Towards Developing Mid-Infrared Photonics Using Mxenes

Recent research and development in the mid-infrared (IR) wavelength range (2-20 um) for a variety of applications, such as trace gas monitoring, thermal imaging, and free space communications have shown tremendous and fascinating progress. MXenes, which mainly refer to two-dimensional (2D) transition-metal carbides, nitrides, and carbonitrides, have drawn a lot of interest since their first investigation in 2011. MXenes project enormous potential for use in optoelectronics, photonics, catalysis, and energy harvesting fields proven by extensive experimental and theoretical studies over a decade. MXenes offers a novel 2D nano platform for cutting-edge optoelectronics devices due to their interesting mechanical, optical, and electrical capabilities, along with their elemental and chemical composition. We here discuss the key developments of MXene emphasizing the evolution of material synthesis methods over time and the resulting device applications. Photonic and optoelectronic device design and fabrication for mid-IR photonics are demonstrated by integrating MXene materials with various electrical and photonic platforms. Here, we show the potential of using Mxene in photonics for mid-IR applications and a pathway toward achieving next-generation devices for various applications.Comment: 50 Pages, 21 figure

Advanced Nanomaterials for Electrochemical Energy Conversion and Storage

This book focuses on advanced nanomaterials for energy conversion and storage, covering their design, synthesis, properties and applications in various fields. Developing advanced nanomaterials for high-performance and low-cost energy conversion and storage devices and technologies is of great significance in order to solve the issues of energy crisis and environmental pollution. In this book, various advanced nanomaterials for batteries, capacitors, electrocatalysis, nanogenerators, and magnetic nanomaterials are presente

Magnetic materials : fundamental synthesis of two-dimensional magnets and applications to neuromorphic computing

Two dimensional magnetic materials hold the promise of helping to achieve beyond CMOS computing tasks. 2D magnetic materials can be used in fabricating magnetic tunnel junctions with higher tunnel magnetoresistance which can then be applied to making new neuromorphic computing architectures primarily geared towards artificial intelligence and machine learning applications. In this work I summarize my synthesis and investigation of the properties of Cr₂C which belongs to the group of 2D transition metal carbides or nitrides called MXenes. Cr₂C has been predicted to have intrinsic half metallic ferromagnetic behaviors. These magnetic behaviors can be tuned based on the level of functionalization of the surface of the material. I show different parameters such as etchant, reaction temperature, and molar concentration that I have tuned in order to optimally derive Cr₂C from its parent MAX phase Cr₂AlC by removing the Al layer with a fluoride salt and hydrochloric acid. I also show how magnetic tunnel junctions (MTJs), which are two ferromagnetic layers with a tunnel barrier in between, can be used to make a synapse which is a neuromorphic computing primitive. The synapse circuit that I have proposed displays spike timing dependent plasticity which is an integral component of learning and memory in the brain. I show how different delay conditions between the presynaptic signal and the postsynaptic signal lead to currents of different magnitudes flowing through the ferromagnetic layer of the magnetic tunnel junction synapse. I also show how these currents move the domain wall both in micromagnetic simulation and using a domain wall MTJ Spice model that has been developed. I went on to wire four of these synapses together to observe the temporal dynamics of the system. My results show that the lower the delay between the presynaptic pulse and the postsynaptic pulse, the higher the current through the MTJ synapse and hence the larger the domain wall displacement. These studies pave the way for empirical understanding of the Cr₂C MXene, including its potential magnetic properties, as well as doing online machine learning classification tasks with arrays of magnetic synapsesElectrical and Computer Engineerin

Recent advances in metallic transition metal dichalcogenides as electrocatalysts for hydrogen evolution reaction

Layered metallic transition metal dichalcogenides (MTMDs) exhibit distinctive electrical and catalytic properties to drive basal plane activity, and, therefore, they have emerged as promising alternative electrocatalysts for sustainable hydrogen evolution reactions (HERs). A key challenge for realizing-MTMDs-based electrocatalysts is the controllable and scalable synthesis of high-quality MTMDs and the development of engineering strategies that allow tuning their electronic structures. However, the lack of a method for the direct synthesis of MTMDs retaining the structural stability limits optimizing the structural design for the next generation of robust electrocatalysts. In this review, we highlight recent advances in the synthesis of MTMDs comprising groups VB and VIB and various routes for structural engineering to enhance the HER catalytic performance. Furthermore, we provide insight into the potential future directions and the development of MTMDs with high durability as electrocatalysts to generate green hydrogen through water-splitting technology

2D metal carbides and nitrides (MXenes) for energy storage

The family of 2D transition metal carbides, carbonitrides and nitrides (collectively referred to as MXenes) has expanded rapidly since the discovery of Ti3C2 in 2011. The materials reported so far always have surface terminations, such as hydroxyl, oxygen or fluorine, which impart hydrophilicity to their surfaces. About 20 different MXenes have been synthesized, and the structures and properties of dozens more have been theoretically predicted. The availability of solid solutions, the control of surface terminations and a recent discovery of multi-transition-metal layered MXenes offer the potential for synthesis of many new structures. The versatile chemistry of MXenes allows the tuning of properties for applications including energy storage, electromagnetic interference shielding, reinforcement for composites, water purification, gas- and biosensors, lubrication, and photo-, electro- and chemical catalysis. Attractive electronic, optical, plasmonic and thermoelectric properties have also been shown. In this Review, we present the synthesis, structure and properties of MXenes, as well as their energy storage and related applications, and an outlook for future research

MXene-Based Nanomaterials for Biomedical Applications: Healthier Substitute Materials for the Future

