6,946 research outputs found
Designing carbon fibre-reinforced composites with improved structural retention on exposure to heat/fire
Carbon fibre-reinforced composites (CFRCs) are increasing in popularity due to their high
strength-to-weight ratio and resistance to corrosion. However, when exposed to temperatures
above 300°C, the polymer matrix within CFRCs decomposes and then starts burning, exposing
carbon fibres to the surroundings. The residual carbon fibres being electrically conductive, may
pose a hazard to the surrounding electronics. Moreover, at over 550°C the carbon fibres begin
to oxidise. This can lead to fibre defibrillation which also poses significant harm to human health
as broken fibres can be sharp enough to cut through human skin, and under 7µm these particles
are considered respirable where on inhalation they can causes damage to the trachea and lungs.
While considerable work has been carried out on assessing the effect of heat/fire on degradation
of the composite resin (matrix) and CFRCs themselves, there are limited studies on identifying
the damage to carbon fibres within CFRCs and the hazards posed by the exposed damaged
carbon fibres. This study examined the damage caused by high temperatures, radiant heat and
flames on carbon fibres and CFRCs, and the effects on their physical properties. A methodology
was developed to study and quantify the structural damage to carbon fibres and CFRCs after
exposure to a range of heat/fire conditions. These included thermogravimetric analysis (up to
900oC in nitrogen and air atmospheres), the tube furnace (450oC–900oC), cone calorimeter
(35kWm-2
to 75kWm-2
) and a propane burner (116kWm-2
) to simulate jet fuel fire conditions.
Residual fibres were removed from different parts of the CFRCs and the physical properties
were studied, such as fibre diameter reduction, change in electrical conductivity and decrease in
tensile strength. It was found that at heat fluxes ≥60kWm-2
oxidation of the carbon fibres
occurred. After 10min exposure to the propane flame, fibres in direct contact with the flame
showed signs of internal oxidation.The aim of this PhD project was to also improve the structural retention of CFRCs on exposure
to heat/fire so that the structural integrity is maintained and the carbon fibres are not exposed to
the environment. To address this, the following approaches were undertaken:
• Modification of the resin by adding flame retardants and nanoparticles in order to reduce the
flammability of CFRCs, improve the mechanical integrity of the char and its adherence to the fibre. Flame retardants included ammonium polyphosphate, resorcinol bis-(diphenyl
phosphate), 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide, and the nano-additives,
nano-clay, layered double hydroxide and carbon nano-tubes. Cone calorimeter testing at
75kWm-2 showed that the addition of 15wt% ammonium polyphosphate resulted in large char
formation and adherence to fibres in the underlying plies, which resulted in less oxidation to
these carbon fibres. The addition of layered double hydroxides and carbon nano-tubes on the
other hand caused pitting on fibres.
• Provide heat protection to carbon fibres within CFRCs by the inclusion of high performance
fibrous veils/woven fabrics of aramid, basalt, E-glass, polyphenylene sulphide and Kevlar.
The inclusion of the woven E-glass resulted in a notable reduction in the percentage of carbon
fibre oxidised. However, the volatiles produced during the decomposition of Kevlar and PPS
sensitised the carbon fibre to oxidation, causing it to occur more rapidly and at a lower
temperature.
