Environmental regulation and corporate strategies to reduce diesel vehicle emissions

Thesis (Ph. D.)--Massachusetts Institute of Technology, Engineering Systems Division, Technology, Management, and Policy Program, 2006.Includes bibliographical references.Environmental regulations are typically portrayed as an outside force stimulating development of environmental technologies in regulated industries. In reality, firms influence regulation by communicating their technological progress, which helps form a basis for future standards. Because of differences in each firm's technological capability and environmental performance, regulations affect the competitive position of firms. Firms with advanced technologies stand to gain competitive benefit from more stringent environmental regulations, and may therefore choose to introduce a more costly but cleaner technology ahead of regulation. Such a competitive regulatory strategy has the potential to bring competitive benefits to the lead firm(s) and environmental benefits to the public. This research explains the conditions under which competitive regulatory strategies are pursued in the diesel vehicle and fuel industry. Growing public concern about the health effects of diesel exhaust has led countries to implement several cycles of increasingly stringent emission and fuel regulations over the past two decades.(cont.) Taking a comparative case study approach, this work studies multiple regulatory cycles for light-duty vehicles, heavy-duty engines, and diesel fuel sulfur in the European Union, Japan, and the United States. For each region's regulatory cycles, cases of corporate behavior, including early adoption, first-mover behavior, and noncompliance, are identified and analyzed for their context, motivation, influence on regulatory policy, and public and private effects. Source material consists of documentary sources, descriptive statistics, and semi-structured interviews with experts. This methodology generates multiple cases for comparison across countries, cycles, sectors, and firms. While early- and first-mover behavior was observed in the regulatory cycles, firms do not aggressively pursue competitive regulatory strategies. They are guided by other motivations, such as fiscal incentives, diesel market share protection, and technology development/testing. A weak business case, risk aversion, industry pressure, and lack of supporting infrastructure pose strong disincentives.(cont.) The final recommendations address issues pertinent to regulators, firms, and environmental groups: fiscal incentives as an effective means to encourage rapid technology adoption; environmental NGOs as a vehicle for communicating technological progress; use of technology demonstrations by lead firms to show regulatory readiness; and combination of short-term and long-term targets with mechanisms to encourage technology-based competition.by Christine Bik-Kay Ng.Ph.D

The state of the art in selective catalytic reduction control

Selective Catalytic Reduction (SCR) is a leading after treatment technology for the removal of nitrogen oxide (NOx) from exhaust gases (DeNOx). It presents an interesting control challenge, especially at high conversion, because both reagents (NOx and ammonia) are toxic, and therefore an excess of either is highly undesirable. Numerous system layouts and control methods have been developed for SCR systems, driven by the need to meet future emission standards. This paper summarizes the current state-of-the-art control methods for the SCR aftertreatment systems, and provides a structured and comprehensive overview of the research on SCR control. The existing control techniques fall into three main categories: traditional SCR control methods, model-based SCR control methods, and advanced SCR control methods. For each category, the basic control technique is defined. Further techniques in the same category are then explained and appreciated for their relative advantages and disadvantages. Thus this paper presents a snapshot of the current state of the art for the research area of SCR control. This is a very active field, and it is hoped that by providing a better understanding of the different control strategies already developed for SCR control, future areas of interest will be identified and developed with the ultimate aim of satisfying the increasingly stringent emissions legislation. Copyright © 2014 SAE International