MXene-based nanomaterial is a revolution 2D material achieving outstanding scientific attention owing to its universal characteristics for different applications (such as electronic appliances, power production, sensors, drug transfer, and biomedical). Although, the cytotoxic consequences of MXene have a considerable circumstance. Thus, rigorous investigation of the biocompatibility of MXene is a crucial prerequisite, formerly the preface to the human biological approach. Literature reveals functional outcomes wherever MXenes are used in vitro and in vivo cancer representatives. It affects drug transfer methods, sensoring electrodes, and assisting mechanisms for photothermal treatment and hyperthermy techniques. In this review, the synthesis process (such as top-down and bottom-up approaches) and properties (such as mechanical, electrical, optical, oxidative/thermal stability, and magnetic) of MXene-based nanomaterials (NMs) are discussed. In addition, the different applications (such as tissue engineering, cancer theranostic, and other biomedical [such as drug delivery biosensors and surface-enhanced Raman spectroscopy substrates for biomedical applications], antiviral, and immunomodulatory properties against SARS-CoV-2) of MXene-based NMs are discussed in detail. Finally, the conclusion, existing challenges, and future outlooks are highlighted for more scope in this field

MXenes—A New Class of Two-Dimensional Materials: Structure, Properties and Potential Applications

A new class of two-dimensional nanomaterials, MXenes, which are carbides/nitrides/carbonitrides of transition and refractory metals, has been critically analyzed. Since the synthesis of the first family member in 2011 by Yury Gogotsi and colleagues, MXenes have quickly become attractive for a variety of research fields due to their exceptional properties. Despite the fact that this new family of 2D materials was discovered only about ten years ago, the number of scientific publications related to MXene almost doubles every year. Thus, in 2021 alone, more than 2000 papers are expected to be published, which indicates the relevance and prospects of MXenes. The current paper critically analyzes the structural features, properties, and methods of synthesis of MXenes based on recent available research data. We demonstrate the recent trends of MXene applications in various fields, such as environmental pollution removal and water desalination, energy storage and harvesting, quantum dots, sensors, electrodes, and optical devices. We focus on the most important medical applications: photo-thermal cancer therapy, diagnostics, and antibacterial treatment. The first results on obtaining and studying the structure of high-entropy MXenes are also presented

Spark Plasma Sintering of 2D Nitride and Carbide based Ceramics

Two-dimensional (2D) nanomaterials have stimulated significant interest among materials community due to a wide variety of application ranging from functional to structural properties. Boron nitride nanosheets (BNNS), boron-carbon-nitride (BCN), and MXene (Mn+1Xn, transition metal carbides, nitrides or carbonitrides) belongs to 2D materials family with van der Waals bonding between the layers. The research on synthesis and properties of BNNS, BCN and MXene have been predominantly explored for single- or multi-layered 2D nanosheets. In this study, the focus is to synthesize bulk layered BNNS and BCN using single or multilayered 2D nanomaterials by spark plasma sintering (SPS). The rapid processing conditions of SPS allow retention of nanoscale structure in the bulk form. Monolithic BNNS with 92% dense structure was prepared by SPS. The monolithic BNNS with h-BN structure displayed a preferred orientation of basal plane (0002) along the top-surface and this is ascribed to BNNS high aspect ratio. During high-load indentation, the total energy dissipation along top-surface was 50% higher than cross-section of BNNS pellet. Ternary BCN phase was synthesized from 2D graphene nanoplatelet (GNP) and BNNS using reactive SPS technique from temperature range of 1650 - 1750 °C. Hexagonal BCN phase with minor cubic BCN phase was formed in the reactive sintered pellets. Tribological behavior of sintered BNNS and BCN was studied at room temperature and 600°C. The coefficient of friction (COF) increased with the formation of cubic BCN at room temperature but reduced at 600°C due to graphitized transfer layer. Room temperature wear rate of BCN synthesized at 1750 °C increased as compared to BCN synthesized at 1650 °C due to higher level of densification. In this study, the other van der Waals 2D material MXenes multi-scale damping properties were explored for the first time. Multiscale damping behavior of MXene showed high loss tangent (tan δ) of 0.37 and it was 200% higher than pure MAX. It has been hypothesized the bond contraction operates within single MXene layer, compression and sliding/shearing of MXene sheets operates between MXene layers. After 50,000 long cycle test, MXene layers exhibit highly stable damping behavior suggesting its suitability as dampener

The Computational 2D Materials Database: High-Throughput Modeling and Discovery of Atomically Thin Crystals

We introduce the Computational 2D Materials Database (C2DB), which organises a variety of structural, thermodynamic, elastic, electronic, magnetic, and optical properties of around 1500 two-dimensional materials distributed over more than 30 different crystal structures. Material properties are systematically calculated by state-of-the art density functional theory and many-body perturbation theory (G$_0\!$W$\!_0$ and the Bethe-Salpeter Equation for $\sim$200 materials) following a semi-automated workflow for maximal consistency and transparency. The C2DB is fully open and can be browsed online or downloaded in its entirety. In this paper, we describe the workflow behind the database, present an overview of the properties and materials currently available, and explore trends and correlations in the data. Moreover, we identify a large number of new potentially synthesisable 2D materials with interesting properties targeting applications within spintronics, (opto-)electronics, and plasmonics. The C2DB offers a comprehensive and easily accessible overview of the rapidly expanding family of 2D materials and forms an ideal platform for computational modeling and design of new 2D materials and van der Waals heterostructures.Comment: Add journal reference and DOI; Minor updates to figures and wordin