The state of the art in selective catalytic reduction control

Selective Catalytic Reduction (SCR) is a leading after treatment technology for the removal of nitrogen oxide (NOx) from exhaust gases (DeNOx). It presents an interesting control challenge, especially at high conversion, because both reagents (NOx and ammonia) are toxic, and therefore an excess of either is highly undesirable. Numerous system layouts and control methods have been developed for SCR systems, driven by the need to meet future emission standards. This paper summarizes the current state-of-the-art control methods for the SCR aftertreatment systems, and provides a structured and comprehensive overview of the research on SCR control. The existing control techniques fall into three main categories: traditional SCR control methods, model-based SCR control methods, and advanced SCR control methods. For each category, the basic control technique is defined. Further techniques in the same category are then explained and appreciated for their relative advantages and disadvantages. Thus this paper presents a snapshot of the current state of the art for the research area of SCR control. This is a very active field, and it is hoped that by providing a better understanding of the different control strategies already developed for SCR control, future areas of interest will be identified and developed with the ultimate aim of satisfying the increasingly stringent emissions legislation. Copyright © 2014 SAE International

Model-Based Ammonia Slip Observation for SCR Control and Diagnosis

© 2020 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.[EN] The control of selective catalytic reduction (SCR) systems, via NH3 injection, requires from a precise estimation of the SCR load in order to ensure NOx reduction by minimizing ammonia slip. This article aims to resolve the cross-sensitivity of current NOx sensors at the outlet of the SCR, by providing the control unit with an estimation of NOx and ammonia slip. The problem of discerning between NOx and ammonia slip is solved by identifying an intermediate variable representing the SCR load. The SCR load is estimated by combining the mass conservation principle between the inlet and the outlet of the SCR and a NOx reduction model, via an extended Kalman filter. Current models and observers have several limitations to represent the real behavior of the SCR along all the operating conditions; on one hand, when relying on the mass conservation, small errors at models are integrated, leading to important bias on the SCR load and on the other hand, the dynamics at the SCRmust be preciselymodelled for an adequate adaptation of the model. The main focus of the developed algorithm is to use a simplified model which might be used for ammonia slip estimation, being aware of current limitations of SCR models in real operation. Experimental results in a EURO 6 compression ignited (CI) engine show the potential of such observation in transient conditions and an adequate correlation with external ammonia measurements provided by additional sensors available on the test bench.This work was supported by the Spanish Ministerio de Economia, Industria y Competitividad under project TRA2016-78717-R.Guardiola, C.; Pla Moreno, B.; Bares-Moreno, P.; Mora, J. (2020). Model-Based Ammonia Slip Observation for SCR Control and Diagnosis. IEEE/ASME Transactions on Mechatronics. 25(3):1346-1353. https://doi.org/10.1109/TMECH.2020.2974341S1346135325

Development of an Ammonia Reduction After-Treatment Systems for Stoichiometric Natural Gas Engines

