837 research outputs found

    PGM-Free Biomass-Derived Electrocatalysts for Oxygen Reduction in Energy Conversion Devices: Promising Materials

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    Biomass is a low-cost, abundant and renewable resource that can be used to manufacture porous carbon-based materials for a variety of applications. Different mesoporous carbon supports can be obtained from the various synthetic approaches that are aimed at increasing the specific surface area and functionalization. Currently, most of the biomass is used for energy recovery. The circular economy approach could lead to the development of cheap and sustainable materials, and turning of wastes into a precious resource. In this review, we provide the recent advances in the field of electrochemistry for porous carbon materials derived from biomass, which offers wider applications in proton exchange membrane fuel cells (PEMFCs), anion exchange membrane fuel cells (AEMFCs) and Zn-air batteries (ZABs). The focus is on understanding the required properties of the materials and the role of synthetic pathways in platinum group metal (PGM) free electrocatalysts. The most promising materials are evaluated towards the oxygen reduction reaction (ORR) in PEMFC, AEMFC, and ZAB. The results achieved showed that the expected performances on these energy conversion devices still lack for deployment in practice, especially if compared with commercially available PGM-free electrocatalysts. This review article provides insights on how to improve the actual electrocatalytic activity of biomass-derived materials. Graphical Abstract: [Figure not available: see fulltext.

    30th European Congress on Obesity (ECO 2023)

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    This is the abstract book of 30th European Congress on Obesity (ECO 2023

    Challenges in the Design and Implementation of IoT Testbeds in Smart-Cities : A Systematic Review

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    Advancements in wireless communication and the increased accessibility to low-cost sensing and data processing IoT technologies have increased the research and development of urban monitoring systems. Most smart city research projects rely on deploying proprietary IoT testbeds for indoor and outdoor data collection. Such testbeds typically rely on a three-tier architecture composed of the Endpoint, the Edge, and the Cloud. Managing the system's operation whilst considering the security and privacy challenges that emerge, such as data privacy controls, network security, and security updates on the devices, is challenging. This work presents a systematic study of the challenges of developing, deploying and managing urban monitoring testbeds, as experienced in a series of urban monitoring research projects, followed by an analysis of the relevant literature. By identifying the challenges in the various projects and organising them under the V-model development lifecycle levels, we provide a reference guide for future projects. Understanding the challenges early on will facilitate current and future smart-cities IoT research projects to reduce implementation time and deliver secure and resilient testbeds

    Intégration des méthodes formelles dans le développement des RCSFs

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    In this thesis, we have relied on formal techniques in order to first evaluate WSN protocols and then to propose solutions that meet the requirements of these networks. The thesis contributes to the modelling, analysis, design and evaluation of WSN protocols. In this context, the thesis begins with a survey on WSN and formal verification techniques. Focusing on the MAC layer, the thesis reviews proposed MAC protocols for WSN as well as their design challenges. The dissertation then proceeds to outline the contributions of this work. As a first proposal, we develop a stochastic generic model of the 802.11 MAC protocol for an arbitrary network topology and then perform probabilistic evaluation of the protocol using statistical model checking. Considering an alternative power source to operate WSN, energy harvesting, we move to the second proposal where a protocol designed for EH-WSN is modelled and various performance parameters are evaluated. Finally, the thesis explores mobility in WSN and proposes a new MAC protocol, named "Mobility and Energy Harvesting aware Medium Access Control (MEH-MAC)" protocol for dynamic sensor networks powered by ambient energy. The protocol is modelled and verified under several features

    Energy-Sustainable IoT Connectivity: Vision, Technological Enablers, Challenges, and Future Directions

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    Technology solutions must effectively balance economic growth, social equity, and environmental integrity to achieve a sustainable society. Notably, although the Internet of Things (IoT) paradigm constitutes a key sustainability enabler, critical issues such as the increasing maintenance operations, energy consumption, and manufacturing/disposal of IoT devices have long-term negative economic, societal, and environmental impacts and must be efficiently addressed. This calls for self-sustainable IoT ecosystems requiring minimal external resources and intervention, effectively utilizing renewable energy sources, and recycling materials whenever possible, thus encompassing energy sustainability. In this work, we focus on energy-sustainable IoT during the operation phase, although our discussions sometimes extend to other sustainability aspects and IoT lifecycle phases. Specifically, we provide a fresh look at energy-sustainable IoT and identify energy provision, transfer, and energy efficiency as the three main energy-related processes whose harmonious coexistence pushes toward realizing self-sustainable IoT systems. Their main related technologies, recent advances, challenges, and research directions are also discussed. Moreover, we overview relevant performance metrics to assess the energy-sustainability potential of a certain technique, technology, device, or network and list some target values for the next generation of wireless systems. Overall, this paper offers insights that are valuable for advancing sustainability goals for present and future generations.Comment: 25 figures, 12 tables, submitted to IEEE Open Journal of the Communications Societ