Optimization of a retrofit urea-SCR system

Oxides of nitrogen (NOx) emissions from legacy diesel engines are often many times over currently mandated standards, contributing significantly to degradation of air quality and negative environmental impact. A retrofit urea-SCR (selective catalytic reduction) aftertreatment system offers a viable solution for reducing NOx emissions from older diesel engines. A stand-alone retrofit urea-SCR aftertreatment system was previously developed by West Virignia University (WVU) engineers, implementing a pre-SCR NOx sensor, open-loop feed-forward control, and stoichiometric NOx reduction logic. During experimental testing at WVU, the urea-SCR system demonstrated NOx reductions of 2% to 53%, depending on the test cycle. In order to optimize the system, this dissertation considered additional control configurations. To evaluate the emissions performance of each control strategy, a neural network heavy-duty diesel engine model was developed along with separate four-state chemical and thermal SCR catalyst models. Each model component was validated with experimental data recorded from the WVU Engine and Emissions Research Laboratory (EERL). The following control configurations were considered: (1) pre-SCR NOx sensor, open-loop feed-forward control, (2) post-SCR NOx sensor, closed-loop feed-back proportional-derivative (PD) control, (3) pre- and post-SCR NOx sensors, closed-loop feed-back proportional-integral-derivative (PID) control, (4) pre-SCR NOx sensor, model-based control.;The evaluation process considered differences between a highly instrumented and highly engineered system. Emissions performance was evaluated over two transient on-road test cycles (FTP, ACES HHDDT_S) and one steady-state marine test cycle (ICOMIA E5), implying broad applicability of the aftertreatment system. The evaluation process was characterized by overall NOx reduction percentage, maximum ammonia slip in parts per million (ppm), and average ammonia slip (ppm). The complexity of the sensor configuration and control strategy calibration were evaluated, as well as how adaptable a given configuration was to variations in engine behavior and sensor measurement accuracy. Finally, total cost was compared between each control configuration, considering system capital, maintenance, operation, control strategy engineering, and system calibration. A final cost per ton of NOx reduced was presented for each control configuration, assuming a six year operational cycle in marine and on-road applications. Based on the collective emissions, complexity, and cost analyses, a configuration implementing pre- and post-SCR NOx sensors and closed-loop PID control was identified as optimal for a retrofit application. Model results demonstrated NOx reductions of 44%, 53%, and 47% over FTP, ICOMIA, and ACES High-Speed Cruise (HHDDT_S) cycles, respectively. The total annual NOx reduction cost was {dollar}8,800 per ton of NOx reduced for an on-road application and {dollar}3,651 per ton of NOx reduced for a marine application

Staten Island Ferry emissions reduction

Marine diesel engines are being investigated thoroughly since many engines in these vessels incorporate older technology that may not have been subjected to emissions regulations and hence produce a significant amount of pollution. The Staten Island Ferry Alice Austen was fitted with selective catalytic reduction (SCR) technology to reduce the emissions of oxides of nitrogen (NOx) to offset the dredging equipment emissions from the Harbor Deepening project. Data logging showed a repeatable route of vessel operation including an idle, acceleration, cruise, and maneuvering mode combined with vessel direction. The SCR system provided 34-64% NOx reduction for a round trip with less than 8ppm ammonia slip. Average NOx reductions during cruise mode were 47-75%. Reductions for the cruise mode during urea injection typically exceeded 94%. From modal analysis of onboard testing, idle, acceleration, and maneuvering produced 20% of the NOx. Cruise produced 80% of the NOx. The oxidation catalyst provided 80-95% reduction in carbon monoxide

