96,589 research outputs found
The impacts of surface conditions on the vapor-liquid-solid growth of germanium nanowires on Si (100) substrate
The impacts of surface conditions on the growth of Ge nanowires on a Si (100) substrate are discussed in detail. On SiO2-terminated Si substrates, high-density Ge nanowires can be easily grown. However, on H-terminated Si substrates, growing Ge nanowires is more complex. The silicon migration and the formation of a native SiO2 overlayer on a catalyst surface retard the growth of Ge nanowires. After removing this overlayer in the HF solution, high-density and well-ordered Ge nanowires are grown. Ge nanowires cross vertically and form two sets of parallel nanowires. It is found that nanowires grew along ?110? direction
Electronic, Mechanical, and Piezoelectric Properties of ZnO Nanowires
Hexagonal [0001] nonpassivated ZnO nanowires are studied with density
functional calculations. The band gap and Young's modulus in nanowires which
are larger than those in bulk ZnO increase along with the decrease of the
radius of nanowires. We find ZnO nanowires have larger effective piezoelectric
constant than bulk ZnO due to their free boundary. In addition, the effective
piezoelectric constant in small ZnO nanowires doesn't depend monotonously on
the radius due to two competitive effects: elongation of the nanowires and
increase of the ratio of surface atoms
Electronic structures of free-standing nanowires made from indirect bandgap semiconductor gallium phosphide
We present a theoretical study of the electronic structures of freestanding
nanowires made from gallium phosphide (GaP)--a III-V semiconductor with an
indirect bulk bandgap. We consider [001]-oriented GaP nanowires with square and
rectangular cross sections, and [111]-oriented GaP nanowires with hexagonal
cross sections. Based on tight binding models, both the band structures and
wave functions of the nanowires are calculated. For the [001]-oriented GaP
nanowires, the bands show anti-crossing structures, while the bands of the
[111]-oriented nanowires display crossing structures. Two minima are observed
in the conduction bands, while the maximum of the valence bands is always at
the -point. Using double group theory, we analyze the symmetry
properties of the lowest conduction band states and highest valence band states
of GaP nanowires with different sizes and directions. The band state wave
functions of the lowest conduction bands and the highest valence bands of the
nanowires are evaluated by spatial probability distributions. For practical
use, we fit the confinement energies of the electrons and holes in the
nanowires to obtain an empirical formula.Comment: 19 pages, 10 figure
Electron transport properties of sub-3-nm diameter copper nanowires
Density functional theory and density functional tight-binding are applied to
model electron transport in copper nanowires of approximately 1 nm and 3 nm
diameters with varying crystal orientation and surface termination. The copper
nanowires studied are found to be metallic irrespective of diameter, crystal
orientation and/or surface termination. Electron transmission is highly
dependent on crystal orientation and surface termination. Nanowires oriented
along the [110] crystallographic axis consistently exhibit the highest electron
transmission while surface oxidized nanowires show significantly reduced
electron transmission compared to unterminated nanowires. Transmission per unit
area is calculated in each case, for a given crystal orientation we find that
this value decreases with diameter for unterminated nanowires but is largely
unaffected by diameter in surface oxidized nanowires for the size regime
considered. Transmission pathway plots show that transmission is larger at the
surface of unterminated nanowires than inside the nanowire and that
transmission at the nanowire surface is significantly reduced by surface
oxidation. Finally, we present a simple model which explains the transport per
unit area dependence on diameter based on transmission pathways results
Fluctuational Instabilities of Alkali and Noble Metal Nanowires
We introduce a continuum approach to studying the lifetimes of monovalent
metal nanowires. By modelling the thermal fluctuations of cylindrical nanowires
through the use of stochastic Ginzburg-Landau classical field theories, we
construct a self-consistent approach to the fluctuation-induced `necking' of
nanowires. Our theory provides quantitative estimates of the lifetimes for
alkali metal nanowires in the conductance range 10 < G/G_0 < 100 (where
G_0=2e^2/h is the conductance quantum), and allows us to account for
qualitative differences in the conductance histograms of alkali vs. noble metal
nanowires
Jahn-Teller Distortions and the Supershell Effect in Metal Nanowires
A stability analysis of metal nanowires shows that a Jahn-Teller deformation
breaking cylindrical symmetry can be energetically favorable, leading to stable
nanowires with elliptic cross sections. The sequence of stable cylindrical and
elliptical nanowires allows for a consistent interpretation of experimental
conductance histograms for alkali metals, including both the shell and
supershell structures. It is predicted that for gold, elliptical nanowires are
even more likely to form since their eccentricity is smaller than for alkali
metals. The existence of certain metastable ``superdeformed'' nanowires is also
predicted
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