46,226 research outputs found
Effect of catalytic conditions on the synthesis of new aconitate esters
Sugar cane is a crop which generates large amounts of biomass and a juice rich in highvalue natural molecules. After extracting sugar from the juice, the recovering of various compounds such as organic acids contained in molasses could contribute to increase the competivity of the sugar industry. Therefore, according to the biorefinery approach, we propose to study the chemical conversion of one of these acids, the aconitic acid, by esterification reactions. A new series of aconitate esters have been synthesized by combining aconitic acid and alcohols from natural origin. The effects of experimental conditions have been investigated and have shown that the type of catalysis has a significant effect on the selectivity. Kinectics have thus been performed to determine the best conditions to synthetize enriched compositions in esters. Homogeneous catalysis generates the highest yield in triester. Heterogeneous catalysis(macroporous resins) is prefered for the production of monoesters while catalysis assisted by ionic liquid is adapted to prepare mainly diesters. Green indicators have been discussed according to the calculations performed. The resulting polyfunctional esters are totally biosourced molecules and have a great potential as bioproducts for different applications
Physics-based prognostic modelling of filter clogging phenomena
In industry, contaminant filtration is a common process to achieve a desired level of purification, since contaminants in liquids such as fuel may lead to performance drop and rapid wear propagation. Generally, clogging of filter phenomena is the primary failure mode leading to the replacement or cleansing of filter. Cascading failures and weak performance of the system are the unfortunate outcomes due to a clogged filter. Even though filtration and clogging phenomena and their effects of several observable parameters have been studied for quite some time in the literature, progression of clogging and its use for prognostics purposes have not been addressed yet. In this work, a physics based clogging progression model is presented. The proposed model that bases on a well-known pressure drop equation is able to model three phases of the clogging phenomena, last of which has not been modelled in the literature yet. In addition, the presented model is integrated with particle filters to predict the future clogging levels and to estimate the remaining useful life of fuel filters. The presented model has been implemented on the data collected from an experimental rig in the lab environment. In the rig, pressure drop across the filter, flow rate, and filter mesh images are recorded throughout the accelerated degradation experiments. The presented physics based model has been applied to the data obtained from the rig. The remaining useful lives of the filters used in the experimental rig have been reported in the paper. The results show that the presented methodology provides significantly accurate and precise prognostic results
Basic Understanding of Condensed Phases of Matter via Packing Models
Packing problems have been a source of fascination for millenia and their
study has produced a rich literature that spans numerous disciplines.
Investigations of hard-particle packing models have provided basic insights
into the structure and bulk properties of condensed phases of matter, including
low-temperature states (e.g., molecular and colloidal liquids, crystals and
glasses), multiphase heterogeneous media, granular media, and biological
systems. The densest packings are of great interest in pure mathematics,
including discrete geometry and number theory. This perspective reviews
pertinent theoretical and computational literature concerning the equilibrium,
metastable and nonequilibrium packings of hard-particle packings in various
Euclidean space dimensions. In the case of jammed packings, emphasis will be
placed on the "geometric-structure" approach, which provides a powerful and
unified means to quantitatively characterize individual packings via jamming
categories and "order" maps. It incorporates extremal jammed states, including
the densest packings, maximally random jammed states, and lowest-density jammed
structures. Packings of identical spheres, spheres with a size distribution,
and nonspherical particles are also surveyed. We close this review by
identifying challenges and open questions for future research.Comment: 33 pages, 20 figures, Invited "Perspective" submitted to the Journal
of Chemical Physics. arXiv admin note: text overlap with arXiv:1008.298
Relativistic Kinetics of Phonon Gas in Superfluids
The relativistic kinetic theory of the phonon gas in superfluids is
developed. The technique of the derivation of macroscopic balance equations
from microscopic equations of motion for individual particles is applied to an
ensemble of quasi-particles. The necessary expressions are constructed in terms
of a Hamilton function of a (quasi-)particle. A phonon contribution into
superfluid dynamic parameters is obtained from energy-momentum balance
equations for the phonon gas together with the conservation law for superfluids
as a whole. Relations between dynamic flows being in agreement with results of
relativistic hydrodynamic consideration are found. Based on the kinetic
approach a problem of relativistic variation of the speed of sound under phonon
influence at low temperature is solved.Comment: 23 pages, Revtex fil
Structural similarity between dry and wet sphere packings
The mechanical properties of granular materials change significantly in the
presence of a wetting liquid which creates capillary bridges between the
particles. Here we demonstrate, using X-ray tomographies of dry and wet sphere
packings, that this change in mechanical properties is not accompanied by
structural differences between the packings. We characterize the latter by the
average numbers of contacts of each sphere and the shape
isotropy of the Voronoi cells of the particles.
Additionally, we show that the number of liquid bridges per sphere is approximately equal to , independent of the
volume fraction of the packing. These findings will be helpful in guiding the
development of both particle-based models and continuum mechanical descriptions
of wet granular matter.Comment: slightly revised versio
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