Surface and inter-phase analysis of Composite Materials using Electromagnetic Techniques based on SQUID Sensors

In this thesis an electromagnetic characterization and a non-destructive evaluation of new advanced composite materials, Carbon Fiber Reinforced Polymers (CFRP) and Fiber-Glass Aluminium (FGA) laminates, using an eddy-current technique based on HTS dc-SQUID (Superconductive QUantum Interference Device) magnetometer is proposed. The main goal of this thesis is to propose a prototype based on a superconducting sensor, such as SQUID, to guarantee a more accuracy in the quality control at research level of the composite materials employed in the aeronautical applications. A briefly introduction about the superconductivity, a complete description of the SQUID properties and its basic working principles have been reported. Moreover, an overview of the most widely used non destructive technique employed in several industrial and research fields have been described. Particular attention is given to the eddy current testing and the technical improvement obtained using SQUID in NDE. The attention has been focused on two particular application, that are the main topics of this thesis. The first concerns with the investigation of the damage due to impact loading on the composites materials, and the second is the study of the corrosion process on the metallic surface. The electrical and mechanical properties of the tested advanced composite materials, such as Carbon Fiber Reinforced Polymers (CFRPs) and Fiber-glass Aluminium (FGA) laminates are investigated. The experimental results concern the non-destructive evaluation of impact loading on the CFRPs and FGA composites, by means of the electromagnetic techniques; the investigation of the electromechanical effect in the CFRPs using the SQUID based prototype and the AFM analyses; and the study of corrosion activity of the metallic surface using magnetic field measurement

Understanding the effect of fabrication conditions on the structural, electrical, and mechanical properties of composite materials containing carbon fillers

Carbon structures are commonly used as the reinforcement phase in composite materials toimprove the electrical, mechanical, and/or thermal properties of the matrix material. The structural diversity of carbon in its various forms (graphene, carbon nanotubes, graphite fibers, for example) makes it a useful reinforcement phase, as the properties of the composite material can be tailored for a specific application depending on the structure and properties of the carbon structure used. In this work, the incorporation of graphene/graphitic carbon into an aluminum metal matrix by an electrocharging assisted process (EAP) was investigated to create a composite material with enhanced electrical conductivity and yield strength. The increased electrical conductivity makes the composite suitable for application in more efficient power transmission lines. The increased strength makes it useful as a lightweight structural material in aerospace applications. The EAP involves applying a direct current to a mixture of molten aluminum and activated carbon to induce the crystallization of graphitic sheets/ribbons that extend throughout the matrix. The effect of processing conditions (current density, in particular) on the graphitic carbon structure, electrical properties, and mechanical properties of the composite material was investigated. The effect of porosity/voids and oxide formation was discussed with respect to the measured properties, and updates to the EAP system were made to mitigate their detrimental effects. It was found that the application of current results in some increase in graphitic carbon crystallite size calculated from Raman spectra, but many areas show the same crystallite size as the activated carbon starting material. It is likely that the current density used during processing was too low to see significant crystallization of graphitic carbon. There was no increase in electrical conductivity compared to a baseline sample with no added carbon, most likely due to porosity/voids in the samples. The mechanical characterization results indicated that the graphitic carbon clusters formed by the process did not act as an effective reinforcement phase, with no improvement in hardness and a decrease in elastic modulus measured by nanoindentation. The decreased elastic modulus was a result of compliant carbon clusters and porosity in the covetic samples. The porosity/voids were not entirely eliminated by the updates to the system, thus the electrical conductivity still did not improve. Additionally, a multifunctional composite structure consisting of a carbon-fiber reinforced polymer (CFRP) laminate with added copper mesh layers was investigated for use in aerospace applications as a structural and electromagnetic interference (EMI) shielding component. The CFRP provides primarily a structural function, while the copper mesh layers were added to increase EMI shielding effectiveness (SE). Nanoindentation was used to study the interfacial mechanical properties of the fiber/polymer and Cu/polymer interfaces, as the interfacial strength dictates the overall mechanical performance of the composite. Further, a finite element model of EMI SE was made to predict SE in the radiofrequency to microwave range for different geometry and configurations of the multifunctional composite structure. The model was used to help determine the optimum design of the multifunctional composite structure for effective shielding of EM radiation. It was found from nanoindentation near the fiber/polymer and Cu/polymer interfaces that the carbon fibers act as an effective reinforcement phase with hardness in the matrix increasing in the interphase region near the carbon fibers due to strong interfacial adhesion. In contrast, the Cu/polymer interface did not exhibit an increase in hardness, indicating poor interfacial adhesion. The EMI SE model indicated that the combination of CFRP layers, which primarily shields EMI by absorption, and Cu mesh, which predominantly shields by reflection, provided adequate SE over a wider frequency range than the individual components alone. Further, it was found that the SE of the CFRP layers were improved by including multiple plies with different relative fiber orientations

