Micromachining of buried micro channels in silicon

A new method for the fabrication of micro structures for fluidic applications, such as channels, cavities, and connector holes in the bulk of silicon wafers, called buried channel technology (BCT), is presented in this paper. The micro structures are constructed by trench etching, coating of the sidewalls of the trench, removal of the coating at the bottom of the trench, and etching into the bulk of the silicon substrate. The structures can be sealed by deposition of a suitable layer that closes the trench. BCT is a process that can be used to fabricate complete micro channels in a single wafer with only one lithographic mask and processing on one side of the wafer, without the need for assembly and bonding. The process leaves a substrate surface with little topography, which easily allows further processing, such as the integration of electronic circuits or solid-state sensors. The essential features of the technology, as well as design rules and feasible process schemes, will be demonstrated on examples from the field of ¿-fluidic

Micro-tubular and micro-monolithic solid oxide fuel cells for energy and environment

Micro-tubular solid oxide fuel cells (MT-SOFCs) have interesting features and presents several advantages and competitiveness such as better thermal shock resistance, higher power density and portable characteristics. Further enhancement in terms of cell performance remains as a challenge to be competitive with the planar design made from similar cell materials. In this work, improvement of the anode micro-structure prepared via a phase-inversion assisted process has been studied by employing common SOFC materials including nickel-yttria stabilised zirconia (Ni-YSZ). A new anode design with longer micro-channels and larger pore entrance made using solvent-based bore fluid gave better electrochemical performance compared to the conventional single-channel anode design. Such new design, when utilising YSZ material could be made into a suitable electrolyte scaffold for incorporating anode materials, copper-ceria (Cu-CeO2). MT-SOFC with Cu-based anode was tested for direct methane (CH4) utilisation. Notwithstanding the great potential of MT-SOFC, problems such as low mechanical robustness of the small micro-tube must be addressed. A multi-channel design has been proposed whereby NiO-YSZ anode substrate with various number of channels have been prepared and developed into complete single micro-monolithic cells. Their properties were compared and eventually tested for electrochemical performances. Micro-monolithic design has a better mechanical property, up to 4-8 times compared to the single-channel counterpart. Electrochemical test showed that 7-channel cell achieved about 120 % increment in terms of power density than the conventional single-channel design. The flexibility in the operation of solid oxide electrochemical reactors allows the use of such devices as a fuel cell and electrolyser. Such unique characteristics have been investigated for fuel cell operation with hydrogen (H2) and carbon dioxide (CO2) electrolysis using a novel 6-channel micro-monolithic cell in which excellent performances have been demonstrated.Open Acces

Design of a Temperature Micro-Sensor with a Gaseous Fluid Flow

Non-intrusive Liquid Crystal Thermography technique (LCT) has been proven as a powerful tool for lowtemperature application in micro-scale systems. It provides high-spatial resolution temperature maps dependent on colour response of heated thermo-chromic liquid crystal material (TLC). Different types of TLCs have been widely used in form of coated paints or water-based droplets in aqueous carrier fluid. Up to now, suitable designs of micro-devices with specific features optimized for their use in the presence of gas micro-flows has still not being proposed. Therefore, the study of a design of single channel micro-device for liquid-gas mixing is presented here. Research work has been performed experimentally and/or numerically to investigate the effect of various geometric designs of micro-devices to provide uniformly distributed TLC particles along a gas flow and to avoid their sedimentation. Beside the geometric design, material and heating systems are of high importance in order to achieve desirable observation of temperature gradients along the channel. Moreover, the flow rate and shear stress inside the channel were set to be minimal due to suspected high sensitivity of TLCs. This paper is intended to bring new insights and fresh perspectives to the development of temperature microscale sensors for practical implementation in the future

Velocity map photoelectron-photoion coincidence imaging on a single detector

Here we report on a new simplified setup for velocity map photoelectron-photoion coincidence imaging using only a single particle detector. We show that both photoelectrons and photoions can be extracted toward the same micro-channel-plate delay line detector by fast switching of the high voltages on the ion optics. This single detector setup retains essentially all the features of a standard two-detector coincidence imaging setup, viz., the high spatial resolution for electron and ion imaging, while only slightly decreasing the ion time-of-flight mass resolution. The new setup paves the way to a significant cost reduction in building a coincidence imaging setup for experiments aiming to obtain the complete correlated three-dimensional momentum distribution of electrons and ions. © 2012 American Institute of Physics

Rapid Fabrication of Custom Microfluidic Devices for Research and Educational Applications

Microfluidic devices allow for the manipulation of fluids, particles, cells, micro-sized organs or organisms in channels ranging from the nano to submillimeter scales. A rapid increase in the use of this technology in the biological sciences has prompted a need for methods that are accessible to a wide range of research groups. Current fabrication standards, such as PDMS bonding, require expensive and time consuming lithographic and bonding techniques. A viable alternative is the use of equipment and materials that are easily affordable, require minimal expertise and allow for the rapid iteration of designs. In this work we describe a protocol for designing and producing PET-laminates (PETLs), microfluidic devices that are inexpensive, easy to fabricate, and consume significantly less time to generate than other approaches to microfluidics technology. They consist of thermally bonded film sheets, in which channels and other features are defined using a craft cutter. PETLs solve field-specific technical challenges while dramatically reducing obstacles to adoption. This approach facilitates the accessibility of microfluidics devices in both research and educational settings, providing a reliable platform for new methods of inquiry

