Nonlinear diffusion problem with dynamical boundary value

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Nonlinear dynamical boundary-value problem of hydrogen thermal desorption

The nonlinear boundary-value problem for the diffusion equation, which models gas interaction with solids, is considered. The model includes diffusion and the sorption/desorption processes on the surface, which leads to dynamical nonlinear boundary conditions. The boundary-value problem is reduced to an integro-differential equation of a special kind; existence and uniqueness of the classical (differentiable) solution theorems are proved. The results of numerical experiments are presented

Stochastic FitzHugh-Nagumo equations on networks with impulsive noise

We consider a system of nonlinear partial differential equations with stochastic dynamical boundary conditions that arises in models of neurophysiology for the diffusion of electrical potentials through a finite network of neurons. Motivated by the discussion in the biological literature, we impose a general diffusion equation on each edge through a generalized version of the FitzHugh-Nagumo model, while the noise acting on the boundary is described by a generalized stochastic Kirchhoff law on the nodes. In the abstract framework of matrix operators theory, we rewrite this stochastic boundary value problem as a stochastic evolution equation in infinite dimensions with a power-type nonlinearity, driven by an additive L\'evy noise. We prove global well-posedness in the mild sense for such stochastic partial differential equation by monotonicity methods.Comment: 18 pages. Minor revisio

Nonlinear mobility continuity equations and generalized displacement convexity

We consider the geometry of the space of Borel measures endowed with a distance that is defined by generalizing the dynamical formulation of the Wasserstein distance to concave, nonlinear mobilities. We investigate the energy landscape of internal, potential, and interaction energies. For the internal energy, we give an explicit sufficient condition for geodesic convexity which generalizes the condition of McCann. We take an eulerian approach that does not require global information on the geodesics. As by-product, we obtain existence, stability, and contraction results for the semigroup obtained by solving the homogeneous Neumann boundary value problem for a nonlinear diffusion equation in a convex bounded domain. For the potential energy and the interaction energy, we present a non-rigorous argument indicating that they are not displacement semiconvex.Comment: 33 pages, 1 figur

Quantum Trajectories, State Diffusion and Time Asymmetric Eventum Mechanics

We show that the quantum stochastic unitary dynamics Langevin model for continuous in time measurements provides an exact formulation of the Heisenberg uncertainty error-disturbance principle. Moreover, as it was shown in the 80's, this Markov model induces all stochastic linear and non-linear equations of the phenomenological "quantum trajectories" such as quantum state diffusion and spontaneous localization by a simple quantum filtering method. Here we prove that the quantum Langevin equation is equivalent to a Dirac type boundary-value problem for the second-quantized input "offer waves from future" in one extra dimension, and to a reduction of the algebra of the consistent histories of past events to an Abelian subalgebra for the "trajectories of the output particles". This result supports the wave-particle duality in the form of the thesis of Eventum Mechanics that everything in the future is constituted by quantized waves, everything in the past by trajectories of the recorded particles. We demonstrate how this time arrow can be derived from the principle of quantum causality for nondemolition continuous in time measurements.Comment: 21 pages. See also relevant publications at http://www.maths.nott.ac.uk/personal/vpb/publications.htm

The Fermi-Pasta-Ulam problem: 50 years of progress

A brief review of the Fermi-Pasta-Ulam (FPU) paradox is given, together with its suggested resolutions and its relation to other physical problems. We focus on the ideas and concepts that have become the core of modern nonlinear mechanics, in their historical perspective. Starting from the first numerical results of FPU, both theoretical and numerical findings are discussed in close connection with the problems of ergodicity, integrability, chaos and stability of motion. New directions related to the Bose-Einstein condensation and quantum systems of interacting Bose-particles are also considered.Comment: 48 pages, no figures, corrected and accepted for publicatio

Pattern forming pulled fronts: bounds and universal convergence

We analyze the dynamics of pattern forming fronts which propagate into an unstable state, and whose dynamics is of the pulled type, so that their asymptotic speed is equal to the linear spreading speed v^*. We discuss a method that allows to derive bounds on the front velocity, and which hence can be used to prove for, among others, the Swift-Hohenberg equation, the Extended Fisher-Kolmogorov equation and the cubic Complex Ginzburg-Landau equation, that the dynamically relevant fronts are of the pulled type. In addition, we generalize the derivation of the universal power law convergence of the dynamics of uniformly translating pulled fronts to both coherent and incoherent pattern forming fronts. The analysis is based on a matching analysis of the dynamics in the leading edge of the front, to the behavior imposed by the nonlinear region behind it. Numerical simulations of fronts in the Swift-Hohenberg equation are in full accord with our analytical predictions.Comment: 27 pages, 9 figure

Strongly nonlinear dynamics of electrolytes in large ac voltages

We study the response of a model micro-electrochemical cell to a large ac voltage of frequency comparable to the inverse cell relaxation time. To bring out the basic physics, we consider the simplest possible model of a symmetric binary electrolyte confined between parallel-plate blocking electrodes, ignoring any transverse instability or fluid flow. We analyze the resulting one-dimensional problem by matched asymptotic expansions in the limit of thin double layers and extend previous work into the strongly nonlinear regime, which is characterized by two novel features - significant salt depletion in the electrolyte near the electrodes and, at very large voltage, the breakdown of the quasi-equilibrium structure of the double layers. The former leads to the prediction of "ac capacitive desalination", since there is a time-averaged transfer of salt from the bulk to the double layers, via oscillating diffusion layers. The latter is associated with transient diffusion limitation, which drives the formation and collapse of space-charge layers, even in the absence of any net Faradaic current through the cell. We also predict that steric effects of finite ion sizes (going beyond dilute solution theory) act to suppress the strongly nonlinear regime in the limit of concentrated electrolytes, ionic liquids and molten salts. Beyond the model problem, our reduced equations for thin double layers, based on uniformly valid matched asymptotic expansions, provide a useful mathematical framework to describe additional nonlinear responses to large ac voltages, such as Faradaic reactions, electro-osmotic instabilities, and induced-charge electrokinetic phenomena.Comment: 30 pages, 17 eps-figures, RevTe