Epoxy-Based Composites

Epoxy-based composites are used in automotive and aerospace applications because of their high strength-to-weight ratio, high stiffness-to-weight ratio, and good resistance to wear and corrosion. This book presents research on epoxy-based composites and their applications. It explains methods of preparing and testing these composites, including the hand lay-up technique, compression molding, and others. This book is useful for industrialists, undergraduate and postgraduate students, research scholars, and scientists

Detection of subsurface anomalies in fiber-reinforced polymer (FRP) wrapped timber bridge components using infrared thermography

This thesis presents the results of an experimental study on the use of Infrared Thermography technique for detection of subsurface anomalies in fiber reinforced polymer (FRP) wrapped timber bridge components. An extensive literature review on the application of various nondestructive evaluation techniques to composite structures has also been presented.;Simulated subsurface delaminations were constructed in the laboratory in timber piles wrapped with FRP composite fabric. The delaminations varied in size, thickness, and severity. These delaminations were placed between the 1/8&inches; thick FRP wrap and timber surface. The thermal images from the delaminated specimens were compared with thermal images from undamaged specimens to study the effect of subsurface anomalies. In addition, several field tests were conducted using the infrared imaging system on three timber railroad bridges located in Moorefield, West Virginia that were reinforced with FRP composite fabric. The field test data was used to detect debonds at the composite-timber interface and study the effect of environmental parameters on infrared images.;This study shows that the infrared thermography technique can be used to effectively to detect subsurface delaminations in timber components wrapped with FRP composite fabric. The study also shows the effect of different parameters (environmental conditions, heat source, etc.) on the clarity of infrared images

Index to 1981 NASA Tech Briefs, volume 6, numbers 1-4

Short announcements of new technology derived from the R&D activities of NASA are presented. These briefs emphasize information considered likely to be transferrable across industrial, regional, or disciplinary lines and are issued to encourage commercial application. This index for 1981 Tech Briefs contains abstracts and four indexes: subject, personal author, originating center, and Tech Brief Number. The following areas are covered: electronic components and circuits, electronic systems, physical sciences, materials, life sciences, mechanics, machinery, fabrication technology, and mathematics and information sciences

Advanced Carbon Fiber Composite Materials for Shielding and Antenna Applications

Due to the low weight, ease of fabrication, low cost, high stiffness, high thermal and electrical conductivity, advanced carbon fiber composite (CFC) material is one of the most desirable materials which have been considered recently in the aerospace, electronic, and infrastructure industry. This thesis examines the use of CFC materials for electromagnetic field shielding and antenna applications. Using a suitable electromagnetic model of composite materials, we evaluate the shielding effectiveness (SE) and other EM properties of composites paying attention to antenna design. Analytical and simulation results are compared with experimental data. Two kinds of composite materials are investigated, namely reinforced continuous carbon-fiber (RCCF) composites and carbon nanotube (CNT) composites. For analytical SE analysis of multilayer RCCF composites, the material shows anisotropic behavior along the direction of the fibers, and we employ the transmission matrix method in conjunction with the anisotropic properties of each layer. The shielding performance of composites is also experimentally investigated. In order to enhance the conductivity of an RCCF composite, a small volume fraction of multi-walled carbon nanotubes (MWCNTs) is added to the RCCF material. We investigate the SE of the proposed MWCNT “nanocomposite” over a wide frequency band up to 26.5 GHz. The effect of aspect ratio on shielding performance is addressed as well. The effective conductivity of the nanocomposites was determined over the frequency range of interest. The use of RCCF and single-walled carbon nanotube (SWCNT) composite is investigated for building antennas, by replacing the metal with CFC. We use an RCCF composite to build resonant and wideband antennas. The effect of the conductivity tensor of RCCF composite on the antenna performance is addressed. We also study the performance of a microstrip patch antenna with the ground plane made of RCCF composite. As one of the most highly-conductive composite materials, single wall carbon nanotube (SWCNT) buckypapers are used to build composite antennas. A new fabrication method is proposed to print arbitrarily-shaped full-composite SWCNT antenna on any type of substrate. Various types of SWCNT antennas are fabricated for different antenna applications, namely UHF-RFID, WLAN, UWB, and mm-wave applications. Good agreement is observed between simulation and experimental results for all the aforementioned composite antennas. Using the spectral domain method, the Green’s function is obtained for an infinitesimal HED on a dielectric slab over a CFC ground plane. Due to the high conductivity, CFCs are modeled using a surface impedance. The expressions for the electric field components are derived. The numerical integration details particularly dealing with low-converged tail of the integrand for fields at the air-dielectric interface are addressed. Numerical results based on this method compare well with results based on a time-domain finite integration technique. The effect of conductivity and anisotropy of the composite ground plane on electric field is investigated

Fabrication of functional micro/nano-carbon composites based on structural design for electromagnetic shielding （構造設計による機能性マイクロ・ナノコンポジットの開発および電磁波遮蔽への応用）