Three-way catalyst (TWC) equipped stoichiometric natural gas vehicles have proven to be an effective alternative fuel strategy that shows significant low NOx emissions characteristics. However, recent studies have shown the TWC activity to contribute to elevated levels of tailpipe ammonia (NH 3) emissions. Although a non-regulated pollutant, ammonia is a potent pre-cursor to ambient secondary PM formation. Ammonia is an inevitable byproduct of fuel rich operation that results in lowest NOx slip through the TWC after-treatment system.;The main objective of the study is to develop a passive Ammonia Reduction Catalyst (passive-ARC) based NH3 reduction strategy that results in an overall reduction of ammonia as well as NOx emissions. The study investigated the characteristics of Fe-based and Cu-based zeolites SCR catalysts in storage and desorption of ammonia at high exhaust temperature conditions, that are typical of stoichiometric natural gas engines. Continuous measurements of NOx and NH3 before and after the SCR systems were conducted using a Fourier Transform Infrared Spectrometry (FTIR) gas analyzer. Results of the investigation showed that both, the Fe- and Cu zeolite SCRs adsorbed above 90% of TWC generated NH3 emissions below 350--375 °C SCR temperatures. Desorption or slipping of NH3 was observed at exhaust gas temperatures exceeding 400 °C. In terms of NOx conversions, Fe-zeolite showed efficiency between 50--80% above temperatures of 300--350 °C while Cu-zeolite performed well at lower SCR temperature from 250 °C and above with a conversion efficiency of greater than 50%.;In order to efficiently reduce both NOx and NH3 simultaneously over longer durations it was found that an engine-based air fuel ratio operation strategy for the passive-ARC system must be developed. To this extent, the study extended its objectives to develop an engine-based control strategy that results in stoichiometric ammonia production operation followed by brief lean operation to regenerate the saturated ammonia reduction catalyst using high NOx slip through TWC. The study presents comprehensive results of ammonia storage characteristics of SCRs pertaining to stoichiometric natural gas engine exhaust as well as an advanced engine control strategy approach to simultaneously reduce both NOx and NH3 using an alternating air -fuel ratio approach

