Structural Evolution, Chemical Order, and Crystallization of Metallic Liquids and Glasses

Over the last 60 years, bulk metallic glasses have emerged as a new class of materials with highly desirable material properties. Their high strength, high elasticity, and corrosion resistance are attractive properties for viable commercial products. At its core, material properties are directly related to the underlying microstructure. By understanding the structural and chemical order in the liquid and undercooled liquid and their relationship to thermophysical properties such as viscosity, a greater understanding of bulk metallic glass formation can be achieved. In this dissertation, electrostatic levitation techniques are used to study the liquid in a containerless environment using a combination of X-ray and neutron scattering techniques. An X-ray diffraction study of liquid and glass Ni-Nb(-Ta) alloys reveals that an acceleration in the rate of structural ordering must take place near the glass transition, providing the framework for a structural description of fragility. X-ray diffraction and thermophysical property measurements of Zr-Ni binary alloys further characterize the structural connection to viscosity, and reveal signatures of chemical ordering in the liquid. By combining X-ray and neutron scattering measurements, the topological and chemical order in Zr80Pt20 and Zr77Rh23 liquids is characterized. Very different chemical order is found between these alloys, despite their remarkable similarity in topological order. Due to this structural similarity, a new metastable phase is predicted and later identified emerging from a deeply supercooled Zr77Rh23 liquid. Zr77Rh23 is found to have many metastable crystallization pathways, which are further characterized here. Through simultaneous wide-angle and small-angle X-ray scattering, the devitrification behavior of a bulk metallic glass (Vitreloy 105) is investigated and is found to decompose into two distinct compositions during crystallization. By understanding crystallization pathways in good glass-forming alloys, a better understanding of glass formation and its connections to structural and thermophysical properties can be achieved

Self Assembly Problems of Anisotropic Particles in Soft Matter.

Anisotropic building blocks assembled from colloidal particles are attractive building blocks for self-assembled materials because their complex interactions can be exploited to drive self-assembly. In this dissertation we address the self-assembly of anisotropic particles from multiple novel computational and mathematical angles. First, we accelerate algorithms for modeling systems of anisotropic particles via massively parallel GPUs. We provide a scheme for generating statistically robust pseudo-random numbers that enables GPU acceleration of Brownian and dissipative particle dynamics. We also show how rigid body integration can be accelerated on a GPU. Integrating these two algorithms into a GPU-accelerated molecular dynamics code (HOOMD-blue), make a single GPU the ideal computing environment for modeling the self-assembly of anisotropic nanoparticles. Second, we introduce a new mathematical optimization problem, filling, a hybrid of the familiar shape packing and covering problem, which can be used to model shaped particles. We study the rich mathematical structures of the solution space and provide computational methods for finding optimal solutions for polygons and convex polyhedra. We present a sequence of isosymmetric optimal filling solutions for the Platonic solids. We then consider the filling of a hyper-cone in dimensions two to eight and show the solution remains scale-invariant but dependent on dimension. Third, we study the impact of size variation, polydispersity, on the self-assembly of an anisotropic particle, the polymer-tethered nanosphere, into ordered phases. We show that the local nanoparticle packing motif, icosahedral or crystalline, determines the impact of polydispersity on energy of the system and phase transitions. We show how extensions of the Voronoi tessellation can be calculated and applied to characterize such micro-segregated phases. By applying a Voronoi tessellation, we show that properties of the individual domains can be studied as a function of system properties such as temperature and concentration. Last, we consider the thermodynamically driven self-assembly of terminal clusters of particles. We predict that clusters related to spherical codes, a mathematical sequence of points, can be synthesized via self-assembly. These anisotropic clusters can be tuned to different anisotropies via the ratio of sphere diameters and temperature. The method suggests a rich new way for assembling anisotropic building blocks.Ph.D.Applied Physics and Scientific ComputingUniversity of Michigan, Horace H. Rackham School of Graduate Studieshttp://deepblue.lib.umich.edu/bitstream/2027.42/91576/1/phillicl_1.pd

LIPIcs, Volume 258, SoCG 2023, Complete Volume

LIPIcs, Volume 258, SoCG 2023, Complete Volum

Engineering Dynamics and Life Sciences

From Preface: This is the fourteenth time when the conference “Dynamical Systems: Theory and Applications” gathers a numerous group of outstanding scientists and engineers, who deal with widely understood problems of theoretical and applied dynamics. Organization of the conference would not have been possible without a great effort of the staff of the Department of Automation, Biomechanics and Mechatronics. The patronage over the conference has been taken by the Committee of Mechanics of the Polish Academy of Sciences and Ministry of Science and Higher Education of Poland. It is a great pleasure that our invitation has been accepted by recording in the history of our conference number of people, including good colleagues and friends as well as a large group of researchers and scientists, who decided to participate in the conference for the first time. With proud and satisfaction we welcomed over 180 persons from 31 countries all over the world. They decided to share the results of their research and many years experiences in a discipline of dynamical systems by submitting many very interesting papers. This year, the DSTA Conference Proceedings were split into three volumes entitled “Dynamical Systems” with respective subtitles: Vibration, Control and Stability of Dynamical Systems; Mathematical and Numerical Aspects of Dynamical System Analysis and Engineering Dynamics and Life Sciences. Additionally, there will be also published two volumes of Springer Proceedings in Mathematics and Statistics entitled “Dynamical Systems in Theoretical Perspective” and “Dynamical Systems in Applications”

Documents as functions

Treating variable data documents as functions over their data bindings opens opportunities for building more powerful, robust and flexible document architectures to meet the needs arising from the confluence of developments in document engineering, digital printing technologies and marketing analysis. This thesis describes a combination of several XML-based technologies both to represent and to process variable documents and their data, leading to extensible, high-quality and 'higher-order' document generation solutions. The architecture (DDF) uses XML uniformly throughout the documents and their processing tools with interspersing of different semantic spaces being achieved through namespacing. An XML-based functional programming language (XSLT) is used to describe all intra-document variability and for implementing most of the tools. Document layout intent is declared within a document as a hierarchical set of combinators attached to a tree-based graphical presentation. Evaluation of a document bound to an instance of data involves using a compiler to create an executable from the document, running this with the data instance as argument to create a new document with layout intent described, followed by resolution of that layout by an extensible layout processor. The use of these technologies, with design paradigms and coding protocols, makes it possible to construct documents that not only have high flexibility and quality, but also perform in higher-order ways. A document can be partially bound to data and evaluated, modifying its presentation and still remaining variably responsive to future data. Layout intent can be re-satisfied as presentation trees are modified by programmatic sections embedded within them. The key enablers are described and illustrated through example

NASA Tech Briefs, Spring 1981

Topics include: NASA TU Services: Technology Utilization services that can assist you In learning about and applying NASA technology; New Product Ideas: A summary of selected innovations of value to manufacturers for the development of new products; Electronic Components and Circuits; Electronic Systems; Physical Sciences; Materials; Life Sciences; Mechanics; Machinery; Fabrication Technology; Mathematics and Information Sciences