信州大学(Shinshu university)博士（工学）この博士論文は、次の学術雑誌論文を一部に使用しています。COMPOSITES SCIENCE AND TECHNOLOGY. 172:108-116 (2019); doi:10.1016/j.compscitech.2019.01.013. © 2019 Elsevier Ltd.MATERIALS LETTERS. 245:98-102 (2019); doi:10.1016/j.matlet.2019.02.101. © 2019 Elsevier Ltd.RSC ADVANCES. 9(17):9401-9409 (2019); doi:10.1039/c9ra00028c. © The Royal Society of Chemistry 2019.MATERIALS LETTERS. 236:116-119 (2019); doi:10.1016/j.matlet.2018.10.101. © 2018 Elsevier B.V.ThesisYAN YONGJIE. Fabrication of functional micro/nano-carbon composites based on structural design for electromagnetic shielding　（構造設計による機能性マイクロ・ナノコンポジットの開発および電磁波遮蔽への応用）. 信州大学, 2019, 博士論文. 博士（工学）, 甲第715号, 令和01年09月30日授与.doctoral thesi

A new mixed model based on the enhanced-Refined Zigzag Theory for the analysis of thick multilayered composite plates

The Refined Zigzag Theory (RZT) has been widely used in the numerical analysis of multilayered and sandwich plates in the last decay. It has been demonstrated its high accuracy in predicting global quantities, such as maximum displacement, frequencies and buckling loads, and local quantities such as through-the-thickness distribution of displacements and in-plane stresses [1,2]. Moreover, the C0 continuity conditions make this theory appealing to finite element formulations [3]. The standard RZT, due to the derivation of the zigzag functions, cannot be used to investigate the structural behaviour of angle-ply laminated plates. This drawback has been recently solved by introducing a new set of generalized zigzag functions that allow the coupling effect between the local contribution of the zigzag displacements [4]. The newly developed theory has been named enhanced Refined Zigzag Theory (en- RZT) and has been demonstrated to be very accurate in the prediction of displacements, frequencies, buckling loads and stresses. The predictive capabilities of standard RZT for transverse shear stress distributions can be improved using the Reissner’s Mixed Variational Theorem (RMVT). In the mixed RZT, named RZT(m) [5], the assumed transverse shear stresses are derived from the integration of local three-dimensional equilibrium equations. Following the variational statement described by Auricchio and Sacco [6], the purpose of this work is to implement a mixed variational formulation for the en-RZT, in order to improve the accuracy of the predicted transverse stress distributions. The assumed kinematic field is cubic for the in-plane displacements and parabolic for the transverse one. Using an appropriate procedure enforcing the transverse shear stresses null on both the top and bottom surface, a new set of enhanced piecewise cubic zigzag functions are obtained. The transverse normal stress is assumed as a smeared cubic function along the laminate thickness. The assumed transverse shear stresses profile is derived from the integration of local three-dimensional equilibrium equations. The variational functional is the sum of three contributions: (1) one related to the membrane-bending deformation with a full displacement formulation, (2) the Hellinger-Reissner functional for the transverse normal and shear terms and (3) a penalty functional adopted to enforce the compatibility between the strains coming from the displacement field and new “strain” independent variables. The entire formulation is developed and the governing equations are derived for cases with existing analytical solutions. Finally, to assess the proposed model’s predictive capabilities, results are compared with an exact three-dimensional solution, when available, or high-fidelity finite elements 3D models. References: [1] Tessler A, Di Sciuva M, Gherlone M. Refined Zigzag Theory for Laminated Composite and Sandwich Plates. NASA/TP- 2009-215561 2009:1–53. [2] Iurlaro L, Gherlone M, Di Sciuva M, Tessler A. Assessment of the Refined Zigzag Theory for bending, vibration, and buckling of sandwich plates: a comparative study of different theories. Composite Structures 2013;106:777–92. https://doi.org/10.1016/j.compstruct.2013.07.019. [3] Di Sciuva M, Gherlone M, Iurlaro L, Tessler A. A class of higher-order C0 composite and sandwich beam elements based on the Refined Zigzag Theory. Composite Structures 2015;132:784–803. https://doi.org/10.1016/j.compstruct.2015.06.071. [4] Sorrenti M, Di Sciuva M. An enhancement of the warping shear functions of Refined Zigzag Theory. Journal of Applied Mechanics 2021;88:7. https://doi.org/10.1115/1.4050908. [5] Iurlaro L, Gherlone M, Di Sciuva M, Tessler A. A Multi-scale Refined Zigzag Theory for Multilayered Composite and Sandwich Plates with Improved Transverse Shear Stresses, Ibiza, Spain: 2013. [6] Auricchio F, Sacco E. Refined First-Order Shear Deformation Theory Models for Composite Laminates. J Appl Mech 2003;70:381–90. https://doi.org/10.1115/1.1572901