Control-oriented modelling and diagnostics of diesel after-treatment catalysts

[ES] Esta tesis doctoral abarca el desarrollo de algoritmos orientados a mejorar el sistema de control de emisiones en motores Diesel. Para este propósito, la inclusión en el vehículo de sensores embarcados como los de temperatura, los de NOx o el de NH3 permite realizar diagnóstico a bordo de los sistemas de post-tratamiento foco de este trabajo, los cuales son el DOC y el SCR. Así pues, el objetivo es el de satisfacer las normativas de diagnóstico a bordo para mantener las emisiones por debajo del umbral permitido por la normativa a lo largo del tiempo. Los tests experimentales, incluyendo las medidas con analizador de gases, permiten tener una visión más amplia de las especies en la línea de escape. Complementariamente, se utilizan unidades nuevas y envejecidas para tener el efecto experimental del envejecimiento en los catalizadores. De esta manera, se analiza el efecto de la temperatura, el gasto de escape, las concentraciones de las especies y el envejecimiento en el DOC y en el SCR, así como la evaluación de algunas de las medidas relevantes realizadas por los sensores. Las temperaturas tienen una influencia destacada en el funcionamiento de los catalizadores, por lo que se requiere la evaluación de las medidas de los sensores de temperatura, junto con el desarrollo de modelos de transmisión de calor, para alimentar las funciones a continuación desarrolladas. En este sentido, la medida lenta del sensor aguas arriba del DOC se mejora en condiciones transitorias mediante una técnica de fusión de la información basada en un filtro de Kalman. Luego, se presenta un modelo de transmisión de calor 1D y un modelo agrupado 0D, en los cuales se evalúan las entradas aguas arriba según el uso del modelo. Por otra parte, se presenta una técnica para estimar el incremento de temperatura debido a la oxidación de los pulsos de post-inyección en el DOC. Se proponen modelos para ambos DOC y SCR para estimar el efecto del envejecimiento en las emisiones, en los cuales el factor de envejecimiento es modelado como un parámetro sintonizable que permite variar desde estados nuevos a envejecidos. Por una parte, un modelo agrupado 0D es desarrollado para el DOC con el propósito de estimar el desliz de HC y CO, el cual es validado en un WLTC para después ser usado en simulación. Por otra parte, un modelo 1D y un modelo 0D se desarrollan para el SCR, los cuales se usan a continuación para alimentar la estrategia de diagnóstico y para simulación. Finalmente, las estrategias de diagnóstico se presentan para fallo total o retirada de DOC, así como para la estimación de la eficiencia en DOC y SCR. Por una parte, la primera estrategia se divide en pasiva y activa, en la que se usan post-inyecciones en la activa para excitar el sistema y confirmar el fallo total si es el caso. A continuación, la eficiencia del DOC se estima a través de una técnica indirecta en la que la temperatura de activación se detecta y se relaciona con el incremento de emisiones a través del modelo. Por otra parte, se desarrolla un observador para estimar el estado de envejecimiento del SCR, el cual está basado en un filtro de Kalman extendido. Sin embargo, para evitar asociar baja eficiencia del catalizador debido a pobre calidad de la urea inyectada, a envejecimiento del SCR, un indicador de la calidad de la urea se ejecuta en paralelo.[CA] Esta tesi doctoral abasta el desenvolupament d'algoritmes orientats a millor el sistema de control d'emissions en motors Diesel. Per a este propòsit, la inclusió en el vehicle de sensor embarcats com els de temperatura, els de NOx o el d'NH3 permet realitzar el diagnòstic a bord dels sistemes de post-tractament focus d'este treball, els quals són el DOC i el SCR. Així doncs, l'objectiu és el de satisfer les normatives de diagnòstic a bord per a mantindre les emissions per baix de l'umbral permés per la normativa al llarg del temps. Els tests experimentals, incloent les mesures amb analitzador de gasos, permeten obtindre una visió més àmplia de les espècies en la línia d'escapament. Complementàriament, s'utilitzen unitats noves i envellides per tal de tindre l'efecte experimental de l'envelliment en els catalitzadors. D'aquesta manera, s'analitza l'efecte de la temperatura, la despesa d'escapament, les concentracions de les espècies i l'envelliment en el DOC i en el SCR, així com l'avaluació d'algunes mesures rellevants realitzades pels sensors. Les temperatures tenen una influència destacada en el funcionament dels catalitzadors, pel que es requerix l'avaluació de les mesures dels sensors de temperatura, junt amb el desenvolupament de models de transmissió de calor, per a alimentar les funcions a continuació desenvolupades. En este sentit, la mesura lenta del sensor a l'entrada del DOC es millora en condicions transitòries mitjançant una tècnica de fusió de la