Engineering of hybrid materials for self-powered flexible sensors

Department of Energy Engineering (Energy Engineering)Along with the 4th industrial revolution, the great advance in wearable electronics has led a new paradigm in our life. Especially, wearable sensor technology has received great attention as promising candidates to improve the quality of life by realizing the ???Internet of Things??? which can be utilized in daily healthcare, intelligent control, daily activity monitoring, and human-machine interface systems. The ideal wearable devices require several characteristics providing light weight, flexible, unobtrusive, autonomously powered for the convenience of user and sustainable uses. Although various emerging technologies have been suggested to meet these requirements, there are still challenges for highly flexible and unobtrusive forms, multifunctionality, and sustainable uses, which are directly related to widespread practical applications. In response to these requirements, several approaches to explore functional materials and to design the effective structures for advanced sensor performances with sustainable uses, high sensitivity, and multifunctionality. For sustainable uses, self-powered sensing system can be developed by triboelectric/piezoelectric/pyroelectric effect, which can rule out any problems with power sources. For wearable and flexible form factors, textile and extremely thin films, which are mountable and attachable on the human body, are used instead of conventional obtrusive devices, improving the wearing sensing of devices. Moreover, the selection of multifunctional materials and modification of material characteristics can realize multifunctionality which can respond to different stimuli (pressure and temperature) simultaneously. Furthermore, soft/hard and organic/inorganic hybrid materials can be used for effective design of high performance wearable sensor by distribution control in dissimilar materials, which is attributed to effectively localized strain and large contrast of dielectric properties. Therefore, self-powered wearable sensors can be developed with functional materials, unique design and novel approach for characteristic modification, which can provide a promising platform to realize ideal wearable sensors for future applications such as daily healthcare, intelligent control, daily activity monitoring, and human-machine interface systems. In this thesis, we suggest the strategy for advanced sustainable wearable sensors with better wearing sensation, multimodality, and enhanced sensory functions through structure design and modification of material characteristics. Firstly, we briefly summarize the fundamental working principles, the latest research trends, and potential applications in Chapter 1. In Chapter 2, we demonstrate as-spun P(VDF) fiber-based self-powered textile sensors with high sensitivity, mechanical stability, and washing durability. In Chapter 3, we introduce multimodal wearable sensors without signal interference based on triboelectric and pyroelectric effect, which is attributed to controllable polarity of P(VDF-TrFE) via ferroelectric polarization. In Chapter 4, we suggest a novel method for high performance of triboelectric sensors based on alternating P(VDF-TrFE)/BaTiO3 multilayer nanocomposites, which is attributed to the efficient stress concentration and large contrast of dielectric properties. Lastly, we summarize this thesis with future prospects in Chapter 5.clos

Surface analysis of xGnP/PEI nanocomposite

Tato Diplomová práce se zabývá povrchovou analýzou nanokompozitní folie polyetherimidu (PEI) vyztuženého exfoliovanými grafitickými nanodestičkami (xGnP). Analyzovány byly take vzorky nevyztužené PEI folie a samostatné nanodestičky. Vzorky nanokompozitu a PEI folie byly plazmaticky leptány s využitím argonového plazmatu po dobu 1, 3 a 10 hod. Skenovací elektronová mikroskopie (SEM) byla použita pro charakterizaci samostatných nanodestiček rozptýlených na křemíkovém substrátu, původních či leptaných vzorků PEI folie a nanokompozitu. Nanodestičky byly identifikovány při povrchu leptané nanokompozitní folie. Mikroskopie atomárních sil (AFM) byla použita pro zobrazení povrchové topografie separovaných nanodestiček a odkrytých destiček při povrchu leptaného kompozitu. Povrchová drsnost (střední kvadratická hodnota, vzdálenost nejnižšího a nejvyššího bodu) leptaného nanokompozitu narůstala s prodlužující se dobou leptání. Akustická mikroskopie atomárních sil (AFAM) byla použita pro charakterizaci elastické anizotropie leptaných kompozitních vzorků. Nanoindentační měření umožnila charakterizaci lokálních mechanických vlastností PEI a nanokompozitních folií.This Diploma thesis deals with surface analysis of nanocomposite foil – polyetherimide matrix (PEI) reinforced by exfoliated graphite nanoplatelets (xGnP). The PEI foil without reinforcement and separate xGnP particles were also analysed. Samples of the nanocomposite and the PEI foil were etched for various times by argon plasma. Scanning electron microscopy (SEM) was used to characterize xGnP agglomerates dispersed over silicon wafer and pristine/etched samples of PEI foil and nanocomposite xGnP/PEI foil. Graphite nanoplatelets were identified at surface of etched nanocomposite foil. Atomic force microscopy (AFM) was used for surface topography imaging of separate nanoplatelets and those uncovered at the surface of etched nanocomposite. Surface roughness (root mean square, peak to peak) of etched nanocomposite increased with prolonged etching time. Atomic force acoustic microscopy (AFAM) was used to characterize elastic anisotropy of etched nanocomposite. Nanoindentation measurements were employed to characterize the local mechanical properties of PEI and nanocomposite foils.

