Development and design of binder systems for titanium metal injection molding: An overview

Titanium metal injection molding (Ti-MIM) has been practiced since the late 1980s. Logically, the Ti-MIM practice follows the similar processes developed for the antecedent materials such as stainless steel and ceramics. Although Ti-MIM is a favorite research topic today, the issue of convincing the designers to use Ti injection-molded parts still exists. This is mainly because of the concern about contamination which seems unavoidable during the Ti-MIM process. Much information about the binder formulation, powder requirements, debinding, and sintering is available in the literature. There are several powder vendors and feedstock suppliers. However, most of the binders in the feedstock are proprietarily protected. The disclosed information on the binders used for formulating powder feedstock is very limited, which in turn discourages their adoption by engineering designers. This overview intends to discuss some of major binder systems for Ti-MIM available in the literature. It serves to provide a guideline for the Ti-MIM practitioners to choose a suitable powder feedstock

Recent advances in 3D printing of biomaterials.

3D Printing promises to produce complex biomedical devices according to computer design using patient-specific anatomical data. Since its initial use as pre-surgical visualization models and tooling molds, 3D Printing has slowly evolved to create one-of-a-kind devices, implants, scaffolds for tissue engineering, diagnostic platforms, and drug delivery systems. Fueled by the recent explosion in public interest and access to affordable printers, there is renewed interest to combine stem cells with custom 3D scaffolds for personalized regenerative medicine. Before 3D Printing can be used routinely for the regeneration of complex tissues (e.g. bone, cartilage, muscles, vessels, nerves in the craniomaxillofacial complex), and complex organs with intricate 3D microarchitecture (e.g. liver, lymphoid organs), several technological limitations must be addressed. In this review, the major materials and technology advances within the last five years for each of the common 3D Printing technologies (Three Dimensional Printing, Fused Deposition Modeling, Selective Laser Sintering, Stereolithography, and 3D Plotting/Direct-Write/Bioprinting) are described. Examples are highlighted to illustrate progress of each technology in tissue engineering, and key limitations are identified to motivate future research and advance this fascinating field of advanced manufacturing

Development and mechanical characterization of novel ceramic foams fabricated by gel-casting

Porous ceramic materials are of considerable interest for a variety of chemical and industrial applications in extremely harsh conditions, particularly at very high temperatures for long time periods. A combined gel-casting-fugitive phase process employing agar as a natural gelling agent and polyethylene spheres as pore formers was exploited to produce porous ceramic bodies. Alumina and alumina–zirconia powders were used to prepare samples having a porosity of about 65–70–75 vol%. The composite powder was produced by a surface modification route, i.e. by coating a well-dispersed alpha-alumina powder with a zirconium chloride aqueous solution. On thermal treatment, ultra-fine tetragonal zirconia grains were formed on the surface of the alumina particles. SEM observations and image analysis were used to characterize the microstructure of porous samples and uniaxial compressive tests were carried out to measure their mechanical behavior

Study of decomposition behaviour of binders and the effect of binder type on strength and density of alumina samples

Organic binders are generally used during green shaping of ceramic bodies as these binders help in obtaining desired green density and defect minimization during pressing. The aim of the present study was two-fold. First was to study the decomposition behaviour of the three chosen binders (viz. PVA, Dextrin and Starch) through DSC/TG, FTIR and weight loss measurements in air. Second was incorporating these binders (in different amount) in reactive alumina (which was chosen as the base ceramic matrix) in different proportions. Subsequently these binder added powders were sintered in air at 1550ºC and sintered pellets were characterized for apparent porosity, bulk density, strength and surface feature (through optical microscope).The strength and density measurements for both green and sintered samples were carried out and they showed varied trends. The green strength of starch added pellets was found to be least while PVA containing pellets had maximum green strength. In case of sintered pellets, starch added samples showed the most consistent set of strength values but its strength decreased with increase in binder concentration while the reverse occurred for PVA and dextrin containing pellets. Removal of binders is an important step during high temperature sintering process and under ideal conditions binder removal should be complete before consolidation of ceramic particles has started. When binder removal from sintered samples is incomplete, the sintered samples may contain defects such as black coring (due to incomplete burning of carbon which will be present as residual carbon below the surface), sealed pores, bloating, etc. Optical microscope imaging was done to observe the presence of such defects. These defects may lead to a variation in pore shape, size and distribution