• Using high temperature chemical coatings to individually coat carbon fibres prior to making
the CFRCs. Ceramic compounds (silica, alumina and zirconia), chosen as coating materials
because of their high thermal stability, were applied by different processes. The most
promising coatings included alumina and silica formed via sol-gel process and polysiloxane
deposited during plasma exposure. Tows coated in these chemicals underwent heat testing in
a tube furnace where those coated with alumina maintained the largest fibre diameters. While
polysiloxane coating provided oxidation protection up to 600°C, after which cracks in the
coating were observed. This was attributed to the mechanical mismatch of the polysiloxane
coating and the carbon fibre
The Effects of Salt Precipitation During CO2 Injection into Deep Saline Aquifer and Remediation Techniques
The by-products of combustion from the utilisation of fossil fuels for energy generation are a source of greenhouse gas emissions, mainly Carbon dioxide (CO2). This has been attributed to climate change because of global warming. Carbon capture and storage (CCS) technology has the potential to reduce anthropogenic greenhouse gas emissions by capturing CO2 from emissions sources and stored in underground formations such as depleted oil and gas reservoirs or deep saline formations. Deep saline aquifers for disposal of greenhouse gases are attracting much attention as a result of their large storage capacity. The problem encountered during CO2 trapping in the saline aquifer is the vaporisation of water along with the dissolution of CO2. This vaporisation cause salt precipitation which eventually reduces porosity and impairs the permeability of the reservoir thereby impeding the storage capacity and efficiency of the technology. Salt precipitation during CO2 storage in deep saline aquifers can have severe consequences during carbon capture and storage operations in terms of CO2 injectivity.This work investigates and assesses, experimentally, the effects of the presence of salt precipitation on the CO2 injectivity, the factors that influence them on selected core samples by core flooding experiments, and remediation of salt precipitation during CO2 injection. The investigation also covered the determination of optimum range of deep saline aquifers for CO2 storage, and the effects of different brine-saturated sandstones during CO2 sequestration in deep saline aquifers. In this investigation, three (3) different sandstone core samples (Bentheimer, Salt Wash North, and Grey Berea) with different petrophysical properties were used for the study. This is carried out in three different phases for a good presentation.• Phase I of this study involved brine preparation and measurement of brine properties such as brine salinity, viscosity, and density. The brine solutions were prepared from different salts (NaCl, CaCl2, KCl, MgCl2), which represent the salt composition of a typical deep saline aquifer. The core samples were saturated with different brine salinities (5, 10, 15, 20, 25, wt.% Salt) and testing was conducted using the three selected core samples.• Phase II entailed the cleaning and characterisation of the core samples by experimental core analyses to determine the petrophysical properties: porosity and permeability. Helium Porosimetry and saturation methods were used for porosity determination. Core flooding was used to determine the permeability of the core samples. The core flooding process was conducted at a simulated reservoir pressure of 1500 psig, the temperature of 45 °C, with injection rates of 3.0 ml/min respectively. Interfacial tension (IFT) measurements between the CO2 and various brine salinities as used in the core flooding were also conducted in this phase. Remediation scenarios of opening the pore spaces of the core samples were carried out using the same core flooding rig and the precipitated core samples were flooded with remediation fluids (low salinity brine and seawater) under the same reservoir conditions. The petrophysical properties (Porosity, Permeability) of the core samples were measured before core flooding, after core flooding and remediation test respectively.• In phase III of the study, SEM Image analyses were conducted on the core samples before core flooding, after core flooding, and remediation test respectively. This was achieved by using the FEI Quanta FEG 250 FEG high-resolution Scanning Electron Microscope (SEM) interfaced to EDAX Energy Dispersive X-ray Analysis (EDX).xivResults from Bentheimer, Salt Wash North, and Grey Berea core samples indicated a reduction in porosity, permeability impairment, as well as salt precipitation. It was also found that, at 10 to 20 wt.% brine concentrations in both monovalent and divalent brine, a substantial volume of CO2 is sequestered, which indicates the optimum concentration ranges for storage purposes. The salting-out effect was greater in divalent salt, MgCl2 and CaCl2 as compared to monovalent salt (NaCl and KCl). Porosity decreased by 0.5% to 7% while permeability was decreased by up to 50% in all the tested scenarios. CO2 solubility was evaluated in a pressure decay test, which in turn affects injectivity. Hence, the magnitude of CO2 injectivity impairment depends on both the concentration and type of salt species. The findings from this study are directly relevant to CO2 sequestration in deep saline aquifers as well as screening criteria for carbon storage with enhanced gas and oil recovery processes. Injection of remediation fluids during remediation tests effectively opened the pore spaces and pore throats of the core samples and thereby increasing the core sample's porosity in the range of 