External grind-hardening forces modelling and experimentation

Grind hardening process utilizes the heat generated in the grinding area for the surface heat treatment of the workpiece. The workpiece surface is heated above the austenitizing temperature by using large values of depth of cut and low workpiece feed speeds. However, such process parameter combinations result in high process forces that inhibit the broad application of grind hardening to smaller grinding machines. In the present paper, modelling and predicting of the process forces as a function of the process parameters are presented. The theoretical predictions present good agreement with experimental results. The results of the study can be used for the prediction of the grind hardening process forces and, therefore, optimize the process parameters so as to be used with every size grinding machine

Oxidation Behavior of a Pd_(43)Cu_(27)Ni_(10)P_(20) Bulk Metallic Glass and Foam in Dry Air

The oxidation behavior of both Pd_(43)Cu_(27)Ni_(10)P_(20) bulk metallic glass (Pd4-BMG) and its amorphous foam containing 45 pct porosity (Pd4-AF) was investigated over the temperature range of 343 K (70 °C) to 623 K (350 °C) in dry air. The results showed that virtually no oxidation occurred in the Pd4-BMG at T < 523 K (250 °C), revealing the alloy’s favorable oxidation resistance in this temperature range. In addition, the oxidation kinetics at T ≥ 523 K (250 °C) followed a parabolic-rate law, and the parabolic-rate constants (k_p values) generally increased with temperature. It was found that the oxidation k_p values of the Pd4-AF are slightly lower than those of the Pd4-BMG, indicating that the porous structure contributes to improving the overall oxidation resistance. The scale formed on the alloys was composed exclusively of CuO at T ≥ 548 K (275 °C), whose thickness gradually increased with increasing temperature. In addition, the amorphous structure remained unchanged at T ≤ 548 K (275 °C), while a triplex-phase structure developed after the oxidation at higher temperatures, consisting of Pd_2Ni_2P, Cu_3P, and Pd_3P

Hierarchical Structure with Highly Ordered Macroporous-Mesoporous Metal-Organic Frameworks as Dual Function for CO2 Fixation.

As a major greenhouse gas, the continuous increase of carbon dioxide (CO2) in the atmosphere has caused serious environmental problems, although CO2 is also an abundant, inexpensive, and nontoxic carbon source. Here, we use metal-organic framework (MOF) with highly ordered hierarchical structure as adsorbent and catalyst for chemical fixation of CO2 at atmospheric pressure, and the CO2 can be converted to the formate in excellent yields. Meanwhile, we have successfully integrated highly ordered macroporous and mesoporous structures into MOFs, and the macro-, meso-, and microporous structures have all been presented in one framework. Based on the unique hierarchical pores, high surface area (592 m2/g), and high CO2 adsorption capacity (49.51 cm3/g), the ordered macroporous-mesoporous MOFs possess high activity for chemical fixation of CO2 (yield of 77%). These results provide a promising route of chemical CO2 fixation through MOF materials

Spectra of Maser Radiation from a Turbulent, Circumnuclear Accretion Disk. III. Circular polarization

Calculations are performed for the circular polarization of maser radiation from a turbulent, Keplerian disk that is intended to represent the sub-parsec disk at the nucleus of the galaxy NGC4258. The polarization in the calculations is a result of the Zeeman effect in the regime in which the Zeeman splitting is much less than the spectral linebreadth. Plausible configurations for turbulent magnetic and velocity fields in the disk are created by statistical methods. This turbulence, along with the Keplerian velocity gradients and the blending of the three hyperfine components to form the $6_{16} - 5_{23}$ masing transition of water, are key ingredients in determining the appearance of the polarized spectra that are calculated. These spectra are quite different from the polarized spectra that would be expected for a two-level transition where there is no hyperfine structure. The effect of the hyperfine structure on the polarization is most striking in the calculations for the maser emission that represents the central (or systemic) features of NGC4258. Information about magnetic fields is inferred from observations for polarized maser radiation and bears on the structure of accretion disks.Comment: Latex, uses aastex, eucal, to be published in the Astrophysical Journa