    Early prediction of Lithium-ion cell degradation trajectories using signatures of voltage curves up to 4-minute sub-sampling rates

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    Feature-based machine learning models for capacity and internal resistance (IR) curve prediction have been researched extensively in literature due to their high accuracy and generalization power. Most such models work within the high frequency of data availability regime, e.g., voltage response recorded every 1–4 s. Outside premium fee cloud monitoring solutions, data may be recorded once every 3, 5 or 10 min. In this low-data regime, there are little to no models available. This literature gap is addressed here via a novel methodology, underpinned by strong mathematical guarantees, called ‘path signature’. This work presents a feature-based predictive model for capacity fade and IR rise curves from only constant-current (CC) discharge voltage corresponding to the first 100 cycles. Included is a comprehensive feature analysis for the model via a relevance, redundancy, and complementarity feature trade-off mechanism. The ability to predict from subsampled ‘CC voltage at discharge’ data is investigated using different time steps ranging from 4 s to 4 min. It was discovered that voltage measurements taken at the end of every 4 min are enough to generate features for curve prediction with End of Life (EOL) and its corresponding IR values predicted with a mean absolute percentage error (MAPE) of approximately 13.2% and 2.1%, respectively. Our model under higher frequency (4 s) produces an improved accuracy with EOL predicted with an MAPE of 10%. Full implementation code publicly available

    Identification and characterization of N-degron pathways

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    MAC protokol adaptivnog faktora ispune zasnovan na predviđanju u bežičnim senzorskim mrežama sa prikupljanjem solarne energije

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    Harvesting ambient energy has enabled the development of energy-harvesting wireless sensor networks (EH-WSNs). However, in these networks, the uncertainty in harvesting rate due to dynamic weather conditions raises new challenges. Therefore, this drives the development of energy harvesting-aware solutions. Formerly, many MAC protocols have been developed for EH-WSNs, which offer various features based on available harvested energy to support different applications. Nevertheless, optimizing MAC performance by incorporating predicted future energy intake is relatively new in EH-WSNs. Therefore, this thesis presents a machine learning prediction based adaptive duty cycle medium access control (MAC) protocol for solar energy harvesting wireless sensor networks WSNs. The developed protocol incorporates information about the current and future harvested energy using mathematical formulations to improve network performance. By doing so, the proposed MAC protocol effectively addresses the primary goals of solar energy harvesting WSNs: ensuring long-term network sustainability and efficient utilization of harvested energy to enhance the application performance under dynamically changing energy harvesting conditions.Сакупљање амбијенталне енергије омогућило је развој бежичних сензорских мрежа (EH-WSN) за прикупљање енергије. Међутим, у овим мрежама, неизвесност у стопи жетве услед динамичних временских услова поставља нове изазове. Стога, ово покреће развој решења која су свесна прикупљања енергије. Раније су развијени многи MAC протоколи за EH-WSN, који нуде различите карактеристике засноване на доступној прикупљеној енергији за подршку различитим апликацијама. Ипак, оптимизација перформанси MAC-а укључивањем предвиђеног будућег уноса енергије је релативно нова у EH-WSN-овима. Стога, ова теза представља протокол адаптивног радног циклуса за контролу приступа медијуму (MAC) заснован на предвиђању заснованом на машинском учењу за бежичне WSN мреже за прикупљање соларне енергије. Развијени протокол укључује информације о тренутној и будућој прикупљеној енергији користећи математичке формулације за побољшање перформанси мреже. На тај начин, предложени MAC протокол ефикасно се бави примарним циљевима WSN-а за прикупљање соларне енергије: обезбеђивање дугорочне одрживости мреже и ефикасно коришћење прикупљене енергије за побољшање перформанси апликације под динамички променљивим условима прикупљања енергије.Sakupljanje ambijentalne energije omogućilo je razvoj bežičnih senzorskih mreža (EH-WSN) za prikupljanje energije. Međutim, u ovim mrežama, neizvesnost u stopi žetve usled dinamičnih vremenskih uslova postavlja nove izazove. Stoga, ovo pokreće razvoj rešenja koja su svesna prikupljanja energije. Ranije su razvijeni mnogi MAC protokoli za EH-WSN, koji nude različite karakteristike zasnovane na dostupnoj prikupljenoj energiji za podršku različitim aplikacijama. Ipak, optimizacija performansi MAC-a uključivanjem predviđenog budućeg unosa energije je relativno nova u EH-WSN-ovima. Stoga, ova teza predstavlja protokol adaptivnog radnog ciklusa za kontrolu pristupa medijumu (MAC) zasnovan na predviđanju zasnovanom na mašinskom učenju za bežične WSN mreže za prikupljanje solarne energije. Razvijeni protokol uključuje informacije o trenutnoj i budućoj prikupljenoj energiji koristeći matematičke formulacije za poboljšanje performansi mreže. Na taj način, predloženi MAC protokol efikasno se bavi primarnim ciljevima WSN-a za prikupljanje solarne energije: obezbeđivanje dugoročne održivosti mreže i efikasno korišćenje prikupljene energije za poboljšanje performansi aplikacije pod dinamički promenljivim uslovima prikupljanja energije

