97,949 research outputs found
Modelling of polymer-carbon nanotube heterojunctions for photovoltaic applications
115 p.Semiconducting single-walled carbon nanotubes (s-SWNT) are promising materialsfor efficient organic photovoltaics (OPVs). Unfortunately, the implementation of s-SWNTs has so far not lead to the expected increase in power conversion efficienciesof OPVs. For this reason, we want to study the electronic processes within polymer-SWNT heterojunctions. Transient spectroscopy provides direct information aboutphotoexcitation processes in blends. We modelled the transient spectrum of apolymer:fullerene:s-SWNT blend using Linear Response. Based on our results, weare able to explain the structure transient spectra of s-SWNT systems and theelectronic dynamics linked to it. Further, we studied the internal quantum efficiencyof different donor/acceptor blends by carrying out calculations of the Landauer-BĂĽtticker conductance of prototypical donor/acceptor heterojunctions. We find adependence of the conductivity on the level alignment. By improving the levelalignment of the polymer and SWNT through the use of larger band gap SWNTs,one may obtain a dramatic improvement in OPV efficiency. In summary, our resultsprovide a deeper insight into the photoexcitation and electronic processes ofpolymer-carbon nanotube heterojunctions and thus support the development of moreefficient polymer-SWNT OPVs
Development of an Analytic Nodal Diffusion Solver in Multigroups for 3D Reactor Cores with Rectangular or Hexagonal Assemblies.
More accurate modelling of physical phenomena involved in present and future nuclear reactors requires a multi-scale and multi-physics approach. This challenge can be accomplished by the coupling of best-estimate core-physics, thermal-hydraulics and multi-physics solvers. In order to make viable that coupling, the current trends in reactor simulations are along the development of a new generation of tools based on user-friendly, modular, easily linkable, faster and more accurate codes to be integrated in common platforms. These premises are in the origin of the NURESIM Integrated Project within the 6th European Framework Program, which is envisaged to provide the initial step towards a Common European Standard Software Platform for nuclear reactors simulations. In the frame of this project and to reach the above-mentioned goals, a 3-D multigroup nodal solver for neutron diffusion calculations called ANDES (Analytic Nodal Diffusion Equation Solver) has been developed and tested in-depth in this Thesis. ANDES solves the steady-state and time-dependent neutron diffusion equation in threedimensions and any number of energy groups, utilizing the Analytic Coarse-Mesh Finite-Difference (ACMFD) scheme to yield the nodal coupling equations. It can be applied to both Cartesian and triangular-Z geometries, so that simulations of LWR as well as VVER, HTR and fast reactors can be performed. The solver has been implemented in a fully encapsulated way, enabling it as a module to be readily integrated in other codes and platforms. In fact, it can be used either as a stand-alone nodal code or as a solver to accelerate the convergence of whole core pin-by-pin code systems. Verification of performance has shown that ANDES is a code with high order definition for whole core realistic nodal simulations. In this paper, the methodology developed and involved in ANDES is presented
Direct and Simultaneous Observation of Ultrafast Electron and Hole Dynamics in Germanium
Understanding excited carrier dynamics in semiconductors is crucial for the
development of photovoltaics and efficient photonic devices. However,
overlapping spectral features in optical/NIR pump-probe spectroscopy often
render assignments of separate electron and hole carrier dynamics ambiguous.
Here, ultrafast electron and hole dynamics in germanium nanocrystalline thin
films are directly and simultaneously observed by attosecond transient
absorption spectroscopy (ATAS) in the extreme ultraviolet at the germanium
M_{4,5}-edge (~30 eV). We decompose the ATAS spectra into contributions of
electronic state blocking and photo-induced band shifts at a carrier density of
8*10^{20}cm^{-3}. Separate electron and hole relaxation times are observed as a
function of hot carrier energies. A first order electron and hole decay of ~1
ps suggests a Shockley-Read-Hall recombination mechanism. The simultaneous
observation of electrons and holes with ATAS paves the way for investigating
few to sub-femtosecond dynamics of both holes and electrons in complex
semiconductor materials and across junctions.Comment: Includes Supplementary Informatio
Improving transient analysis technology for aircraft structures
Aircraft dynamic analyses are demanding of computer simulation capabilities. The modeling complexities of semi-monocoque construction, irregular geometry, high-performance materials, and high-accuracy analysis are present. At issue are the safety of the passengers and the integrity of the structure for a wide variety of flight-operating and emergency conditions. The technology which supports engineering of aircraft structures using computer simulation is examined. Available computer support is briefly described and improvement of accuracy and efficiency are recommended. Improved accuracy of simulation will lead to a more economical structure. Improved efficiency will result in lowering development time and expense
Comparative analysis of neutronics/thermal-hydraulics multi-scale coupling for LWR analysis
