Composite CDMA - A statistical mechanics analysis

Code Division Multiple Access (CDMA) in which the spreading code assignment to users contains a random element has recently become a cornerstone of CDMA research. The random element in the construction is particular attractive as it provides robustness and flexibility in utilising multi-access channels, whilst not making significant sacrifices in terms of transmission power. Random codes are generated from some ensemble, here we consider the possibility of combining two standard paradigms, sparsely and densely spread codes, in a single composite code ensemble. The composite code analysis includes a replica symmetric calculation of performance in the large system limit, and investigation of finite systems through a composite belief propagation algorithm. A variety of codes are examined with a focus on the high multi-access interference regime. In both the large size limit and finite systems we demonstrate scenarios in which the composite code has typical performance exceeding sparse and dense codes at equivalent signal to noise ratio.Comment: 23 pages, 11 figures, Sigma Phi 2008 conference submission - submitted to J.Stat.Mec

OFDM-IDMA for Uplink Transmission in Passive Optical Networks

In this paper, we propose the orthogonal frequency-division multiplexing-interleaved division multiplexing access (OFDM-IDMA) technique for passive optical networks (PONs). We evaluate the performance of such systems and compare it with the already proposed OFDM-Access (OFDMA) technique by means of the bit error rate versus received power for two different coding schemes and different number of iterations. Results show that OFDM-IDMA technique with an unequal power allocation distribution among the different optical network units (ONUs) offers similar performance to OFDMA when used with a simple convolutional code at an aggregated rate of 4 and 8 Gbits/s. Dynamic bandwidth allocation can be easily implemented with this technique. © 2011 IEEE.Sánchez Costa, C.; Ortega Tamarit, B.; Capmany Francoy, J. (2012). OFDM-IDMA for Uplink Transmission in Passive Optical Networks. IEEE Photonics Journal. 4(1):1-13. doi:10.1109/JPHOT.2011.2177450S1134

The use of electrochemical detectors for high pressure liquid chromatography

Imperial Users onl

NMR solution structure of DNA double helices with built-in polarity probes

Die Strukturen in Lösung dreier unterschiedlich modifizierter DNA Doppelstränge wurden mittels NMR Spektroskopie gelöst. Sie alle besitzen polare Sonden im Zentrum der Helix, welche sensitiv für die nähere Umgebung sind. Ihr Schmelzverhalten wurde mit Hilfe einer neuen Methode charakterisiert, welche komplette Absorptionsspektren in Kombination mit Singularwertzerlegung (SVD) nutzt. Letztere erlaubt die Analyse der Spektren als Ganzes, die notwendig ist um der Blauverschiebung des Sondensignals zu folgen, welche durch die zuvor genannte Sensitivität zur Umgebung verursacht wird. Auf diese Weise kann der Schmelzprozess des Duplex lokal und global beschrieben werden. Die erste Modifikation, 2-Hydroxy-7-Carboxyfluoren (HCF), wurde gegenüber einer abasischen Seite platziert, um sterische Spannungen zu vermeiden. Die NMR Spektroskopie deckte zwei gleichverteilte Konformationen auf, da die Rotation des HCF Chromophors nur durch die Stapelwechselwirkung innerhalb der Helix unterbunden wird. Der zweite Doppelstrang enthält ein über R-Glycerol gebundenes 6-Hydroxychinolinium (6HQ) gegenüber Cytosin. Der Einbau von 6HQ als Mononukleotid einer Glykolnukleinsäure (GNA) ist ein strukturelles Alleinstellungsmerkmal. Bisher sind nur Kristallstrukturen von vollständiger GNA bekannt, daher ist die Struktur in Lösung dieses Doppelstranges von generellem Interesse. Die geringe Größe von R-Glycerol stört das Rückgrat des 6HQ-Stranges, welche eine von der helikalen Achse abweichende Stapelachse für die drei zentralen Basen verursacht. Die letzte Modifikation ist ein künstliches Basenpaar bestehend aus 4-Aminophthalimid (4AP) und 2,4-Diaminopyrimidin (DAP). Anstatt der gewünschten drei Wasserstoffbrücken wurden zwei Strukturen, die entweder eine oder zwei Wasserstoffbrücken beinhalten, beobachtet, welche durch die Verbindung von 4AP zur 2’-Deoxyribofuranose erklärt werden können.The solution structures of three differently modified DNA double strands were solved by NMR spectroscopy. They all incorporate polarity probes in the center of the helix that are sensitive to the immediate environment. Their melting behavior was characterized by a new method that utilizes complete absorption spectra in combination with Singular Value Decomposition (SVD). The latter allows to analyze the spectra in their entirety, which is required to follow the blue shift of the probe signal that is caused by the aforementioned sensitivity to the environment. In this way the duplex melting process is characterized in local and global terms.The first modification, 2-hydroxy-7-carboxyfluorene (HCF), is placed opposite an abasic site to avoid steric strain. NMR spectroscopy revealed two equally distributed conformations, since rotation of the HCF chromophore is only hindered by stacking interactions inside the helix. The second double strand comprises R-glycerol linked 6-hydroxyquinolinium (6HQ) opposite cytosine. The incorporation of 6HQ as glycol nucleic acid (GNA) mononucleotide is a unique structural feature. Until now, only crystal structures of full GNA backbone duplexes are known, so the solution structure of this double strand is of general interest. The small size of R-glycerol disturbs the backbone of the 6HQ strand, which causes a stacking axis that differs from the helical long axis for the three central bases. The last modification is an artificial base pair made of 4-aminophthalimide (4AP) and 2,4-diaminopyrimidine (DAP). Instead of the desired three hydrogen bonds, two structures containing either a single or two hydrogen bonds are observed that can be explained by the linkage of 4AP to 2’-deoxyribofuranose

Terahertz wireless communication

The goal of this thesis is to explore Terahertz (THz) wireless communication technology. More specifically the objective is to develop and characterize several THz communication systems and study the effect of atmosphere propagation through fog droplets and dust particles on THz communications. For demonstration, a THz continuous wave (CW) photomixing system is designed. Terahertz signals are phase encoded with both analog ramp signals and pseudorandom binary data, transmitted over a short distance, and detected. The limitation of transmission bandwidth, low single to noise ratio, vibration effects are also analyzed. In order to study and compare propagation features of THz links with infrared (IR) links under different weather conditions, a THz and IR communications lab setup with a maximum data rate of 2.5 Gb/s at 625 GHz carrier frequency and 1.5 gm wavelength, have been developed respectively. A usual non return-to-zero (NRZ) format is applied to modulate the IR channel but a duobinary coding technique is used for driving the multiplier chain-based 625 GHz source, which enables signaling at high data rate and higher output power. The bit-error rate (BER), signal-to-noise ratio (SNR) and power on the receiver side have been measured, which describe the signal performance. Since weather conditions such as fog and dust exhibit a spectral dependence in the atmospheric attenuation, the corresponding impact on THz in comparison with IR communications is not equivalent. Simulation results of attenuation by fog and dust in the millimeter and sub-millimeter waveband (from 0.1 to 1 THz) and infrared waveband (1.5 µm) are presented and compared. Experimentally, after THz and IR beams propagated through the same weather conditions (fog), performance of both channels are analyzed and compared. The attenuation levels for the IR beam are typically several orders of magnitude higher than those for the THz beam. Mie scattering theory was used to study the attenuation of THz and IR radiation due to the dust particle. Different amounts of dust are loaded in the chamber to generate a variety of concentration for beam propagation. As the dust loading becomes heavier, the measured attenuation becomes more severe. Under identical dust concentrations, IR wavelengths are strongly attenuated while THz shows almost no impact