A compact micro-wave synthesizer for transportable cold-atom interferometers

We present the realization of a compact micro-wave frequency synthesizer for an atom interferometer based on stimulated Raman transitions, applied to transportable inertial sensing. Our set-up is intended to address the hyperfine transitions of Rubidium 87 atoms at 6.8 GHz. The prototype is evaluated both in the time and the frequency domain by comparison with state-of-the-art frequency references developed at LNE-SYRTE. In free-running mode, it features a residual phase noise level of -65 dBrad$^2.Hz^{-1} at 10-Hz offset frequency and a white phase noise level in the order of -120 dBrad^2.Hz^{-1} for Fourier frequencies above 10 kHz. The phase noise effect on the sensitivity of the atomic interferometer is evaluated for diverse values of cycling time, interrogation time and Raman pulse duration. To our knowledge, the resulting contribution is well below the sensitivity of any demonstrated cold atom inertial sensors based on stimulated Raman transitions. The drastic improvement in terms of size, simplicity and power consumption paves the way towards field and mobile operations.Comment: accepted for publication in Review of Scientific Instruments, 6 pages, 4 figure

Ferromanganese nodules and micro-hardgrounds associated with the Cadiz Contourite Channel (NE Atlantic): Palaeoenvironmental records of fluid venting and bottom currents

Ferromanganese nodule fields and hardgrounds have recently been discovered in the Cadiz Contourite Channel in the Gulf of Cadiz (850–1000 m). This channel is part of a large contourite depositional system generated by the Mediterranean Outflow Water. Ferromanganese deposits linked to contourites are interesting tools for palaeoenviromental studies and show an increasing economic interest as potential mineral resources for base and strategic metals. We present a complete characterisation of these deposits based on submarine photographs and geophysical, petrographic, mineralogical and geochemical data. The genesis and growth of ferromanganese deposits, strongly enriched in Fe vs. Mn (av. 39% vs. 6%) in this contourite depositional system result from the combination of hydrogenetic and diagenetic processes. The interaction of the Mediterranean Outflow Water with the continental margin has led to the formation of Late Pleistocene–Holocene ferromanganese mineral deposits, in parallel to the evolution of the contourite depositional system triggered by climatic and tectonic events. The diagenetic growth was fuelled by the anaerobic oxidation of thermogenic hydrocarbons (δ13CPDB=−20 to −37‰) and organic matter within the channel floor sediments, promoting the formation of Fe–Mn carbonate nodules. High 87Sr/86Sr isotopic values (up to 0.70993±0.00025) observed in the inner parts of nodules are related to the influence of radiogenic fluids fuelled by deep-seated fluid venting across the fault systems in the diapirs below the Cadiz Contourite Channel. Erosive action of the Mediterranean Outflow Water undercurrent could have exhumed the Fe–Mn carbonate nodules, especially in the glacial periods, when the lower core of the undercurrent was more active in the study area. The growth rate determined by 230Thexcess/232Th was 113±11 mm/Ma, supporting the hypothesis that the growth of the nodules records palaeoenvironmental changes during the last 70 ka. Ca-rich layers in the nodules could point to the interaction between the Mediterranean Outflow Water and the North Atlantic Deep Water during the Heinrich events. Siderite–rhodochrosite nodules exposed to the oxidising seabottom waters were replaced by Fe–Mn oxyhydroxides. Slow hydrogenetic growth of goethite from the seawaters is observed in the outermost parts of the exhumed nodules and hardgrounds, which show imprints of the Mediterranean Outflow Water with low 87Sr/86Sr isotopic values (down to 0.70693±0.00081). We propose a new genetic and evolutionary model for ferromanganese oxide nodules derived from ferromanganese carbonate nodules formed on continental margins above the carbonate compensation depth and dominated by hydrocarbon seepage structures and strong erosive action of bottom currents. We also compare and discuss the generation of ferromanganese deposits in the Cadiz Contourite Channel with that in other locations and suggest that our model can be applied to ferromanganiferous deposits in other contouritic systems affected by fluid venting

Micro protocol engineering for unstructured carriers: On the embedding of steganographic control protocols into audio transmissions

Network steganography conceals the transfer of sensitive information within unobtrusive data in computer networks. So-called micro protocols are communication protocols placed within the payload of a network steganographic transfer. They enrich this transfer with features such as reliability, dynamic overlay routing, or performance optimization --- just to mention a few. We present different design approaches for the embedding of hidden channels with micro protocols in digitized audio signals under consideration of different requirements. On the basis of experimental results, our design approaches are compared, and introduced into a protocol engineering approach for micro protocols.Comment: 20 pages, 7 figures, 4 table