The aim of the research described in this paper is to perform consistent comparative analyses of two different approaches for coupling of two-scale, two-physics phenomena in reactor core calculations. The physical phenomena of interest are the neutronics and the thermal-hydraulics core behaviors and their interactions, while the spatial scales are the “global” (assembly/channel-wise) and the “local” (pin/sub-channel-wise). The objective is three-fold: qualification of coupled code systems by consistent step-by-step cross-comparison (in order to understand the prediction deviations in both neutronics and thermal-hydraulics parameters); assessment of fine scale (local/subchannel-wise) thermal-hydraulic effects; and evaluation of the impact of on-line modeling of interactions of the two spatial scales. The reported work is within the cooperation between the Universidad Politécnica de Madrid (UPM), Spain and the Pennsylvania State University (PSU), USA. The paper first presents the two multi-scale coupled code systems followed by cross-comparisons for steady state calculations. Selected results are discussed to highlight some of the issues involved in comparative analysis of coupled multi-scale simulations. The transient comparisons are subject of future work and publications
Wind tunnel evaluation of YF-12 inlet response to internal airflow disturbances with and without control
The response of terminal-shock position and static pressures in the subsonic duct of a YF-12 aircraft flight-hardware inlet to perturbations in simulated engine corrected airflow were obtained with and without inlet control. Frequency response data, obtained with inlet controls inactive, indicated the general nature of the inherent inlet dynamics, assisted in the design of controls, and provided a baseline reference for responses with active controls. All the control laws were implemented by means of a digital computer that could be programmed to behave like the flight inlet's existing analog control. The experimental controls were designed using an analytical optimization technique. The capabilities of the controls were limited primarily by the actuation hardware. The experimental controls provided somewhat better attenuation of terminal shock excursions than did the YF-13 inlet control. Controls using both the forward and aft bypass systems also provided somewhat better attenuation than those using just the forward bypass. The main advantage of using both bypasses is in the greater control flexibility that is achieved
Magneto-optical properties of Au upon the injection of hot spin-polarized electrons across Fe/Au(001) interfaces
We demonstrate a novel method for the excitation of sizable magneto-optical
effects in Au by means of the laser-induced injection of hot spin-polarized
electrons in Au/Fe/MgO(001) heterostructures. It is based on the energy- and
spin-dependent electron transmittance of Fe/Au interface which acts as a spin
filter for non-thermalized electrons optically excited in Fe. We show that
after crossing the interface, majority electrons propagate through the Au layer
with the velocity on the order of 1 nm/fs (close to the Fermi velocity) and the
decay length on the order of 100 nm. Featuring ultrafast functionality and
requiring no strong external magnetic fields, spin injection results in a
distinct magneto-optical response of Au. We develop a formalism based on the
phase of the transient complex MOKE response and demonstrate its robustness in
a plethora of experimental and theoretical MOKE studies on Au, including our ab
initio calculations. Our work introduces a flexible tool to manipulate
magneto-optical properties of metals on the femtosecond timescale that holds
high potential for active magneto-photonics, plasmonics, and spintronics
Properties of Physical Systems: Transient Singularities on Borders and Surface Transitive Zones
Certain alternative properties of physical systems are describable by
supports of arguments of response functions (e.g. light cone, borders of media)
and expressed by projectors; corresponding equations of restraints lead to
dispersion relations, theorems of counting, etc. As supports are measurable,
their absolutely strict borders contradict the spirit of quantum theory and
their quantum evolution leading to appearance of subtractions or certain needed
flattening would be considered. Flattening of projectors introduce transitive
zones that can be examined as a specification of adiabatic hypothesis or the
Bogoliubov regulatory function in QED. For demonstration of their possibilities
the phenomena of refraction and reflection of electromagnetic wave are
considered; they show, in particular, the inevitable appearing of double
electromagnetic layers on all surfaces that formerly were repeatedly
postulated, etc. Quantum dynamics of projectors proves the neediness of
subtractions that usually are artificially adding and express transient
singularities and zones in squeezed forms.Comment: 12 p
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Ultrahigh Hot Carrier Transient Photocurrent in Nanocrystal Arrays by Auger Recombination.
In this report, we show that a new mechanism for carrier transport in solution-processed colloidal semiconductor nanocrystal arrays exists at high excitation intensity on ultrafast time scales and allows for facile intrinsic transport between as-prepared nanocrystals over long distances. By combining a high speed photoconductive switch with an ultrafast laser excitation in a sub-40 ps photoconductor, we observed transient photocurrents with peak densities of 3 × 104 - 106 mA/cm2 in self-assembled PbSe nanocrystals capped with long native oleic acid ligands. The ratio between the transient photocurrent peak and the steady-state dark current is 10 orders of magnitude. The transient mobility at the peak current is estimated to range between 0.5-17.5 cm2/(V s) for the various nanocrystal sizes studied, which is 6 to 9 orders of magnitude higher than the dark current steady-state mobility in PbSe, CdSe, and CdTe nanocrystals capped with native ligands. The results are analyzed using a kinetic model which attributes the ultrahigh transient photocurrent to multiple photogenerated excitons undergoing on-particle Auger recombination, followed by rapid tunneling at high energies. This mechanism is demonstrated for a wide range of PbSe nanocrystals sizes (diameters from 2.7 to 7.1 nm) and experimental parameters. Our observations indicate that native ligand-capped nanocrystal arrays are promising for optoelectronics applications wherein multiple carriers are photoinjected to interband states
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