabilities, the NN ensured high accuracy in well reproducing evolution of degradation in SOFC stacks, especially thanks to the inclusion of time among model inputs. Moreover, a Recurrent Neural Network for dynamic simulation of TOPSOE stack voltage and a similar one for a short stack built by HTc and tested by VTT were developed. The stacks analyzed were: a planar co-flow SOFC stack (TOPSOE) and a planar counter-flow SOFC stack (VTT-HTc). All models developed in this thesis have shown high accuracy and computation times that allow them to be implemented into diagnostic and control tool both for off-line (1-D model and grey-box) and for on-line (NN and RNNs) applications. It is important noting that the models were developed with reference to stacks produced by different companies. This allowed the evaluation of different SOFC technologies, thus obtaining useful information in the models development. The information underlined the critical aspects of these systems with regard to the measurements and control of some system variables, giving indications for the stack models development. The proposed modeling approaches are good candidates to address emerging needs in fuel cell development and on-field deployment, such as the opportunity of developing versatile model-based tools capable to be generic enough for real-time control and diagnosis of different fuel cell systems typologies, technologies and power scales. [edited by author]XI n.s

Computing air demand using the Takagi–Sugeno model for dam outlets

An adaptive neuro-fuzzy inference system (ANFIS) was developed using the subtractive clustering technique to study the air demand in low-level outlet works. The ANFIS model was employed to calculate vent air discharge in different gate openings for an embankment dam. A hybrid learning algorithm obtained from combining back-propagation and least square estimate was adopted to identify linear and non-linear parameters in the ANFIS model. Empirical relationships based on the experimental information obtained from physical models were applied to 108 experimental data points to obtain more reliable evaluations. The feed-forward Levenberg-Marquardt neural network (LMNN) and multiple linear regression (MLR) models were also built using the same data to compare model performances with each other. The results indicated that the fuzzy rule-based model performed better than the LMNN and MLR models, in terms of the simulation performance criteria established, as the root mean square error, the Nash–Sutcliffe efficiency, the correlation coefficient and the Bias