14.0% to 28.5% and 2.2% to 12.9% after using low salinity brine and seawater remediation fluids respectively. Permeability also increases in the range of 40.6% to 68.4% and 7.4% to 17.2% after using low salinity brine and seawater remediation fluids respectively. These findings provide remediation strategies useful in dissolving precipitated salt as well as decreasing the salinity of the near-well brine which causes precipitation.The SEM images of the core samples after the flooding showed that salt precipitation not only plugged the pore spaces of the core matrix but also showed significant precipitation around the rock grains thereby showing an aggregation of the salts. This clearly proved that the reduction in the capacity of the rock is associated with salt precipitation in the pore spaces as well as the pore throats. Thus, insight gained in this study could be useful in designing a better mitigation technique, CO2 injectivity scenarios, as well as an operating condition for CO2 sequestration in deep saline aquifers
Feature Papers in Compounds
This book represents a collection of contributions in the field of the synthesis and characterization of chemical compounds, natural products, chemical reactivity, and computational chemistry. Among its contents, the reader will find high-quality, peer-reviewed research and review articles that were published in the open access journal Compounds by members of the Editorial Board and the authors invited by the Editorial Office and Editor-in-Chief
Measurement of the Environmental Impact of Materials
Throughout their life cycles—from production, usage, through to disposal—materials and products interact with the environment (water, soil, and air). At the same time, they are exposed to environmental influences and, through their emissions, have an impact on the environment, people, and health. Accelerated experimental testing processes can be used to predict the long-term environmental consequences of innovative products before these actually enter the environment. We are living in a material world. Building materials, geosynthetics, wooden toys, soil, nanomaterials, composites, wastes and more are research subjects examined by the authors of this book. The interactions of materials with the environment are manifold. Therefore, it is important to assess the environmental impact of these interactions. Some answers to how this task can be achieved are given in this Special Issue
The role of exports in manufacturing pollution in sub–Saharan Africa and South Asia: towards a better trade-environment governance
Based on the gaps and challenges identified through case studies, the report proposes recommendations for
Kenya, the United Republic of Tanzania, Bangladesh, and Pakistan along with the main three areas of research:
(i) Environmental Law and Public Governance, (ii) Private Sector Governance, and (iii) Life Cycle Assessment.
Even though at different stages, the four countries are building diversified economies by developing their industrial sectors. As exports play a significant role in their economic growth, those countries gain from more sustainable manufacturing practices
Anuário científico da Escola Superior de Tecnologia da Saúde de Lisboa - 2021
É com grande prazer que apresentamos a mais recente edição (a 11.ª) do Anuário Científico da Escola Superior de Tecnologia da Saúde de Lisboa. Como instituição de ensino superior, temos o compromisso de promover e incentivar a pesquisa científica em todas as áreas do conhecimento que contemplam a nossa missão. Esta publicação tem como objetivo divulgar toda a produção científica desenvolvida pelos Professores, Investigadores, Estudantes e Pessoal não Docente da ESTeSL durante 2021. Este Anuário é, assim, o reflexo do trabalho árduo e dedicado da nossa comunidade, que se empenhou na produção de conteúdo científico de elevada qualidade e partilhada com a Sociedade na forma de livros, capítulos de livros, artigos publicados em revistas nacionais e internacionais, resumos de comunicações orais e pósteres, bem como resultado dos trabalhos de 1º e 2º ciclo. Com isto, o conteúdo desta publicação abrange uma ampla variedade de tópicos, desde temas mais fundamentais até estudos de aplicação prática em contextos específicos de Saúde, refletindo desta forma a pluralidade e diversidade de áreas que definem, e tornam única, a ESTeSL. Acreditamos que a investigação e pesquisa científica é um eixo fundamental para o desenvolvimento da sociedade e é por isso que incentivamos os nossos estudantes a envolverem-se em atividades de pesquisa e prática baseada na evidência desde o início dos seus estudos na ESTeSL. Esta publicação é um exemplo do sucesso desses esforços, sendo a maior de sempre, o que faz com que estejamos muito orgulhosos em partilhar os resultados e descobertas dos nossos investigadores com a comunidade científica e o público em geral. Esperamos que este Anuário inspire e motive outros estudantes, profissionais de saúde, professores e outros colaboradores a continuarem a explorar novas ideias e contribuir para o avanço da ciência e da tecnologia no corpo de conhecimento próprio das áreas que compõe a ESTeSL. Agradecemos a todos os envolvidos na produção deste anuário e desejamos uma leitura inspiradora e agradável.info:eu-repo/semantics/publishedVersio
Proceedings of FORM 2022. Construction The Formation of Living Environment
This study examines the integration of building information modelling (BIM) technologies in operation & maintenance stage in the system of managing real estate that helps to reduce transaction costs. The approach and method are based on Digital Twin technology and Model Based System Engineering (MBSE) approach.
