Ultrafast Hot Carrier Dynamics in GaN and its Impact on the Efficiency Droop

GaN is a key material for lighting technology. Yet, the carrier transport and ultrafast dynamics that are central in GaN light emitting devices are not completely understood. We present first-principles calculations of carrier dynamics in GaN, focusing on electron-phonon (e-ph) scattering and the cooling and nanoscale dynamics of hot carriers. We find that e-ph scattering is significantly faster for holes compared to electrons, and that for hot carriers with an initial 0.5$-$1 eV excess energy, holes take a significantly shorter time ($\sim$0.1 ps) to relax to the band edge compared to electrons, which take $\sim$1 ps. The asymmetry in the hot carrier dynamics is shown to originate from the valence band degeneracy, the heavier effective mass of holes compared to electrons, and the details of the coupling to different phonon modes in the valence and conduction bands. We show that the slow cooling of hot electrons and their long ballistic mean free paths (over 3 nm) are a possible cause of efficiency droop in GaN light emitting diodes. Taken together, our work sheds light on the ultrafast dynamics of hot carriers in GaN and the nanoscale origin of efficiency droop.Comment: Submitted, 10 pages, 4 figure

The effect of pressure on open-framework silicates: elastic behaviour and crystal-fluid interaction

The elastic behaviour and the structural evolution of microporous materials compressed hydrostatically in a pressure-transmitting fluid are drastically affected by the potential crystal-fluid interaction, with a penetration of new molecules through the zeolitic cavities in response to applied pressure. In this manuscript, the principal mechanisms that govern the P-behaviour of zeolites with and without crystal-fluid interaction are described, on the basis of previous experimental findings and computational modelling studies. When no crystal-fluid interaction occurs, the effects of pressure are mainly accommodated by tilting of (quasi-rigid) tetrahedra around O atoms that behave as hinges. Tilting of tetrahedra is the dominant mechanism at low-mid P-regime, whereas distortion and compression of tetrahedra represent the mechanisms which usually dominate the mid-high P regime. One of the most common deformation mechanisms in zeolitic framework is the increase of channels ellipticity. The deformation mechanisms are dictated by the topological configuration of the tetrahedral framework; however, the compressibility of the cavities is controlled by the nature and bonding configuration of the ionic and molecular content, resulting in different unit-cell volume compressibility in isotypic structures. The experimental results pertaining to compression in "penetrating" fluids, and thus with crystal-fluid interaction, showed that not all the zeolites experience a P-induced intrusion of new monoatomic species or molecules from the P-transmitting fluids. For example, zeolites with well-stuffed channels at room conditions (e.g. natural zeolites) tend to hinder the penetration of new species through the zeolitic cavities. Several variables govern the sorption phenomena at high pressure, among those: the "free diameters" of the framework cavities, the chemical nature and the configuration of the extra-framework population, the partial pressure of the penetrating molecule in the fluid (if mixed with other non-penetrating molecules), the rate of P-increase, the surface/volume ratio of the crystallites under investigations and the temperature at which the experiment is conducted. An overview of the intrusion phenomena of monoatomic species (e.g. He, Ar, Kr), small (e.g. H2O, CO2) and complex molecules, along with the P-induced polymerization phenomena (e.g. C2H2, C2H4, C2H6O, C2H6O2, BNH6, electrolytic MgCl2*21H2O solution) is provided, with a discussion of potential technological and geological implications of these experimental findings

Evaluation of performance of mobile terminal antennas

Fast development of new mobile communications equipment results in demand for fast and reliable evaluation methods to estimate the performance of mobile terminals because the performance of antennas located on the terminals varies in different multipath propagation environments. Two methods presented in this thesis provide new possibilities in antenna design because, from now on, the performance of new antennas can be tested already before a prototype antenna is constructed by using existing radio channel libraries and simulated radiation patterns of the antennas. The performance can be estimated by calculating the mean effective gain (MEG) of the antenna using the elevation power distribution or by a plane wave -based method using sets of incident plane waves and the radiation pattern of an antenna. In addition to different propagation environments, the effects of the user on performance can be included in the evaluation. In this thesis, estimating the MEG of different antennas using the elevation power distribution and the power patterns of the antennas is shown to be an accurate and fast method by comparing the results with direct radio channel measurements. The mean difference between the methods is −0.18 dB with standard deviation of 0.19 dB. The usefulness of the evaluation method is demonstrated by evaluating the performance of several antennas located on mobile terminals. The antenna evaluation provided important and unique knowledge of the effect of both the environment and the user on performance. Because in calculating the radiation efficiency of the antenna we assume uniform incident field, the efficiency can result in a performance estimation that does not correspond to real usage situations. Therefore, including the environmental effects in the evaluation procedure is important, although the effect of the antenna is more important than the effect of the environment on MEG. It was noticed with calculated Gaussian-shaped beams that tilting or changing the beamwidth of a mobile terminal antenna has an effect of about 2 dB on MEG in multipath environments. Matching the polarization of the antenna to that of the environment can improve the performance more. A novel incident plane wave -based tool has been developed for evaluating the performance of antenna configurations designed for diversity and Multiple-Input Multiple-Output (MIMO) systems. In this thesis, the instantaneous joint contribution of incident field consisting of a number of extracted plane waves and the complex three-dimensional radiation pattern of the antenna is shown to be accurate and extremely fast way to estimate the diversity advantages of different antenna configurations in time-variable radio channels. The difference between the diversity gains achieved by the plane wave -based method and by the direct radio channel measurements is on average less than 0.9 dB. Moreover, the radio channel can be exactly the same for all antenna configurations under test. Furthermore, this thesis includes evaluation of the performance of different MIMO antenna configurations. The studied antenna configurations have been selected from the 16×64 MIMO channel measurement data. A novel way of using one omnidirectional reference antenna in a normalization procedure is shown to be reasonable especially in cases of antenna arrays consisting of directive elements. Three different propagation environments are used as evaluation platforms. The azimuth orientation of mobile terminal antennas may influence the performance of a MIMO antenna configuration significantly. In MIMO configurations compact dual-polarized receiving antennas provide capacity performance almost equal to the arrays employing single polarization.reviewe