Contribution au pronostic de durée de vie des systèmes piles à combustible PEMFC

This thesis work aims to provide solutions for the limited lifetime of Proton Exchange Membrane Fuel Cell Systems (PEM-FCS) based on two complementary disciplines:A first approach consists in increasing the lifetime of the PEM-FCS by designing and implementing a Prognostics & Health Management (PHM) architecture. The PEM-FCS are essentially multi-physical systems (electrical, fluid, electrochemical, thermal, mechanical, etc.) and multi-scale (time and space), thus its behaviors are hardly understandable. The nonlinear nature of phenomena, the reversibility or not of degradations and the interactions between components makes it quite difficult to have a failure modeling stage. Moreover, the lack of homogeneity (actual) in the manufacturing process makes it difficult for statistical characterization of their behavior. The deployment of a PHM solution would indeed anticipate and avoid failures, assess the state of health, estimate the Remaining Useful Lifetime (RUL) of the system and finally consider control actions (control and/or maintenance) to ensure operation continuity.A second approach proposes to use a passive hybridization of the PEMFC with Ultra Capacitors (UC) to operate the fuel cell closer to its optimum operating conditions and thereby minimize the impact of aging. The UC appear as an additional source to the PEMFC due to their high power density, their capacity to charge/discharge rapidly, their reversibility and their long life. If we take the example of fuel cell hybrid electrical vehicles, the association between a PEMFC and UC can be performed using a hybrid of active or passive type system. The overall behavior of the system depends on both, the choice of the architecture and the positioning of these elements in connection with the electric charge. Today, research in this area focuses mainly on energy management between the sources and embedded storage and the definition and optimization of a power electronic interface designated to adjust the flow of energy between them. However, the presence of power converters increases the source of faults and failures (failure of the switches of the power converter and the impact of high frequency current oscillations on the aging of the PEMFC), and also increases the energy losses of the entire system (even if the performance of the power converter is high, it nevertheless degrades the overall system).Les travaux de cette thèse visent à apporter des éléments de solutions au problème de la durée de vie des systèmes pile à combustible (FCS – Fuel Cell System) de type à « membrane échangeuse de protons » (PEM – Proton Exchange Membrane) et se décline sur deux champs disciplinaires complémentaires :Une première approche vise à augmenter la durée de vie de celle-ci par la conception et la mise en œuvre d'une architecture de pronostic et de gestion de l'état de santé (PHM – Prognostics & Health Management). Les PEM-FCS, de par leur technologie, sont par essence des systèmes multi-physiques (électriques, fluidiques, électrochimiques, thermiques, mécaniques, etc.) et multi-échelles (de temps et d'espace) dont les comportements sont difficilement appréhendables. La nature non linéaire des phénomènes, le caractère réversible ou non des dégradations, et les interactions entre composants rendent effectivement difficile une étape de modélisation des défaillances. De plus, le manque d'homogénéité (actuel) dans le processus de fabrication rend difficile la caractérisation statistique de leur comportement. Le déploiement d'une solution PHM permettrait en effet d'anticiper et d'éviter les défaillances, d'évaluer l'état de santé, d'estimer le temps de vie résiduel du système, et finalement, d'envisager des actions de maîtrise (contrôle et/ou maintenance) pour assurer la continuité de fonctionnement. Une deuxième approche propose d'avoir recours à une hybridation passive de la PEMFC avec des super-condensateurs (UC – Ultra Capacitor) de façon à faire fonctionner la pile au plus proche de ses conditions opératoires optimales et ainsi, à minimiser l'impact du vieillissement. Les UCs apparaissent comme une source complémentaire à la PEMFC en raison de leur forte densité de puissance, de leur capacité de charge/décharge rapide, de leur réversibilité et de leur grande durée de vie. Si l'on prend l'exemple des véhicules à pile à combustible, l'association entre une PEMFC et des UCs peut être réalisée en utilisant un système hybride de type actif ou passif. Le comportement global du système dépend à la fois du choix de l'architecture et du positionnement de ces éléments en lien avec la charge électrique. Aujourd'hui, les recherches dans ce domaine se focalisent essentiellement sur la gestion d'énergie entre les sources et stockeurs embarqués ; et sur la définition et l'optimisation d'une interface électronique de puissance destinée à conditionner le flux d'énergie entre eux. Cependant, la présence de convertisseurs statiques augmente les sources de défaillances et pannes (défaillance des interrupteurs du convertisseur statique lui-même, impact des oscillations de courant haute fréquence sur le vieillissement de la pile), et augmente également les pertes énergétiques du système complet (même si le rendement du convertisseur statique est élevé, il dégrade néanmoins le bilan global)

Advanced Modeling, Control, and Optimization Methods in Power Hybrid Systems - 2021

The climate changes that are becoming visible today are a challenge for the global research community. In this context, renewable energy sources, fuel cell systems and other energy generating sources must be optimally combined and connected to the grid system using advanced energy transaction methods. As this reprint presents the latest solutions in the implementation of fuel cell and renewable energy in mobile and stationary applications such as hybrid and microgrid power systems based on the Energy Internet, blockchain technology and smart contracts, we hope that they will be of interest to readers working in the related fields mentioned above

A review on prognostics and health monitoring of proton exchange membrane fuel cell

Fuel cell technology can be traced back to 1839 when British scientist Sir William Grove discovered that it was possible to generate electricity by the reaction between hydrogen and oxygen gases. However, fuel cell still cannot compete with internal combustion engines although they have many advantages including zero carbon emissions. Fossil fuels are cheaper and present very high volumetric energy densities compared with the hydrogen gas. Furthermore, hydrogen storage as a liquid is still a huge challenge. Another important disadvantage is the lifespan of the fuel cell because of their durability, reliability and maintainability. Prognostics is an emerging technology in sustainability of engineering systems through failure prevention, reliability assessment and remaining useful lifetime estimation. Prognostics and health monitoring can play a critical role in enhancing the durability, reliability and maintainability of the fuel cell system. This paper presents a review on the current state-of-the-art in prognostics and health monitoring of Proton Exchange Membrane Fuel Cell (PEMFC), aiming at identifying research and development opportunities in these fields. This paper also highlights the importance of incorporating prognostics and failure modes, mechanisms and effects analysis (FMMEA) in PEMFC to give them sustainable competitive advantage when compared with other non-clean energy solutions