Microfabricated tactile sensors for biomedical applications: a review

During the last decades, tactile sensors based on different sensing principles have been developed due to the growing interest in robotics and, mainly, in medical applications. Several technological solutions have been employed to design tactile sensors; in particular, solutions based on microfabrication present several attractive features. Microfabrication technologies allow for developing miniaturized sensors with good performance in terms of metrological properties (e.g., accuracy, sensitivity, low power consumption, and frequency response). Small size and good metrological properties heighten the potential role of tactile sensors in medicine, making them especially attractive to be integrated in smart interfaces and microsurgical tools. This paper provides an overview of microfabricated tactile sensors, focusing on the mean principles of sensing, i.e., piezoresistive, piezoelectric and capacitive sensors. These sensors are employed for measuring contact properties, in particular force and pressure, in three main medical fields, i.e., prosthetics and artificial skin, minimal access surgery and smart interfaces for biomechanical analysis. The working principles and the metrological properties of the most promising tactile, microfabricated sensors are analyzed, together with their application in medicine. Finally, the new emerging technologies in these fields are briefly described

Finite element modeling of dielectric elastomer actuators for space applications

A special actuator device with passive sensing capability based on dielectric elastomer was studied and specialized to be used in space applications. The work illustrates the research project modeling procedure adopted to simulate the mechanical behavior of this material based on a finite element theory approach. The Mooney-Rivlin’s hyperelastic and Maxwell’s electrostatic models provide the theoretical basis to describe its electro-mechanic behavior. The validation of the procedure is performed through a numerical-experimental correlation between the response of a prototype of actuator developed by the Risø Danish research center and the 3D finite element model simulations. An investigation concerning a possible application in the space environment of dielectric elastomer actuators (DEA) is also presented

Life cycle monitoring of composite aircraft components with structural health monitoring technologies

Life cycle monitoring could considerably improve the economy and sustainability of composite aircraft components. Knowledge about the quality of a component and its structural health allows thorough exploitation of it’s useful life and offers opportunity for optimization. Current life cycle monitoring efforts can be split in two main fields 1) process monitoring and 2) structural health monitoring with little overlap between them. This work aims to propose an integral monitoring approach, enabling entire life monitoring with the same sensor. First, the state of the art of both composite manufacturing as well as structural health monitoring technologies is presented. Piezoelectric sensors have been ruled out for further investigation due their brittleness. Fiber optical sensors and electrical property-based methods are further investigated. Distributed fiber optic sensors have been successfully used in composite manufacturing trials. Two processes were demonstrated: vacuum assisted resin transfer molding and resin infusion under flexible tooling. Due to their flexibility, optical fibers can survive the loads occurring during manufacturing and deliver valuable insights. It is shown for the first time numerically and experimentally, that fiber bed compaction levels and volume fractions can be calculated from the optical frequency shift measured by the optical fiber sensors. The same sensor was used for subsequent structural health monitoring. This proves that the gap between process monitoring and structural health monitoring can be closed with mutual benefits in both areas. The final chapter presents a novel electrical property-based sensing technique. The sensors are highly flexible and manufactured with a robot-based 3D-printing method. They are shown to reliably work as strain sensors and crack detectors. This work presents a thorough investigation of available and novel sensing technologies for process monitoring and structural health monitoring settings. The results obtained could pave the way to more efficient aircraft structures.Open Acces

The Development of a Flexible Sensor for Continuum Soft-Bodied Robots

In this thesis, we investigate, develop, and verify an approach to sense over soft and flexible materials based on the use of a tomographic technique known as Electrical Impedance Tomography

Stochastic analysis of guided wave structural health monitoring for aeronautical composites

This thesis presents new methods developed for improvement of the reliability of Guided Wave Structural Health Monitoring (GWSHM) systems for aeronautical composite. Particular attention is devoted to the detection and localisation of barely visible impact damage (BVID) in Carbon-Fibre Reinforced Polymer (CFRP) structures. A novel sensor installation method is developed that offers ease of application and replacement as well as excellent durability. Electromechanical Impedance (EMI) is used to assess the durability of the sensor installation methods in simulated aircraft operational conditions, including thermal cycles, fatigue loading and hot-wet conditions. The superiority of the developed method over existing installation methods is demonstrated through extensive tests. Damage characterisation using GWSHM is investigated in different CFRP structures. Key issues in guided wave based damage identification are addressed, including wave mode /frequency selection, the influence of dynamic load, the validity of simulated damage, sensitivity of guided wave to impact damage in different CFRP materials. Identification of barely visible impact damage (BVID) are investigated on three simple CFRP panels and two stiffened CFRP panels. BVID is detected using three different damage index and located using RAPID, Delay-and-sum, Rayleigh maximum likelihood estimation (RMLE) and Bayesian inference (BI). The influence of temperature on guided wave propagation in anisotropic CFRP structures is addressed and a novel baseline reconstruction approach for temperature compensation is proposed. The proposed temperature compensation method accommodates various sensor placement and can be established using coupon level structures for the application in larger scale structures. Finally, a multi-level hierarchical approach is proposed for the quantification of ultrasonic guided wave based structural health monitoring (GWSHM) system. The hierarchical approach provides a systemic and practical way of establishing GWSHM systems for different structures under uncertainties and assessing system performance. The proposed approach is demonstrated in aircraft CFRP structures from coupon level to sub-component level.Open Acces