Control-oriented modelling and diagnostics of diesel after-treatment catalysts

[ES] Esta tesis doctoral abarca el desarrollo de algoritmos orientados a mejorar el sistema de control de emisiones en motores Diesel. Para este propósito, la inclusión en el vehículo de sensores embarcados como los de temperatura, los de NOx o el de NH3 permite realizar diagnóstico a bordo de los sistemas de post-tratamiento foco de este trabajo, los cuales son el DOC y el SCR. Así pues, el objetivo es el de satisfacer las normativas de diagnóstico a bordo para mantener las emisiones por debajo del umbral permitido por la normativa a lo largo del tiempo. Los tests experimentales, incluyendo las medidas con analizador de gases, permiten tener una visión más amplia de las especies en la línea de escape. Complementariamente, se utilizan unidades nuevas y envejecidas para tener el efecto experimental del envejecimiento en los catalizadores. De esta manera, se analiza el efecto de la temperatura, el gasto de escape, las concentraciones de las especies y el envejecimiento en el DOC y en el SCR, así como la evaluación de algunas de las medidas relevantes realizadas por los sensores. Las temperaturas tienen una influencia destacada en el funcionamiento de los catalizadores, por lo que se requiere la evaluación de las medidas de los sensores de temperatura, junto con el desarrollo de modelos de transmisión de calor, para alimentar las funciones a continuación desarrolladas. En este sentido, la medida lenta del sensor aguas arriba del DOC se mejora en condiciones transitorias mediante una técnica de fusión de la información basada en un filtro de Kalman. Luego, se presenta un modelo de transmisión de calor 1D y un modelo agrupado 0D, en los cuales se evalúan las entradas aguas arriba según el uso del modelo. Por otra parte, se presenta una técnica para estimar el incremento de temperatura debido a la oxidación de los pulsos de post-inyección en el DOC. Se proponen modelos para ambos DOC y SCR para estimar el efecto del envejecimiento en las emisiones, en los cuales el factor de envejecimiento es modelado como un parámetro sintonizable que permite variar desde estados nuevos a envejecidos. Por una parte, un modelo agrupado 0D es desarrollado para el DOC con el propósito de estimar el desliz de HC y CO, el cual es validado en un WLTC para después ser usado en simulación. Por otra parte, un modelo 1D y un modelo 0D se desarrollan para el SCR, los cuales se usan a continuación para alimentar la estrategia de diagnóstico y para simulación. Finalmente, las estrategias de diagnóstico se presentan para fallo total o retirada de DOC, así como para la estimación de la eficiencia en DOC y SCR. Por una parte, la primera estrategia se divide en pasiva y activa, en la que se usan post-inyecciones en la activa para excitar el sistema y confirmar el fallo total si es el caso. A continuación, la eficiencia del DOC se estima a través de una técnica indirecta en la que la temperatura de activación se detecta y se relaciona con el incremento de emisiones a través del modelo. Por otra parte, se desarrolla un observador para estimar el estado de envejecimiento del SCR, el cual está basado en un filtro de Kalman extendido. Sin embargo, para evitar asociar baja eficiencia del catalizador debido a pobre calidad de la urea inyectada, a envejecimiento del SCR, un indicador de la calidad de la urea se ejecuta en paralelo.[CA] Esta tesi doctoral abasta el desenvolupament d'algoritmes orientats a millor el sistema de control d'emissions en motors Diesel. Per a este propòsit, la inclusió en el vehicle de sensor embarcats com els de temperatura, els de NOx o el d'NH3 permet realitzar el diagnòstic a bord dels sistemes de post-tractament focus d'este treball, els quals són el DOC i el SCR. Així doncs, l'objectiu és el de satisfer les normatives de diagnòstic a bord per a mantindre les emissions per baix de l'umbral permés per la normativa al llarg del temps. Els tests experimentals, incloent les mesures amb analitzador de gasos, permeten obtindre una visió més àmplia de les espècies en la línia d'escapament. Complementàriament, s'utilitzen unitats noves i envellides per tal de tindre l'efecte experimental de l'envelliment en els catalitzadors. D'aquesta manera, s'analitza l'efecte de la temperatura, la despesa d'escapament, les concentracions de les espècies i l'envelliment en el DOC i en el SCR, així com l'avaluació d'algunes mesures rellevants realitzades pels sensors. Les temperatures tenen una influència destacada en el funcionament dels catalitzadors, pel que es requerix l'avaluació de les mesures dels sensors de temperatura, junt amb el desenvolupament de models de transmissió de calor, per a alimentar les funcions a continuació desenvolupades. En este sentit, la mesura lenta del sensor a l'entrada del DOC es millora en condicions transitòries mitjançant una tècnica de fusió de la informació basada en un filtre de Kalman. Després, es presenta un model de transmissió de calor 1D i un model agrupat 0D, en els quals s'avaluen les entrades a l'entrada segons l'ús del model. Per altra banda, es presenta una tècnica per a estimar l'increment de temperatura degut a l'oxidació dels polsos de post-injecció en el DOC. Es proposen models per a DOC i SCR per a estimar l'efecte de l'envelliment en les emissions, en els quals es modela el factor d'envelliment com un paràmetre sintonitzable, que permet variar des d'estats nous a envellits. Per altra banda, un model agrupat 0D _es desenvolupat per al DOC amb el propòsit d'estimar la relliscada de HC i CO, el qual és validat en un WLTC per a després ser usat en simulació. Per altra banda, un model 1D i un model 0D es desenvolupen per al SCR, els quals s'usen a continuació per a alimentar l'estratègia de diagnòstic i per a simulació. Finalment, les estratègies de diagnòstic es presenten per a la fallada total o retirada del DOC, així com per a l'estimació de l'eficiència en DOC i SCR. Per altra banda, la primera estratègia es divideix en passiva i activa, en la que s'utilitzen post-injeccions en la activa per a excitar el sistema i confirmar la fallada total si es dona el cas. A continuació, l'eficiència del DOC s'estima a través d'una tècnica indirecta en la que la temperatura d'activació es detecta i es relaciona amb l'increment d'emissions a través del model. Per altra banda, es desenvolupa un observador per a estimar l'estat d'envelliment del SCR, el qual està basat en un filtre de Kalman extés. No obstant això, per a evitar associar baixa eficiència degut a pobre qualitat de l'urea injectada a l'envelliment del SCR, un indicador de la qualitat de l'urea s'executa en paral·lel.[EN] This dissertation covers the development of algorithms oriented to improve the emission control system of Diesel engines. For this purpose, the inclusion of on-board sensors like temperature, NOx and NH3 sensors allows performing on-board diagnostics to the after-treatment systems focus of this work, which are the DOC and the SCR system. Then, the target is to meet on-board diagnostics regulations in order to keep emissions below a regulation threshold over time. Experimental tests, including gas analyzer measurements, allow having a wider view of the species in the exhaust line. Complementary, new and aged units are used in order to have the experimental effect of ageing on the catalysts. Then, the effect of temperature, exhaust mass flow, species concentrations and ageing is analyzed for DOC and SCR, in combination with the assessment of some relevant sensors measurements. As a result, the characteristics, opportunities and limitations extracted from experimental data are used as the basis for the development of models and diagnostics techniques. The assessment of temperature sensors measurements, along with the development of heat transfer models is required to feed temperature dependent functions. In this sense, the slow measurement of the DOC upstream temperature sensor is improved in transient conditions by means of a data fusion technique, based on a fast model and a Kalman filter. Then, a 1D and a 0D lumped heat transfer models are presented, in which the upstream inputs are assessed in relation to its use. On the other hand, a technique to estimate the temperature increase due to post-injection pulses oxidation is also presented. Both DOC and SCR models are proposed in order to estimate the effect of ageing on emissions, in which an ageing factor is modelled as a tunable parameter that allows varying from new to aged states. On the one hand, a 0D lumped model is developed for DOC in order to estimate the HC and CO species slip, which is validated in a WLTC and is then used for simulation. On the other hand, a 1D and a 0D models are developed for SCR, which are then used to feed the diagnostics strategy and for simulation. Finally, diagnostics strategies are presented for total failure or removal of DOC, as well as for efficiency estimation of DOC and SCR. On the one hand, the former strategy is separated into passive and active diagnostics, in which post-injections are used in active diagnostics in order to excite the system and confirm a total failure, in case. Then, the DOC efficiency estimation is done by means of an indirect technique in which the light-off temperature is detected and an emissions increase is related by means of the DOC ageing model. On the other hand, an observer to estimate the SCR ageing state is developed, which is based on an extended Kalman filter. However, in order to avoid associating low SCR efficiency to ageing, an indicator of the injected urea quality is developed to run in parallel.Mora Pérez, J. (2018). Control-oriented modelling and diagnostics of diesel after-treatment catalysts [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/115937TESI