Colloidal approach for the design of Ti powders sinterable at low temperature

The colloid-chemistry control of metallic powders in aqueous slurries is proposed as a way to produce spherical granules of fine titanium particles able to be processed by powder metallurgy (PM) techniques. Significant improvement of sintering behavior is achieved, leading to high dense parts at reduced sintering temperature and time. Consequently the control of grain growth during sintering was achieved, as well as the oxygen content. This approach can be extended to other strategies for Ti design, such as the homogeneous dispersion of second phases for further control of grain size and modification of properties.The authors would like to acknowledge the financial support from Spanish Government through the projects MAT 2009-14448-C02-01 and 02, MAT2012-38650-C02-01 and 02En prens

Nonterrestrial utilization of materials: Automated space manufacturing facility

Four areas related to the nonterrestrial use of materials are included: (1) material resources needed for feedstock in an orbital manufacturing facility, (2) required initial components of a nonterrestrial manufacturing facility, (3) growth and productive capability of such a facility, and (4) automation and robotics requirements of the facility

Stability and rheology of dispersions of silicon nitride and silicon carbide

The relationship between the surface and colloid chemistry of commercial ultra-fine silicon carbide and silicon nitride powders was examined by a variety of standard characterization techniques and by methodologies especially developed for ceramic dispersions. These include electrokinetic measurement, surface titration, and surface spectroscopies. The effects of powder pretreatment and modification strategies, which can be utilized to augment control of processing characteristics, were monitored with these technologies. Both silicon carbide and nitride were found to exhibit silica-like surface chemistries, but silicon nitride powders possess an additional amine surface functionality. Colloidal characteristics of the various nitride powders in aqueous suspension is believed to be highly dependent on the relative amounts of the two types of surface groups, which in turn is determined by the powder synthesis route. The differences in the apparent colloidal characteristics for silicon nitride powders cannot be attributed to the specific absorption of ammonium ions. Development of a model for the prediction of double-layer characteristics of materials with a hybrid site interface facilitated understanding and prediction of the behavior of both surface charge and surface potential for these materials. The utility of the model in application to silicon nitride powders was demonstrated

The materials processing research base of the Materials Processing Center

The goals and activities of the center are discussed. The center activities encompass all engineering materials including metals, ceramics, polymers, electronic materials, composites, superconductors, and thin films. Processes include crystallization, solidification, nucleation, and polymer synthesis

Near net shape manufacturing of metal : a review of approaches and their evolutions

In the last thirty years the concept of manufacturability has been applied to many different processes in numerous industries. This has resulted in the emergence of several different "Design for Manufacturing" methodologies which have in common the aim of reducing productions costs through the application of general manufacturing rules. Near net shape technologies have expanded these concepts, targeting mainly primary shaping process, such as casting or forging. The desired outcomes of manufacturability analysis for near-net-shape (NNS) processes are cost and lead/time reduction through minimization of process steps (in particular cutting and finishing operations) and raw material saving. Product quality improvement, variability reduction and component design functionality enhancement are also achievable through NNS optimization. Process parameters, product design and material selection are the changing variables in a manufacturing chain that interact in complex, non-linear ways. Consequently modeling and simulation play important roles in the investigation of alternative approaches. However defining the manufacturing capability of different processes is also a “moving target” because the various NNS technologies are constantly improving and evolving so there is challenge in accurately reflecting their requirements and capabilities. In the last decade, for example, CAD, CNC technologies and innovation in materials have impacted enormously on the development of NNS technologies. This paper reviews the different methods reported for NNS manufacturability assessment and examines how they can make an impact on cost, quality and process variability in the context of a specific production volume. The discussion identifies a lack of structured approaches, poor connection with process optimization methodologies and a lack of empirical models as gaps in the reported approaches