The results of the development of a service for digital facility management and
digital expertise are presented. The connection between physical and digital objects is conceptualized
Influence of local PO₂ on skeletal muscle microvascular blood flow during hyperinsulinemia
The goal of this thesis was to test the hypothesis that insulin mediated hyperemia is partially dependent on local muscle oxygen concentration. To do so, microvascular blood flow was measured in response to varying imposed concentrations of oxygen in rat skeletal muscle. Sprague-Dawley rats were anesthetized, and the extensor digitorum longus (EDL) was reflected onto an inverted microscope. Intravital video microscopy sequences were recorded during baseline and hyperinsulinemic euglycemia. The muscle was reflected over a glass stage insert (Experiment 1a and 1b), or over a gas exchange chamber (Experiment 2), and microvascular capillary blood flow was recorded during sequential changes (7%-12%-2%-7%) of oxygen (O₂) concentration. Blood flow was measured by the red blood cell supply rate (SR) in number of cells per second. In Experiment 1a, supply rate (SR) increased from 8.0 to 14 cells/s at baseline to euglycemia (p = 0.01), while no significant SR variation was detected after performing a sham hyperinsulinemic euglycemic clamp (Experiment 1b). In Experiment 2, SR decreased at 12% O₂ and increased at 2% O₂, compared to 7% O₂, under both experimental conditions. SR responses to oxygen square wave oscillations during euglycemia were not different to those at baseline at each O₂ concentration (p > 0.9). Our results suggest the increase in blood flow observed in response to insulin is eliminated if tissue oxygen microenvironment is clamped at given oxygen concentrations.
All animal protocols were approved by Memorial University’s Institutional Animal Care Committee
Towards A Graphene Chip System For Blood Clotting Disease Diagnostics
Point of care diagnostics (POCD) allows the rapid, accurate measurement of analytes near to a patient. This enables faster clinical decision making and can lead to earlier diagnosis and better patient monitoring and treatment. However, despite many prospective POCD devices being developed for a wide range of diseases this promised technology is yet to be translated to a clinical setting due to the lack of a cost-effective biosensing platform.This thesis focuses on the development of a highly sensitive, low cost and scalable biosensor platform that combines graphene with semiconductor fabrication tech-niques to create graphene field-effect transistors biosensor. The key challenges of designing and fabricating a graphene-based biosensor are addressed. This work fo-cuses on a specific platform for blood clotting disease diagnostics, but the platform has the capability of being applied to any disease with a detectable biomarker.Multiple sensor designs were tested during this work that maximised sensor ef-ficiency and costs for different applications. The multiplex design enabled different graphene channels on the same chip to be functionalised with unique chemistry. The Inverted MOSFET design was created, which allows for back gated measurements to be performed whilst keeping the graphene channel open for functionalisation. The Shared Source and Matrix design maximises the total number of sensing channels per chip, resulting in the most cost-effective fabrication approach for a graphene-based sensor (decreasing cost per channel from £9.72 to £4.11).The challenge of integrating graphene into a semiconductor fabrication process is also addressed through the development of a novel vacuum transfer method-ology that allows photoresist free transfer. The two main fabrication processes; graphene supplied on the wafer “Pre-Transfer” and graphene transferred after met-allisation “Post-Transfer” were compared in terms of graphene channel resistance and graphene end quality (defect density and photoresist). The Post-Transfer pro-cess higher quality (less damage, residue and doping, confirmed by Raman spec-troscopy).Following sensor fabrication, the next stages of creating a sensor platform involve the passivation and packaging of the sensor chip. Different approaches using dielec-tric deposition approaches are compared for passivation. Molecular Vapour Deposi-tion (MVD) deposited Al2O3 was shown to produce graphene channels with lower damage than unprocessed graphene, and also improves graphene doping bringing the Dirac point of the graphene close to 0 V. The packaging integration of microfluidics is investigated comparing traditional soft lithography approaches and the new 3D printed microfluidic approach. Specific microfluidic packaging for blood separation towards a blood sampling point of care sensor is examined to identify the laminar approach for lower blood cell count, as a method of pre-processing the blood sample before sensing.To test the sensitivity of the Post-Transfer MVD passivated graphene sensor de-veloped in this work, real-time IV measurements were performed to identify throm-bin protein binding in real-time on the graphene surface. The sensor was function-alised using a thrombin specific aptamer solution and real-time IV measurements were performed on the functionalised graphene sensor with a range of biologically relevant protein concentrations. The resulting sensitivity of the graphene sensor was in the 1-100 pg/ml concentration range, producing a resistance change of 0.2% per pg/ml. Specificity was confirmed using a non-thrombin specific aptamer as the neg-ative control. These results indicate that the graphene sensor platform developed in this thesis has the potential as a highly sensitive POCD. The processes developed here can be used to develop graphene sensors for multiple biomarkers in the future
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