Investigation on new structure of Selective Catalyst Reaction coated Diesel Particulate Filter for optimising DeNOx

Selective Catalyst Reduction (SCR) is the most promising technology to reduce NOx emissions from conventional diesel engines and other lean combustion engines. Traditional after treatment system in the majority of diesel vehicles includes a Diesel Oxidation Catalyst (DOC), a Diesel Particulate Filter (DPF) and a Selective Catalytic Reduction (SCR) catalyst. As emission control by regulations is tightening every year and the demanding for better efficiency, a combination of Selective Catalytic Reduction (SCR) catalyst and Diesel Particulate Filter (DPF) have been researched for several years. The combination catalyst is actually putting an SCR coating on and into DPF’s porous walls so that this combination catalyst (SCR coated DPF or SCR-DPF) can be used to filter diesel particulates and reduce NOx at the same time. The benefit of this combination catalyst system is obvious: the compactness of SCR-DPF reduces the weight, the cost and the complexity of the after treatment system; more importantly, it reduces the engine’s back pressure losses as one of the catalysts is removed from the after treatment system. Despite those benefits, SCR-DPF has some drawbacks. There are studies claiming that the NOx conversion efficiency of SCR-DPF is lower than traditional SCR catalyst and more challenging to control NOx conversion process during the regeneration process due to high temperature and so on. In this research, a new catalyst structure is proposed to solve one of the SCR-DPF limitations. This structure provides large extra surface catalytic area for NOx conversion and it is free from ash loading effect as the extra surface islocated in the outlet channel. And based on the results, for the same NOx conversion rate, the catalyst size can be reduced to half if using new structure. This is owning to the extra surface area in the new structure. In this thesis, 3 three-dimensional catalyst models on channel scale, a Flow-Through (FT) catalyst, a Wall-Flow (WF) catalyst and a Wall-Flow catalyst with Fin (WF-Fin) in outlet channel are proposed and built in order to investigate the cause of performance difference between traditional Flow-Through SCR, Wall-Flow SCR and Wall-Flow SCR with fins. The model of Flow-Through SCR is acted as a benchmarksince it is built and validated against Olsson’s experimental research work. A later model of Wall-Flow type catalyst is modified to Flow-Through SCR model by changing the geometry. The results from the Flow-Through SCR model follows Olsson’s experiment results closely for a wide temperature range under steady and transient conditions, that indicates the successful modelling of the base model. The comparison between WF and WF-Fin model has been made from many different aspects, such as velocity, species composition and reaction rates. The WF-Fin model is focused in the later investigation, the fins bring more active site surface for SCR reactions, but it also has adverse effects to the flow in porous walls if the fin is impermeable as a solid material. The effect of different performance factors requires more studies. But based on the current results, a conclusion can bedrawn for the difference between these three types of SCR catalyst, and the possible causes of performance difference are identified

