6 research outputs found

    Beyond the thermodynamic limit: finite-size corrections to state interconversion rates

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    Thermodynamics is traditionally constrained to the study of macroscopic systems whose energy fluctuations are negligible compared to their average energy. Here, we push beyond this thermodynamic limit by developing a mathematical framework to rigorously address the problem of thermodynamic transformations of finite-size systems. More formally, we analyse state interconversion under thermal operations and between arbitrary energy-incoherent states. We find precise relations between the optimal rate at which interconversion can take place and the desired infidelity of the final state when the system size is sufficiently large. These so-called second-order asymptotics provide a bridge between the extreme cases of single-shot thermodynamics and the asymptotic limit of infinitely large systems. We illustrate the utility of our results with several examples. We first show how thermodynamic cycles are affected by irreversibility due to finite-size effects. We then provide a precise expression for the gap between the distillable work and work of formation that opens away from the thermodynamic limit. Finally, we explain how the performance of a heat engine gets affected when one of the heat baths it operates between is finite. We find that while perfect work cannot generally be extracted at Carnot efficiency, there are conditions under which these finite-size effects vanish. In deriving our results we also clarify relations between different notions of approximate majorisation.Comment: 31 pages, 10 figures. Final version, to be published in Quantu

    Noise in Quantum Information Processing

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    Quantum phenomena such as superposition and entanglement imbue quantum systems with information processing power in excess of their classical counterparts. These properties of quantum states are, however, highly fragile. As we enter the era of noisy intermediate-scale quantum (NISQ) devices, this vulnerability to noise is a major hurdle to the experimental realisation of quantum technologies. In this thesis we explore the role of noise in quantum information processing from two different perspectives. In Part I we consider noise from the perspective of quantum error correcting codes. Error correcting codes are often analysed with respect to simplified toy models of noise, such as iid depolarising noise. We consider generalising these techniques for analysing codes under more realistic noise models, including features such as biased or correlated errors. We also consider designing customised codes which not only take into account and exploit features of the underlying physical noise. Considering such tailored codes will be of particular importance for NISQ applications in which finite-size effects can be significant. In Part II we apply tools from information theory to study the finite-resource effects which arise in the trade-offs between resource costs and error rates for certain quantum information processing tasks. We start by considering classical communication over quantum channels, providing a refined analysis of the trade-off between communication rate and error in the regime of a finite number of channel uses. We then extend these techniques to the problem of resource interconversion in theories such as quantum entanglement and quantum thermodynamics, studying finite-size effects which arise in resource-error trade-offs. By studying this effect in detail, we also show how detrimental finite-size effects in devices such as thermal engines may be greatly suppressed by carefully engineering the underlying resource interconversion processes

    Quantum dichotomies and coherent thermodynamics beyond first-order asymptotics

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    We address the problem of exact and approximate transformation of quantum dichotomies in the asymptotic regime, i.e., the existence of a quantum channel E\mathcal E mapping ρ1n\rho_1^{\otimes n} into ρ2Rnn\rho_2^{\otimes R_nn} with an error ϵn\epsilon_n (measured by trace distance) and σ1n\sigma_1^{\otimes n} into σ2Rnn\sigma_2^{\otimes R_n n} exactly, for a large number nn. We derive second-order asymptotic expressions for the optimal transformation rate RnR_n in the small, moderate, and large deviation error regimes, as well as the zero-error regime, for an arbitrary pair (ρ1,σ1)(\rho_1,\sigma_1) of initial states and a commuting pair (ρ2,σ2)(\rho_2,\sigma_2) of final states. We also prove that for σ1\sigma_1 and σ2\sigma_2 given by thermal Gibbs states, the derived optimal transformation rates in the first three regimes can be attained by thermal operations. This allows us, for the first time, to study the second-order asymptotics of thermodynamic state interconversion with fully general initial states that may have coherence between different energy eigenspaces. Thus, we discuss the optimal performance of thermodynamic protocols with coherent inputs and describe three novel resonance phenomena allowing one to significantly reduce transformation errors induced by finite-size effects. What is more, our result on quantum dichotomies can also be used to obtain, up to second-order asymptotic terms, optimal conversion rates between pure bipartite entangled states under local operations and classical communication.Comment: 51 pages, 6 figures, comments welcom

    Catalysis of entanglement and other quantum resources

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    In chemistry, a catalyst is a substance which enables a chemical reaction or increases its rate, while remaining unchanged in the process. Instead of chemical reactions, quantum catalysis enhances our ability to convert quantum states into each other under physical constraints. The nature of the constraints depends on the problem under study, and can arise, e.g., from energy preservation. In this article we review the most recent developments of quantum catalysis, and give also a historical overview of this research direction. We focus on catalysis of quantum entanglement and coherence, and also discuss this phenomenon in quantum thermodynamics and general quantum resource theories. We review applications of quantum catalysis, and discuss also the recent efforts on universal catalysis, where the quantum state of the catalyst does not depend on the states to be transformed. Catalytic embezzling is also considered, a phenomenon which occurs if the state of the catalyst can change in the transition.Comment: 38 pages, 3 figures, comments and additional references are welcom

    Moderate deviation analysis of majorisation-based resource interconversion

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    © 2019 IEEE. We consider the problem of interconverting a finite amount of resources within all theories whose single-shot transformation rules are based on a majorisation relation, e.g. the resource theories of entanglement and coherence (for pure state transformations), as well as thermodynamics (for energy-incoherent transformations). When only finite resources are available we expect to see a non-trivial trade-off between the rate rn at which n copies of a resource state ρ can be transformed into nrn copies of another resource state σ, and the error level ϵn of the interconversion process, as a function of n. In this work we derive the optimal trade-off in the so-called moderate deviation regime, where the rate of interconversion rn approaches its optimum in the asymptotic limit of unbounded resources (n → ∞), while the error ϵn vanishes in the same limit. We find that the moderate deviation analysis exhibits a resonance behaviour which implies that certain pairs of resource states can be interconverted at the asymptotically optimal rate with negligible error, even in the finite n regime
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