informació basada en un filtre de Kalman. Després, es presenta un model de transmissió de calor 1D i un model agrupat 0D, en els quals s'avaluen les entrades a l'entrada segons l'ús del model. Per altra banda, es presenta una tècnica per a estimar l'increment de temperatura degut a l'oxidació dels polsos de post-injecció en el DOC. Es proposen models per a DOC i SCR per a estimar l'efecte de l'envelliment en les emissions, en els quals es modela el factor d'envelliment com un paràmetre sintonitzable, que permet variar des d'estats nous a envellits. Per altra banda, un model agrupat 0D _es desenvolupat per al DOC amb el propòsit d'estimar la relliscada de HC i CO, el qual és validat en un WLTC per a després ser usat en simulació. Per altra banda, un model 1D i un model 0D es desenvolupen per al SCR, els quals s'usen a continuació per a alimentar l'estratègia de diagnòstic i per a simulació. Finalment, les estratègies de diagnòstic es presenten per a la fallada total o retirada del DOC, així com per a l'estimació de l'eficiència en DOC i SCR. Per altra banda, la primera estratègia es divideix en passiva i activa, en la que s'utilitzen post-injeccions en la activa per a excitar el sistema i confirmar la fallada total si es dona el cas. A continuació, l'eficiència del DOC s'estima a través d'una tècnica indirecta en la que la temperatura d'activació es detecta i es relaciona amb l'increment d'emissions a través del model. Per altra banda, es desenvolupa un observador per a estimar l'estat d'envelliment del SCR, el qual està basat en un filtre de Kalman extés. No obstant això, per a evitar associar baixa eficiència degut a pobre qualitat de l'urea injectada a l'envelliment del SCR, un indicador de la qualitat de l'urea s'executa en paral·lel.[EN] This dissertation covers the development of algorithms oriented to improve the emission control system of Diesel engines. For this purpose, the inclusion of on-board sensors like temperature, NOx and NH3 sensors allows performing on-board diagnostics to the after-treatment systems focus of this work, which are the DOC and the SCR system. Then, the target is to meet on-board diagnostics regulations in order to keep emissions below a regulation threshold over time. Experimental tests, including gas analyzer measurements, allow having a wider view of the species in the exhaust line. Complementary, new and aged units are used in order to have the experimental effect of ageing on the catalysts. Then, the effect of temperature, exhaust mass flow, species concentrations and ageing is analyzed for DOC and SCR, in combination with the assessment of some relevant sensors measurements. As a result, the characteristics, opportunities and limitations extracted from experimental data are used as the basis for the development of models and diagnostics techniques. The assessment of temperature sensors measurements, along with the development of heat transfer models is required to feed temperature dependent functions. In this sense, the slow measurement of the DOC upstream temperature sensor is improved in transient conditions by means of a data fusion technique, based on a fast model and a Kalman filter. Then, a 1D and a 0D lumped heat transfer models are presented, in which the upstream inputs are assessed in relation to its use. On the other hand, a technique to estimate the temperature increase due to post-injection pulses oxidation is also presented. Both DOC and SCR models are proposed in order to estimate the effect of ageing on emissions, in which an ageing factor is modelled as a tunable parameter that allows varying from new to aged states. On the one hand, a 0D lumped model is developed for DOC in order to estimate the HC and CO species slip, which is validated in a WLTC and is then used for simulation. On the other hand, a 1D and a 0D models are developed for SCR, which are then used to feed the diagnostics strategy and for simulation. Finally, diagnostics strategies are presented for total failure or removal of DOC, as well as for efficiency estimation of DOC and SCR. On the one hand, the former strategy is separated into passive and active diagnostics, in which post-injections are used in active diagnostics in order to excite the system and confirm a total failure, in case. Then, the DOC efficiency estimation is done by means of an indirect technique in which the light-off temperature is detected and an emissions increase is related by means of the DOC ageing model. On the other hand, an observer to estimate the SCR ageing state is developed, which is based on an extended Kalman filter. However, in order to avoid associating low SCR efficiency to ageing, an indicator of the injected urea quality is developed to run in parallel.Mora Pérez, J. (2018). Control-oriented modelling and diagnostics of diesel after-treatment catalysts [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/115937TESI