A SCR Model based on Reactor and Engine Experimental Studies for a Cu-zeolite Catalyst

A NOx reduction efficiency higher than 95% with NH3 slip less than 30 ppm is desirable for heavy-duty diesel (HDD) engines using selective catalytic reduction (SCR) systems to meet the US EPA 2010 NOx standard and the 2014-2018 fuel consumption regulation. The SCR performance needs to be improved through experimental and modeling studies. In this research, a high fidelity global kinetic 1-dimensional 2-site SCR model with mass transfer, heat transfer and global reaction mechanisms was developed for a Cu-zeolite catalyst. The model simulates the SCR performance for the engine exhaust conditions with NH3 maldistribution and aging effects, and the details are presented. SCR experimental data were collected for the model development, calibration and validation from a reactor at Oak Ridge National Laboratory (ORNL) and an engine experimental setup at Michigan Technological University (MTU) with a Cummins 2010 ISB engine. The model was calibrated separately to the reactor and engine data. The experimental setup, test procedures including a surrogate HD-FTP cycle developed for transient studies and the model calibration process are described. Differences in the model parameters were determined between the calibrations developed from the reactor and the engine data. It was determined that the SCR inlet NH3 maldistribution is one of the reasons causing the differences. The model calibrated to the engine data served as a basis for developing a reduced order SCR estimator model. The effect of the SCR inlet NO2/NOx ratio on the SCR performance was studied through simulations using the surrogate HD-FTP cycle. The cumulative outlet NOx and the overall NOx conversion efficiency of the cycle are highest with a NO2/NOx ratio of 0.5. The outlet NH3 is lowest for the NO2/NOx ratio greater than 0.6. A combined engine experimental and simulation study was performed to quantify the NH3 maldistribution at the SCR inlet and its effects on the SCR performance and kinetics. The uniformity index (UI) of the SCR inlet NH3 and NH3/NOx ratio (ANR) was determined to be below 0.8 for the production system. The UI was improved to 0.9 after installation of a swirl mixer into the SCR inlet cone. A multi-channel model was developed to simulate the maldistribution effects. The results showed that reducing the UI of the inlet ANR from 1.0 to 0.7 caused a 5-10% decrease in NOx reduction efficiency and 10-20 ppm increase in the NH3 slip. The simulations of the steady-state engine data with the multi-channel model showed that the NH3 maldistribution is a factor causing the differences in the calibrations developed from the engine and the reactor data. The Reactor experiments were performed at ORNL using a Spaci-IR technique to study the thermal aging effects. The test results showed that the thermal aging (at 800°C for 16 hours) caused a 30% reduction in the NH3 stored on the catalyst under NH3 saturation conditions and different axial concentration profiles under SCR reaction conditions. The kinetics analysis showed that the thermal aging caused a reduction in total NH3 storage capacity (94.6 compared to 138 gmol/m3), different NH3 adsorption/desorption properties and a decrease in activation energy and the pre-exponential factor for NH3 oxidation, standard and fast SCR reactions. Both reduction in the storage capability and the change in kinetics of the major reactions contributed to the change in the axial storage and concentration profiles observed from the experiments

