11,853 research outputs found

    Enhanced dynamic nuclear polarization via swept microwave frequency combs

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    Dynamic Nuclear Polarization (DNP) has enabled enormous gains in magnetic resonance signals and led to vastly accelerated NMR/MRI imaging and spectroscopy. Unlike conventional cw-techniques, DNP methods that exploit the full electron spectrum are appealing since they allow direct participation of all electrons in the hyperpolarization process. Such methods typically entail sweeps of microwave radiation over the broad electron linewidth to excite DNP, but are often inefficient because the sweeps, constrained by adiabaticity requirements, are slow. In this paper we develop a technique to overcome the DNP bottlenecks set by the slow sweeps, employing a swept microwave frequency comb that increases the effective number of polarization transfer events while respecting adiabaticity constraints. This allows a multiplicative gain in DNP enhancement, scaling with the number of comb frequencies and limited only by the hyperfine-mediated electron linewidth. We demonstrate the technique for the optical hyperpolarization of 13C nuclei in powdered microdiamonds at low fields, increasing the DNP enhancement from 30 to 100 measured with respect to the thermal signal at 7T. For low concentrations of broad linewidth electron radicals, e.g. TEMPO, these multiplicative gains could exceed an order of magnitude.Comment: Contains supplementary inf

    Entropy production in full phase space for continuous stochastic dynamics

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    The total entropy production and its three constituent components are described both as fluctuating trajectory-dependent quantities and as averaged contributions in the context of the continuous Markovian dynamics, described by stochastic differential equations with multiplicative noise, of systems with both odd and even coordinates with respect to time reversal, such as dynamics in full phase space. Two of these constituent quantities obey integral fluctuation theorems and are thus rigorously positive in the mean by Jensen's inequality. The third, however, is not and furthermore cannot be uniquely associated with irreversibility arising from relaxation, nor with the breakage of detailed balance brought about by non-equilibrium constraints. The properties of the various contributions to total entropy production are explored through the consideration of two examples: steady state heat conduction due to a temperature gradient, and transitions between stationary states of drift-diffusion on a ring, both in the context of the full phase space dynamics of a single Brownian particle

    Optimization of exposure time division for wide field observations

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    The optical observations of wide fields of view encounter the problem of selection of best exposure time. As there are usually plenty of objects observed simultaneously, the quality of photometry of the brightest ones is always better than of the dimmer ones. Frequently all of them are equally interesting for the astronomers and thus it is desired to have all of them measured with the highest possible accuracy. In this paper we present a novel optimization algorithm dedicated for the division of exposure time into sub-exposures, which allows to perform photometry with more balanced noise budget. Thanks to the proposed technique, the photometric precision of dimmer objects is increased at the expense of the measurement fidelity of the brightest ones. We tested the method on real observations using two telescope setups demonstrating its usefulness and good agreement with the theoretical expectations. The main application of our approach is a wide range of sky surveys, including the ones performed by the space telescopes. The method can be applied for planning virtually any photometric observations, in which the objects of interest show a wide range of magnitudes.Comment: 18 pages, 5 figure
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