    MAC protokol adaptivnog faktora ispune zasnovan na predviđanju u bežičnim senzorskim mrežama sa prikupljanjem solarne energije

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    Harvesting ambient energy has enabled the development of energy-harvesting wireless sensor networks (EH-WSNs). However, in these networks, the uncertainty in harvesting rate due to dynamic weather conditions raises new challenges. Therefore, this drives the development of energy harvesting-aware solutions. Formerly, many MAC protocols have been developed for EH-WSNs, which offer various features based on available harvested energy to support different applications. Nevertheless, optimizing MAC performance by incorporating predicted future energy intake is relatively new in EH-WSNs. Therefore, this thesis presents a machine learning prediction based adaptive duty cycle medium access control (MAC) protocol for solar energy harvesting wireless sensor networks WSNs. The developed protocol incorporates information about the current and future harvested energy using mathematical formulations to improve network performance. By doing so, the proposed MAC protocol effectively addresses the primary goals of solar energy harvesting WSNs: ensuring long-term network sustainability and efficient utilization of harvested energy to enhance the application performance under dynamically changing energy harvesting conditions.Сакупљање амбијенталне енергије омогућило је развој бежичних сензорских мрежа (EH-WSN) за прикупљање енергије. Међутим, у овим мрежама, неизвесност у стопи жетве услед динамичних временских услова поставља нове изазове. Стога, ово покреће развој решења која су свесна прикупљања енергије. Раније су развијени многи MAC протоколи за EH-WSN, који нуде различите карактеристике засноване на доступној прикупљеној енергији за подршку различитим апликацијама. Ипак, оптимизација перформанси MAC-а укључивањем предвиђеног будућег уноса енергије је релативно нова у EH-WSN-овима. Стога, ова теза представља протокол адаптивног радног циклуса за контролу приступа медијуму (MAC) заснован на предвиђању заснованом на машинском учењу за бежичне WSN мреже за прикупљање соларне енергије. Развијени протокол укључује информације о тренутној и будућој прикупљеној енергији користећи математичке формулације за побољшање перформанси мреже. На тај начин, предложени MAC протокол ефикасно се бави примарним циљевима WSN-а за прикупљање соларне енергије: обезбеђивање дугорочне одрживости мреже и ефикасно коришћење прикупљене енергије за побољшање перформанси апликације под динамички променљивим условима прикупљања енергије.Sakupljanje ambijentalne energije omogućilo je razvoj bežičnih senzorskih mreža (EH-WSN) za prikupljanje energije. Međutim, u ovim mrežama, neizvesnost u stopi žetve usled dinamičnih vremenskih uslova postavlja nove izazove. Stoga, ovo pokreće razvoj rešenja koja su svesna prikupljanja energije. Ranije su razvijeni mnogi MAC protokoli za EH-WSN, koji nude različite karakteristike zasnovane na dostupnoj prikupljenoj energiji za podršku različitim aplikacijama. Ipak, optimizacija performansi MAC-a uključivanjem predviđenog budućeg unosa energije je relativno nova u EH-WSN-ovima. Stoga, ova teza predstavlja protokol adaptivnog radnog ciklusa za kontrolu pristupa medijumu (MAC) zasnovan na predviđanju zasnovanom na mašinskom učenju za bežične WSN mreže za prikupljanje solarne energije. Razvijeni protokol uključuje informacije o trenutnoj i budućoj prikupljenoj energiji koristeći matematičke formulacije za poboljšanje performansi mreže. Na taj način, predloženi MAC protokol efikasno se bavi primarnim ciljevima WSN-a za prikupljanje solarne energije: obezbeđivanje dugoročne održivosti mreže i efikasno korišćenje prikupljene energije za poboljšanje performansi aplikacije pod dinamički promenljivim uslovima prikupljanja energije

    Applications

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    Volume 3 describes how resource-aware machine learning methods and techniques are used to successfully solve real-world problems. The book provides numerous specific application examples: in health and medicine for risk modelling, diagnosis, and treatment selection for diseases in electronics, steel production and milling for quality control during manufacturing processes in traffic, logistics for smart cities and for mobile communications
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