Bibliography of Lewis Research Center technical publications announced in 1985

This compilation of abstracts describes and indexes the technical reporting that resulted from the scientific and engineering work performed and managed by the Lewis Research Center in 1985. All the publications were announced in the 1985 issues of STAR (Scientific and Technical Aerospace Reports) and/or IAA (International Aerospace Abstracts). Included are research reports, journal articles, conference presentations, patents and patent applications, and theses

Bibliography of Lewis Research Center technical publications announced in 1984

This compilation of abstracts describes and indexes the technical reporting that resulted from the scientific and engineering work performed and managed by the Lewis Research Center in 1984. All the publications were announced in the 1984 issues of STAR (Scientific and Technical Aerospace Reports) and/or IAA (International Aerospace Abstracts). Included are research reports, journal articles, conference presentations, patents and patent applications, and theses

Proceedings of Abstracts 10th International Conference on Air Quality Science and Application

This 10th International Conference in Air Quality - Science and Application is being held in the elegant and vibrant city of Milan, Italy. Our local hosts are ARIANET and ARPA Lombardia both of whom play a leading role in assessing and managing air pollution in the area. The meeting builds upon the series that began at the University of Hertfordshire, UK in July 1996. Subsequent meetings have been held at the Technical University of Madrid, Spain (1999), Loutraki, Greece (2001), Charles University, Prague, Czech Republic (2003), Valencia, Spain (2005), Cyprus (2007), Istanbul, Turkey (2009) Athens, Greece (2012) and Garmisch-Partenkirchen, Germany (2014). Over the last two decades controls to limit air pollution have increased but the problem of poor air quality persists in all cities of the world. Consequently, the issue of the quality of air that we breathe remains at the forefront of societal concerns and continues to demand the attention of scientists and policy makers to reduce health impacts and to achieve sustainable development. Although urbanisation is growing in terms of population, transport, energy consumption and utilities, science has shown that impact from air pollution in cities is not restricted to local scales but depends on contributions from regional and global scales including interactions with climate change. Despite improvements in technology, users still demand robust management and assessment tools to formulate effective control policies and strategies for reducing the health impact of air pollution. The topics of papers presented at the conference reflect the diversity of scales, processes and interactions affecting air pollution and its impact on health and the environment. As usual, the conference is stimulating cross-fertilisation of ideas and cooperation between the different air pollution science and user communities. In particular, there is greater involvement of city, regional and global air pollution, climate change, users and health communities at the meeting. This international conference brings together scientists, users and policy makers from across the globe to discuss the latest scientific advances in our understanding of air pollution and its impacts on our health and environment. In addition to the scientific advances, the conference will also seek to highlight applications and developments in management strategies and assessment tools for policy and decision makers. This volume presents a collection of abstracts of papers presented at the Conference. The main themes covered in the Conference include: Air quality and impact on regional to global scales Development/application/evaluation of air quality and related models Environmental and health impact resulting from air pollution Measurement of air pollutants and process studies Source apportionment and emission models/inventories Urban meteorology Special session: Air quality impacts of the increasing use of biomass fuels Special session: Air quality management for policy support and decisions Special session: Air pollution meteorology from local to global scales Special session: Climate change and human health Special Session: Modelling and measuring non-exhaust emissions from traffic Special session: Transport related air pollution - PM and its impact on cities and across EuropeFinal Published versio