Development of an Emissions Monitoring Methodology Using On-Board NOx Sensors and Revision to Current In-Use Emissions Regulatory Protocols

Measurement of in-use emissions from heavy-duty (HD) vehicles under real-world operation has been widely performed by using portable emissions measurement system (PEMS). PEMS serve as an accurate and lightweight emissions measurement system to evaluate in-use emissions from HD vehicles. However, emissions measurement using PEMS instrumentation can be time consuming and labor intensive. Advantage of utilizing already existing on-board sensors such that they can potentially provide an alternative measurement methodology to the PEMS. A successful implementation of an on-board NOx sensor-based methodology for assessing in-use NOx emissions will allow for a cost-effective and simplified approach to monitor real-world, NOx emission rates. The technology of on-board NOx sensors is in its initial stages to be used to monitor in-use NOx emissions and the ability of the sensor to measure NO x concentration during selective catalytic reduction (SCR) activity period is of concern. Furthermore, the on-board NOx sensors are also subject to various cross-sensitivity and durability concerns.;The primary objective of this dissertation is to compare the on-board NOx sensor response and accuracy against laboratory grade instrumentation that include PEMS using Non-Dispersive Ultra-Violent (NDUV) and Fourier transform infrared spectroscopy (FTIR) measurement to assess the measurement thresholds of on-board NOx sensors. The study compares the cross-sensitivity of the NOx sensors to ammonia (NH3) concentration in the exhaust. NH3 slip from SCR is believed to interfere with NO x measurements using Zirconium oxide sensors and this study will discuss NH3-NOx cross sensitivity on on-board NO x sensors during real-world HD vehicle activity. Results from this study will compare on-board NOx sensor measurement capabilities and they will be assessed at different power levels related to different SCR conversion efficiency and different NOx concentration levels related to measurements obtained from a laboratory grade emissions measurement system FTIR. The secondary objective of this work is to explore and modify boundary conditions for the Not-to-exceed (NTE) and (Work-based window) WBW regulatory protocols due to deficiencies of current protocols in appropriately characterizing regulated emissions especially during the port drayage and urban activity, characterized by low-load engine operation. Thus, new revised regulatory protocols for a wide range of driving activity are needed for an accurate characterization of in-use NOx emissions

Dual-layered Multi-Objective Genetic Algorithms (D-MOGA): A Robust Solution for Modern Engine Development and Calibrations

Heavy-duty (HD) diesel engines are the primary propulsion systems used within the freight transportation sector and are subjected to stringent emissions regulations. The primary objective of this study is to develop a robust calibration technique for HD engine optimization in order to meet current and future regulated emissions standards during certification cycles and off-cycle vocation activities. Recently, California - Air Resources Board (C-ARB) has also shown interests in controlling off-cycle emissions from vehicles operating in California by funding projects such as the Ultra-Low NOx study by Sharp et. al [1]. Moreover, there is a major push for the complex real-world driving emissions testing protocol as the confirmatory and certification testing procedure in Europe and Asia through the United Nations - Economic Commission for Europe (UN-ECE) and International Organization for Standardization (ISO). This calls for more advanced and innovative approaches to optimize engine operation to meet the regulated certification levels.;A robust engine calibration technique was developed using dual-layered multi-objective genetic algorithms (D-MOGA) to determine necessary engine control parameter settings. The study focused on reducing fuel consumption and lowering oxides of nitrogen (NOx) emissions, while simultaneously increasing exhaust temperatures for thermal management of exhaust after-treatment system. The study also focused on using D-MOGA to develop a calibration routine that simultaneously calibrates engine control parameters for transient certification cycles and vocational drayage operation. Several objective functions and alternate selection techniques for D-MOGA were analyzed to improve the optimality of the D-MOGA results.;The Low-NOx calibration for the Federal Test Procedure (FTP) which was obtained using the simple desirability approach was validated in the engine dynamometer test cell over the FTP and near-dock test cycles. In addition, the 2010 emissions compliant calibration was baselined for performance and emissions over the FTP and custom developed low-load Near-Dock engine dynamometer test cycles. Performance and emissions of the baseline calibrations showed a 63% increase in engine-out brake-specific NOx emissions and a proportionate 77% decrease in engine-out soot emissions over the Near-Dock cycle as compared to the FTP cycle. Engine dynamometer validation results of the Low-NOx FTP cycle calibration developed using D-MOGA, showed a 17% increase brake-specific NOx emissions over the FTP cycle, compared to the baseline calibrations. However, a 50% decrease in engine-out soot emissions and substantial increase in exhaust temperature were observed with no penalties on fuel consumption.;The tools developed in this study can play a role in meeting current and future regulations as well as bridging the gap between emissions during certification and real-world engine operations and eventually could play a vital role in meeting the National Ambient Air Quality Standards (NAAQS) in areas such as the port of Los Angeles, California in the South Coast Air Basin